Aprepitant-loaded solid lipid nanoparticles: a novel approach to enhance oral bioavailability

• Mazhar Hussain,
• Muhammad Farooq,
• Muhammad Asad Saeed,
• Muhammad Ijaz,
• Sherjeel Adnan,
• Zeeshan Masood,
• Muhammad Waqas,
• Wafa Ishaq and
• Nabeela Ameer

Beilstein J. Nanotechnol. 2025, 16, 652–663, doi:10.3762/bjnano.16.50

• formulations remained almost constant after redispersion, with only minor variations observed. APT-CD-NP1 showed a slight reduction from 204.9 ± 0.3 to 200.0 ± 0.1 nm, and the size of APT-PX-NP5 decreased from 257.6 ± 0.3 to 251.0 ± 0.7 nm. These small changes indicated efficient redispersion without

• −1 (C=O stretching). The peak at 1119 cm−1 slightly shifted to 1110 cm−1 in APT-loaded SLNs formulations (Figure 4a). The peaks at 2849 and 2921 cm−1 are attributed to C–H bonds of poloxamer 407 or β-CD. A reduction in intensity and shift of the polymer peaks indicates the interaction between APT and

• exhibited less sharp peaks than APT because of a reduction of the polymer crystallinity. Also, the interaction of polymeric content with APT via hydrogen bonding converts the crystalline form of APT into an amorphous form [20]. TGA and DSC studies Thermogravimetric analysis showed that the thermal

Nanoscale capacitance spectroscopy based on multifrequency electrostatic force microscopy

• Pascal N. Rohrbeck,
• Lukas D. Cavar,
• Franjo Weber,
• Peter G. Reichel,
• Mara Niebling and
• Stefan A. L. Weber

Beilstein J. Nanotechnol. 2025, 16, 637–651, doi:10.3762/bjnano.16.49

• frequencies and beyond. Our results show a significant reduction of signal background from long-range electrostatic interactions, resulting in highly localized measurements. Combined with refined tip–sample capacitance models, MFH-EFM will enhance the precision of quantitative studies on dielectric effects in

• frequency ωm ± 2ωmod. The latter one is independent of the local CPD, making it interesting for dielectric measurements. As the magnitude of this force component depends on C″, we can expect a superior lateral resolution through a reduction of long-range force contributions from tip cone and cantilever. As

• on the second term in Equation 10 (Figure 6, non-normalized data in Figures S9–S11, Supporting Information File 1). In comparison to the MFH-EFM data, the C′ frequency sweep looked very similar on the different structures. We think that this reduction in contrast is caused by the stronger influence

A formulation containing Cymbopogon flexuosus essential oil: improvement of biochemical parameters and oxidative stress in diabetic rats

• Ailton Santos Sena-Júnior,
• Cleverton Nascimento Santana Andrade,
• Pedro Henrique Macedo Moura,
• Jocsã Hémany Cândido dos Santos,
• Cauãn Torres Trancoso,
• Eloia Emanuelly Dias Silva,
• Deise Maria Rego Rodrigues Silva,
• Ênio Pereira Telles,
• Luiz André Santos Silva,
• Isabella Lima Dantas Teles,
• Sara Fernanda Mota de Almeida,
• Daniel Alves de Souza,
• Jileno Ferreira Santos,
• Felipe José Aidar Martins,
• Ana Mara de Oliveira e Silva,
• Sandra Lauton-Santos,
• Guilherme Rodolfo Souza de Araujo,
• Cristiane Bani Correa,
• Rogéria De Souza Nunes,
• Lysandro Pinto Borges and
• Ana Amélia Moreira Lira

Beilstein J. Nanotechnol. 2025, 16, 617–636, doi:10.3762/bjnano.16.48

• surroundings, covering a wider spectrum of compounds [34]. Finally, FRAP evaluates the interaction of the compounds with a ferric complex (TPTZ-Fe3+), with hydrogen donation and reduction effects (TPTZ-Fe2+). Another point to be raised is the saturation of the system. In the DPPH test, the antioxidant activity

• microcapsules, showed a reduction in the antioxidant activity of the formulation when compared to the oil alone. However, the authors defend the idea that the high temperature used in the process altered the compounds in the oil and reduced the antioxidant activity. In the microemulsion formulation in this

• = 452.78 mg/dL), induced by STZ, compared to supplemented animals. Treatment with the essential oil (EOCF = 234.71 mg/dL, p < 0.0001), the microemulsion (M7-EOCF = 283.75 mg/dL, p < 0.001), and metformin (MET = 300.86 mg/dL, p < 0.01) provided a significant reduction in glucose by, respectively, 48.16

Polyurethane/silk fibroin-based electrospun membranes for wound healing and skin substitute applications

• Iqra Zainab,
• Zohra Naseem,
• Syeda Rubab Batool,
• Muhammad Waqas,
• Ahsan Nazir and
• Muhammad Anwaar Nazeer

Beilstein J. Nanotechnol. 2025, 16, 591–612, doi:10.3762/bjnano.16.46

• showed that various proteases, such as protease K, collagenase, and α-chymotrypsin can degrade silk, resulting in a gradual reduction in material strength and weight over time [100]. In vivo, silk degradation is also affected by the β-sheet content; scaffolds that have a high concentration of β-sheets

Feasibility analysis of carbon nanofiber synthesis and morphology control using a LPG premixed flame

• Iftikhar Rahman Bishal,
• Muhammad Hilmi Ibrahim,
• Norikhwan Hamzah,
• Mohd Zamri Mohd Yusop,
• Faizuan Bin Abdullah,
• I Putu Tedy Indrayana and
• Mohd Fairus Mohd Yasin

Beilstein J. Nanotechnol. 2025, 16, 581–590, doi:10.3762/bjnano.16.45

• beads. After saturation, the impregnated zirconia beads were dried at a temperature of 90 °C. Finally, a reduction process was carried out in a furnace at a temperature of 500 °C to transform the nickel nitrate into nickel oxide on the zirconia substrate. Experimental setup The setup of the premixed

Nanomaterials in targeting amyloid-β oligomers: current advances and future directions for Alzheimer's disease diagnosis and therapy

• Shiwani Randhawa,
• Trilok Chand Saini,
• Manik Bathla,
• Rahul Bhardwaj,
• Rubina Dhiman and
• Amitabha Acharya

Beilstein J. Nanotechnol. 2025, 16, 561–580, doi:10.3762/bjnano.16.44

• ” curvilinear fibrils and recognized as a specific form of AβOs than other known antibodies such as aducanumab or gantenerumab. Furthermore, clinical observations have indicated that treatment with lecanemab is associated with a reduction in cognitive decline, underscoring its promise as a viable therapeutic

• , exhibiting the greatest reduction in Aβ1–42 peptide-induced cytotoxicity in Neuro-2a cell lines. Structural studies indicate that these palladium complexes interact with both the fibrillar (PDB: 2BEG) and monomeric (PDB: 1IYT) forms of the Aβ1–42 peptide. This interaction occurs through a variety of binding

Retrieval of B1 phase from high-pressure B2 phase for CdO nanoparticles by electronic excitations in Cd_xZn_1−xO composite thin films

• Arkaprava Das,
• Marcin Zając and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2025, 16, 551–560, doi:10.3762/bjnano.16.43

• peak corresponding to willemite Zn2SiO4 (space group R−3) is observed at 38.8°, previously identified as a contributing factor to the B2 phase transition [1]. In the case of the CZ900_113O sample, a reduction in the intensity of the B2 phase reflections is noted, accompanied by a subtle emergence of

• publication [1]. The prominent features a1 and a2 observed at 535 eV and 537 eV, respectively, in the O K edge spectrum of the CZ900_Pris sample correspond to electronic transitions from O 1s to hybridized Zn 4s and O 2p orbitals. In the CZ900_313O thin film, there is a significant reduction in the intensity

• of the B1 phase is the reduction of localized pressure exerted by Zn2SiO4 nanoparticles due to oxygen ion irradiation. This phase transition from B1 to B2 is reported to be irreversible under hydrostatic pressure [14] or localized pressure [1]. However, ion irradiation has emerged as an effective

Functionalized gold nanoflowers on carbon screen-printed electrodes: an electrochemical platform for biosensing hemagglutinin protein of influenza A H1N1 virus

• Carlos Enrique Torres-Méndez,
• Sharmilee Nandi,
• Klara Martinovic,
• Patrizia Kühne,
• Yifan Liu,
• Sam Taylor,
• Maria Lysandrou,
• Maria Ines Berrojo Romeyro Mascarenhas,
• Viktoria Langwallner,
• Javier Enrique Sebastián Alonso,
• Ivana Jovanovic,
• Maike Lüftner,
• Georgia-Vasiliki Gkountana,
• David Bern,
• Abdul-Raouf Atif,
• Ehsan Manouchehri Doulabi,
• Gemma Mestres and
• Masood Kamali-Moghaddam

Beilstein J. Nanotechnol. 2025, 16, 540–550, doi:10.3762/bjnano.16.42

• the scan rate (Figure 6), suggesting that the reduction and oxidation of the complex [Fe(CN)6]3−/4− is a diffusion-controlled process. The performance of mouse monoclonal influenza A H1N1 hemagglutinin antibodies was tested using sandwich ELISA. They were selected as biorecognition element in our

• measurement employing the standard DPV experiment (n = 3), a decrease in current response of 3.1% was observed (Figure 8) in comparison to a measurement without the microfluidics system. This decrease was probably due to a slight reduction in the surface area of the working electrode once the biosensor was

Electron beam-based direct writing of nanostructures using a palladium β-ketoesterate complex

• Chinmai Sai Jureddy,
• Krzysztof Maćkosz,
• Aleksandra Butrymowicz-Kubiak,
• Iwona B. Szymańska,
• Patrik Hoffmann and
• Ivo Utke

Beilstein J. Nanotechnol. 2025, 16, 530–539, doi:10.3762/bjnano.16.41

• diffusion process taking place. TEM analysis revealed metal nanograins embedded in a carbonaceous matrix. The deposits contained up to 30 atom % Pd, with a prominent reduction of about 90% of the 23 carbon atoms in the precursor. Using a continuum model, the calculated upper limit of the desorption rate

• could be broadly used for any FEBID deposits. In our case, the carbon contamination contributed 2–4 atom % carbon content in the FEB deposit. The [Pd(tbaoac)2] precursor exhibits the highest reduction in carbon content by FEBID compared to other precursors with large ligands, highlighting the importance

• precursors. The substrate and GIS temperatures (T) are indicated. Note the highest ligand removal efficiency for the β-ketoesterate complex [Pd(tbaoac)2]. The arrows represent the reduction of atoms in the pristine molecule with respect to the number of atoms in the FEBID deposit composition. RT stands for

Zeolite materials with Ni and Co: synthesis and catalytic potential in the selective hydrogenation of citral

• Inocente Rodríguez-Iznaga,
• Yailen Costa Marrero,
• Tania Farias Piñeira,
• Céline Fontaine,
• Lexane Paget,
• Beatriz Concepción Rosabal,
• Arbelio Penton Madrigal,
• Vitalii Petranovskii and
• Gwendoline Lafaye

Beilstein J. Nanotechnol. 2025, 16, 520–529, doi:10.3762/bjnano.16.40

• and temperature-programmed reduction. The materials prepared by IE had negligible chloride content (0.02–0.07%), and their specific surface areas (138–146 m2/g) were greater than those of the materials obtained by Imp (54–67 m2/g). The bimetallic systems exhibited enhanced reducibility of the Co2+ and

• hydrogenation by leveraging controlled acidity to prevent overhydrogenation and optimize product yields [15]. Similarly, Co-modified zeolites have been effectively used in cinnamaldehyde hydrogenation, where the balance between acidity and metal dispersion facilitates the selective reduction of the carbonyl

• monometallic materials obtained from both treatments. Despite the previously mentioned observations, both types of materials (from IE and Imp) exhibit a reduction in Na, K, Ca, and Mg levels compared to ZSA, with this decrease being more pronounced in the materials obtained via IE. This suggests that in both

Water in nanoporous hexagonal boron nitride nanosheets: a first-principles study

• Juliana A. Gonçalves,
• Ronaldo J. C. Batista and
• Marcia C. Barbosa

Beilstein J. Nanotechnol. 2025, 16, 510–519, doi:10.3762/bjnano.16.39

• recent decades, technological advances such as membrane technology and energy recovery equipment have led to a considerable reduction in the energy required to desalinate seawater [2][3]. The proposal to use membranes that exhibit superior selectivity and high water flux has been a major focus for

• influences the mobility of water/ions through the membrane. Consequently, the transport rates of both ions and water decrease when passing through the highly polarized membrane. Additionally, the salt rejection in the polarized channel increases in proportion to the channel length, accompanied by a reduction

• typically observed at lower temperatures. The incorporation of B–H or B–OH moieties at the vertices of triangular pores results in a significant reduction in formation energies. The decrease in energy per atom ranges from −1.230 to −0.525 eV, depending on the chemical environment (B-rich or N-rich, defined

N₂⁺-implantation-induced tailoring of structural, morphological, optical, and electrical characteristics of sputtered molybdenum thin films

• Usha Rani,
• Kafi Devi,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 495–509, doi:10.3762/bjnano.16.38

• -centered cubic Mo phase, as per JCPDS no. 01-088-2331 [29]. In Figure 2A, there is a notable reduction in peak intensity of the Mo film after N2+ implantation relative to the as-deposited Mo film. This reveals a significant alteration in structure due to the implantation process. Similarly, in Figure 2B–D

• thickness increased from 150 to 300 nm, signifying a reduction in interplanar spacing. The decrease in interplanar spacing is a direct consequence of the compressive force induced by nitrogen implantation. During the deposition process, Mo thin films exhibit different types of stress due to changes in

• pronounced (111) orientation. Crystallite size and texture coefficients of these Mo thin films significantly increase with the thickness of Mo thin films. Moreover, a significant reduction has been observed in both these parameters after nitrogen implantation compared to equivalently thick as-deposited films

Effect of additives on the synthesis efficiency of nanoparticles by laser-induced reduction

• Rikuto Kuroda,
• Takahiro Nakamura,
• Hideki Ina and
• Shuhei Shibata

Beilstein J. Nanotechnol. 2025, 16, 464–472, doi:10.3762/bjnano.16.35

• Rikuto Kuroda Takahiro Nakamura Hideki Ina Shuhei Shibata illuminus Inc., 307 Wako Riken Incubation Plaza, 2–3–13, Minami, Wako, Saitama, 351–0104, Japan 10.3762/bjnano.16.35 Abstract Laser-induced reduction in liquid (LRL) is a physicochemical technique for synthesizing nanoparticles by

• applications. Keywords: laser-induced reduction; laser synthesis and processing of colloidal nanoparticles; production efficiency; Introduction Metal nanoparticles exhibit unique chemical, physical and optical properties that are not found in their bulk materials, and are used in a variety of fields

• including electrode materials [1], conductive pastes [2][3], catalysts [4][5], sensors [6][7][8], and drug delivery systems [9]. The chemical reduction [10] and the solvothermal methods [11][12] are well known for synthesizing nanoparticles in large quantities at low cost, but these methods require the use

Synthetic-polymer-assisted antisense oligonucleotide delivery: targeted approaches for precision disease treatment

• Ana Cubillo Alvarez,
• Dylan Maguire and
• Ruairí P. Brannigan

Beilstein J. Nanotechnol. 2025, 16, 435–463, doi:10.3762/bjnano.16.34

• % inhibition by the ASO alone. Furthermore, the Gal–PLL conjugation facilitated higher liver-specific uptake, with a 52.1% concentration in the liver compared to 21.9% for ASOs alone. This targeted approach resulted in a significant reduction in HBV DNA levels in transgenic mice, with some achieving

• mRNA and activity, Jääskeläinen et al. demonstrated that linear PLLs with average molecular weights (Mn) of 4, 20, and 200 kDa exhibited no enhancement on PS-ODN activity [75]. Conversely, Marano et al. showed that a series of hybrid lipid–lysine dendrimer–ASO conjugates resulted in 40–60% reduction in

• 81.5% compared to 56.8% for dendrimers with fewer charges. This improved transfection efficiency correlated with a significant reduction in VEGF expression, with certain dendrimer/ODN-1 complexes maintaining VEGF inhibition for up to 48 h after transfection. Moreover, in vivo experiments using a rat

Quantification of lead through rod-shaped silver-doped zinc oxide nanoparticles using an electrochemical approach

• Ravinder Lamba,
• Gaurav Bhanjana,
• Neeraj Dilbaghi,
• Vivek Gupta and
• Sandeep Kumar

Beilstein J. Nanotechnol. 2025, 16, 422–434, doi:10.3762/bjnano.16.33

• the ZnO crystal lattice results in a decrement in the peak position values because Ag+ ion (12.2 nm) has a larger ionic size compared to that of the Zn2+ ion (7.4 nm). Consequently, the given data aligns with the decrease in the highest location of the point, indicating a reduction in the c-axis

• ZnO frequently causes a reduction in the bandgap, leading to a shift toward longer wavelengths in the absorption spectra. The smaller bandgaps of the samples in optoelectronic devices provide a significant advantage [21]. Zeta potential of Ag@ZnO nanorods Surface properties of the synthesized Ag@ZnO

• ) lead at a 40 mV/s scan rate is shown in Figure 9. The obtained CV graph demonstrates that the gold electrode modified with Ag@ZnO NRs exhibits no response in the absence of lead (black line). However, when lead is introduced in moderate quantities, a significant reduction peak is distinctly observed in

Biomimetics and bioinspired surfaces: from nature to theory and applications

• Rhainer Guillermo Ferreira,
• Thies H. Büscher,
• Manuela Rebora,
• Poramate Manoonpong,
• Zhendong Dai and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2025, 16, 418–421, doi:10.3762/bjnano.16.32

• Mechanics and Control for Aerospace Structures, College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing, China 10.3762/bjnano.16.32 Keywords: adhesives; bioengineering; biomimetics; drag reduction; functional morphology; insects; medical coatings

• scaling on steel surfaces. Using silicone nanofilaments, they achieved 75.5% reduction of calcium carbonate deposition on treated steel samples. While many articles concentrated on using natural designs to inspire technological innovation (biology-push), others took an application-driven (technology-pull

Size control of nanoparticles synthesized by pulsed laser ablation in liquids using donut-shaped beams

• Abdel Rahman Altakroury,
• Oleksandr Gatsa,
• Farbod Riahi,
• Zongwen Fu,
• Miroslava Flimelová,
• Andrei Samokhvalov,
• Stephan Barcikowski,
• Carlos Doñate-Buendía,
• Alexander V. Bulgakov and
• Bilal Gökce

Beilstein J. Nanotechnol. 2025, 16, 407–417, doi:10.3762/bjnano.16.31

• laser beam. In experiments on pulsed laser ablation in water of gold, yttrium oxide, and high-entropy alloy targets with both Gaussian and donut-shaped beams, we observed a significant reduction in particle size, narrowing of the size distribution width, and an improvement in sphericity when utilizing

• phase transformation processes do not seem to have a major impact on the resulting sizes of NPs produced with donut-shaped pulses since the observed trends of size reduction and narrowing the distribution are similar to those for the other studied materials. The peak corresponding to the

• crystallographic plane (111) is very small but visible, whereas the other (200) and (220) peaks are not visible for the NPs. Laser irradiation plays a major role in the formation of HEA with strong (111) peak while minimizing (200) and (220) peaks [54]. The observed NP size-reduction trend for the donut-shaped

Development of a mucoadhesive drug delivery system and its interaction with gastric cells

• Ahmet Baki Sahin,
• Serdar Karakurt and
• Deniz Sezlev Bilecen

Beilstein J. Nanotechnol. 2025, 16, 371–384, doi:10.3762/bjnano.16.28

• complexes after mucin interaction. In addition to the size distribution and PDI alterations, the zeta potential of EudAlg nanoparticles shifted from 39.72 ± 6.7 to −12.13 ± 9.8 mV after interaction with mucin. The observed reduction in zeta potential is also attributed to the interaction and surrounding of

• 595 nm with a microplate reader (BioTek Synergy H1). From these optical density values, percent reduction values (representing the metabolic activity) were calculated for each time point. Data is represented as percent viability, which was calculated by the formula below. The viability percentages of

Pulsed laser in liquid grafting of gold nanoparticle–carbon support composites

• Madeleine K. Wilsey,
• Teona Taseska,
• Qishen Lyu,
• Connor P. Cox and
• Astrid M. Müller

Beilstein J. Nanotechnol. 2025, 16, 349–361, doi:10.3762/bjnano.16.26

• electrocatalytic hydrogen evolution in aqueous bicarbonate reduction. Keywords: catalysis; composite; electroreduction; gold nanoparticles; impedance; Introduction The main challenge in the manufacturing of nanocatalyst-containing electrodes is the attachment of nanoparticles on electrode supports. Nanoparticles

• composites as cathodes in electrocatalytic aqueous bicarbonate reduction and compared their performance and electrical impedance to analogous electrodes that were conventionally prepared by electrostatically attaching commercial nucleation grown and citrate-capped gold nanoparticles to carbon fiber paper

• . Results and Discussion Carbon fiber paper served as electrode support material because graphite is cost-effective, scalable, and the premier electrode support material for reduction reactions [21]. Gold nanoparticles were laser grafted from aqueous HAuCl4 solution. The use of an aqueous liquid requires

Tailoring of physical properties of RF-sputtered ZnTe films: role of substrate temperature

• Kafi Devi,
• Usha Rani,
• Arun Kumar,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 333–348, doi:10.3762/bjnano.16.25

• leads to a reduction in microstrain and dislocation density. The optical studies using UV–vis–NIR spectroscopy reveal that the transmittance of films increases with substrate temperature. Further, the shift in transmittance threshold towards lower wavelengths with substrate temperature indicates that

Graphene oxide–chloroquine conjugate induces DNA damage in A549 lung cancer cells through autophagy modulation

• Braham Dutt Arya,
• Sandeep Mittal,
• Prachi Joshi,
• Alok Kumar Pandey,
• Jaime E. Ramirez-Vick,
• Govind Gupta and
• Surinder P. Singh

Beilstein J. Nanotechnol. 2025, 16, 316–332, doi:10.3762/bjnano.16.24

• functional groups in the GO–Chl nanoconjugate. The observed reduction in the intensity of COOH peaks for GO–Chl as compared to that of GO, could be attributed to the possible reduction of oxygen-rich functional groups as a result of their interaction with amino groups present in Chl [47]. It was observed

Fabrication and evaluation of BerNPs regarding the growth and development of Streptococcus mutans

• Tuyen Huu Nguyen,
• Hong Thanh Pham,
• Kieu Kim Thanh Nguyen,
• Loan Hong Ngo,
• Anh Ngoc Tuan Mai,
• Thu Hoang Anh Lam,
• Ngan Thi Kim Phan,
• Dung Tien Pham,
• Duong Thuy Hoang,
• Thuc Dong Nguyen and
• Lien Thi Xuan Truong

Beilstein J. Nanotechnol. 2025, 16, 308–315, doi:10.3762/bjnano.16.23

• an efficient technique for fabricating nanoparticles from crystalline structures of organic pharmaceutical raw materials [18]. Other studies have shown that incorporating surfactants into the wet ball milling process significantly enhances particle size reduction, facilitates the effective production

Enhancing mechanical properties of chitosan/PVA electrospun nanofibers: a comprehensive review

• Nur Areisman Mohd Salleh,
• Amalina Muhammad Afifi,
• Fathiah Mohamed Zuki and
• Hanna Sofia SalehHudin

Beilstein J. Nanotechnol. 2025, 16, 286–307, doi:10.3762/bjnano.16.22

• ratio on tensile properties of the material. Koosha et al. [59] observed a reduction in ultimate tensile strength, Young’s modulus, elongation at break, and toughness with the incorporation of chitosan as opposed to pure PVA membranes. As the chitosan content increases, the tensile strength decreases

• was found to increase with increasing chitosan concentration, but only up to 3.5% (w/w); further increasing the concentration resulted in a significant reduction in elasticity. The elongation at break was also highest at a chitosan concentration of 3.5% (w/w). These results indicate that the

Emerging strategies in the sustainable removal of antibiotics using semiconductor-based photocatalysts

• Yunus Ahmed,
• Keya Rani Dutta,
• Parul Akhtar,
• Md. Arif Hossen,
• Md. Jahangir Alam,
• Obaid A. Alharbi,
• Hamad AlMohamadi and
• Abdul Wahab Mohammad

Beilstein J. Nanotechnol. 2025, 16, 264–285, doi:10.3762/bjnano.16.21

• − + h+ → HO• + H+) [35][57]. After excitation, H+ possesses the capacity to interact with electrons, generating thermal energy (H+ + e− → energy). This process results in a reduction of the photodegradation efficiency. Notably, the typical redox potential of photocatalysts must exceed that of HO•/OH

• effective segregation of light-induced charge carriers allows the CB of the second semiconductor and the VB of the first semiconductor to engage in reduction and oxidation processes, thus enhancing the photocatalytic activity. Although type-II heterojunctions can restrict photogenerated charge recombination

• eV, this material can efficiently absorb a significant amount of visible light, which is advantageous for both oxidation and reduction reactions [100]. Nevertheless, some noteworthy concerns arise, such as elevated rate of electron–hole recombination, limited surface area, restricted number of active

Preferential enrichment and extraction of laser-synthesized nanoparticles in organic phases

• Theo Fromme,
• Maximilian L. Spiekermann,
• Florian Lehmann,
• Stephan Barcikowski,
• Thomas Seidensticker and
• Sven Reichenberger

Beilstein J. Nanotechnol. 2025, 16, 254–263, doi:10.3762/bjnano.16.20

• system. The abundance of nanoparticles in PC or alcohol was found to correlate with the electrochemical reduction potential of the respective metal, where the noble metals were enriched within the more polar solvents. The polarity of the solvents (as function of the carbon chain length of the alcohol

• , polarity of the solvent, or even physical attributes (e.g., boiling point), phase transfer methods are essential. To close this knowledge gap, we have performed ablation of six different metals (Au, Ag, Cu, Fe, Al, and Ti) ranging from high to low standard electrochemical reduction potentials in a

• , changing the polarity of the non-polar solvent phase for the laser ablation of copper. Iron and copper stand in the middle of the investigated standard electrochemical reduction potential metal series and show quite interesting phase selectivity behavior. Moreover, cupreous nanoparticles are relevant for