Graphene–graphite hybrid epoxy composites with controllable workability for thermal management

• Idan Levy,
• Eyal Merary Wormser,
• Maxim Varenik,
• Matat Buzaglo,
• Roey Nadiv and
• Oren Regev

Beilstein J. Nanotechnol. 2019, 10, 95–104, doi:10.3762/bjnano.10.9

• demonstrate the utility of this approach by fabricating a thermal interface material with tunable workability and testing it in a model electronic device. Keywords: hybrid composites; nanocomposites; rheology; thermal interface material; thermal properties; Introduction Modern-day miniaturization of

A novel polyhedral oligomeric silsesquioxane-modified layered double hydroxide: preparation, characterization and properties

• Xianwei Zhang,
• Zhongzhu Ma,
• Hong Fan,
• Carla Bittencourt,
• Jintao Wan and
• Philippe Dubois

Beilstein J. Nanotechnol. 2018, 9, 3053–3068, doi:10.3762/bjnano.9.284

• the range of 0.17–0.33, and the species of metallic ions and intercalated anions are variable, giving rise to versatile isostructural LDHs [1][2][3][4]. In recent years, LDHs have found wide application in polymer nanocomposites because they are highly tunable and can observably improve the flame

Electrostatic force microscopy for the accurate characterization of interphases in nanocomposites

• Diana El Khoury,
• Richard Arinero,
• Jean-Charles Laurentie,
• Mikhaël Bechelany,
• Michel Ramonda and
• Jérôme Castellon

Beilstein J. Nanotechnol. 2018, 9, 2999–3012, doi:10.3762/bjnano.9.279

• de Montpellier, Université de Montpellier, Montpellier, France 10.3762/bjnano.9.279 Abstract The unusual properties of nanocomposites are commonly explained by the structure of their interphase. Therefore, these nanoscale interphase regions need to be precisely characterized; however, the existing

• deduced by comparison of experimental data and numerical simulations, as well as the interface state of silicone dioxide layers. Keywords: atomic force microscopy; building-block materials; dielectric permittivity; electrostatic force microscopy; finite element simulation; interphases; nanocomposites

• [6][7][8][9]. This unusual behavior of nanocomposites is due to the interfacial region between the nanoparticles and polymer, also called the “interphase”. The interphase region can range from a few angstroms to a few nanometers, and usually has properties that differ from those of the polymer and

Ternary nanocomposites of reduced graphene oxide, polyaniline and hexaniobate: hierarchical architecture and high polaron formation

• Claudio H. B. Silva,
• Maria Iliut,
• Christopher Muryn,
• Christian Berger,
• Zachary Coldrick,
• Vera R. L. Constantino,
• Marcia L. A. Temperini and
• Aravind Vijayaraghavan

Beilstein J. Nanotechnol. 2018, 9, 2936–2946, doi:10.3762/bjnano.9.272

• Nanostructured systems, such as nanocomposites, are potential materials for usage in different fields since synergistic effects of their components at the nanoscale domain may improve physical/chemical properties when compared to individual phases. We report here the preparation and characterisation of a new

• Nanostructured systems, such as nanocomposites, are potential materials for usage as electrochemical (bio)sensors for analytical purposes, electronics, energy storage devices and corrosion protection because the synergistic effects of their components at the nanoscale range may improve physical/chemical

• properties when compared to individual phases or enable new technological applications [1][2][3]. For instance, ternary nanocomposites (conducting polymers, metal oxides and carbon-based materials) exhibit improved energy and power densities, improved stabilities upon charge/discharge cycles [4], and higher

Layered calcium phenylphosphonate: a hybrid material for a new generation of nanofillers

• Kateřina Kopecká,
• Ludvík Beneš,
• Klára Melánová,
• Vítězslav Zima,
• Petr Knotek and
• Kateřina Zetková

Beilstein J. Nanotechnol. 2018, 9, 2906–2915, doi:10.3762/bjnano.9.269

• exfoliation and can thereby serve as a component of nanocomposites. The synthesis procedure was revised and the reaction conditions, under which this material can be prepared in a form suitable for exfoliation in a sufficient amount, were found. Furthermore, the conditions for the exfoliation of this compound

Nanostructured liquid crystal systems and applications

• Alexei R. Khokhlov and
• Alexander V. Emelyanenko

Beilstein J. Nanotechnol. 2018, 9, 2644–2645, doi:10.3762/bjnano.9.245

• . There have also been reports of some very interesting experiments with nanocomposites where the solid nanoparticles are dissolved in liquid crystals. Composite materials and mixtures of liquid crystals usually possess better properties than their pure liquid crystal counterparts. Many challenges could

Cytotoxicity of doxorubicin-conjugated poly[N-(2-hydroxypropyl)methacrylamide]-modified γ-Fe₂O₃ nanoparticles towards human tumor cells

• Zdeněk Plichta,
• Yulia Kozak,
• Rostyslav Panchuk,
• Viktoria Sokolova,
• Matthias Epple,
• Lesya Kobylinska,
• Pavla Jendelová and
• Daniel Horák

Beilstein J. Nanotechnol. 2018, 9, 2533–2545, doi:10.3762/bjnano.9.236

• hMSCs. In particular, the number of dying cells under the action of these nanocomposites increased by 10–20% compared to free Dox (Figure 7). In contrast, the percentage of alive hMSCs increased by 5–25% in the presence of γ-Fe2O3@P(HPMA-MMAA)-Dox particles (Figure 8). Thus, it seems that γ-Fe2O3@PHPMA

Non-agglomerated silicon–organic nanoparticles and their nanocomplexes with oligonucleotides: synthesis and properties

• Asya S. Levina,
• Marina N. Repkova,
• Nadezhda V. Shikina,
• Zinfer R. Ismagilov,
• Svetlana A. Yashnik,
• Dmitrii V. Semenov,
• Yulia I. Savinovskaya,
• Natalia A. Mazurkova,
• Inna A. Pyshnaya and
• Valentina F. Zarytova

Beilstein J. Nanotechnol. 2018, 9, 2516–2525, doi:10.3762/bjnano.9.234

• formation of TiO2·PL–DNA nanocomposites [1][2]. Silica nanoparticles can also be used as vehicles to deliver nucleic acid fragments into cells [3][4]. SiO2 nanoparticles bearing amino groups on the surface were shown to bind plasmid DNA, allowing the nanoparticles to penetration into cells, and even nuclei

Nanocellulose: Recent advances and its prospects in environmental remediation

• Katrina Pui Yee Shak,
• Yean Ling Pang and
• Shee Keat Mah

Beilstein J. Nanotechnol. 2018, 9, 2479–2498, doi:10.3762/bjnano.9.232

• graphitic carbon nitride [2][3], carbon nanodots [4], and two-dimensional carbon-based nanocomposites [5][6][7] are a few trending nanomaterials that have already found extensive applications in both environmental remediation and energy generation. In the past, carbon nanotubes (CNTs) have received a great

• addition, nanocomposites fabricated from another species known as the stalked sea squirt (Styela Clava) has also demonstrated its usefulness as a catalyst for water remediation [60]. In a separate investigation led by Yu et al. [61], stalked sea squirt nanocellulose were also used as an environmentally

• nanocomposites with hierarchical structure. Besides, these –OH groups can be tailored for selective and improved interactions through a variety of chemical modifications [88]. The hydrophilicity of nanocellulose can be improved by inserting hydrophilic groups, such as carboxylic acids, alcohols, and amides, into

SERS active Ag–SiO₂ nanoparticles obtained by laser ablation of silver in colloidal silica

• Cristina Gellini,
• Francesco Muniz-Miranda,
• Alfonso Pedone and
• Maurizio Muniz-Miranda

Beilstein J. Nanotechnol. 2018, 9, 2396–2404, doi:10.3762/bjnano.9.224

• examined by UV–vis absorption spectroscopy, transmission electron microscopy and Raman spectroscopy. The surface enhanced Raman scattering (SERS) activity of these nanocomposites was tested using 2,2’-bipyridine as a molecular reporter and excitation in the visible and near-IR spectral regions. The

• ; silver; Introduction Silica nanoparticles in an aqueous suspension are known to be inert and dispersible – properties which can be quite useful in the preparation of colloidal nanocomposites with silver. For this reason, there are a significant number of studies in the literature on colloidal substrates

• chemical reactants. These nanocomposites, which combine the adsorption properties of silica with the plasmonic properties of nanometer-sized silver, can be used for several purposes, for example, for the SERS detection of environmental contaminants such as POPs (persistent organic pollutants), as

Electrospun one-dimensional nanostructures: a new horizon for gas sensing materials

• Muhammad Imran,
• Nunzio Motta and
• Mahnaz Shafiei

Beilstein J. Nanotechnol. 2018, 9, 2128–2170, doi:10.3762/bjnano.9.202

• composites, are fabricated in various assemblies (e.g., as mixed nanocomposites, double-layers, core–shell or hollow forms) using the electrospinning technique [37]. These electrospun nanofibers exhibit enhanced specific surface area, superior mechanical properties, nanoporosity and improved surface

Uniform cobalt nanoparticles embedded in hexagonal mesoporous nanoplates as a magnetically separable, recyclable adsorbent

• Can Zhao,
• Yuexiao Song,
• Tianyu Xiang,
• Wenxiu Qu,
• Shuo Lou,
• Xiaohong Yin and
• Feng Xin

Beilstein J. Nanotechnol. 2018, 9, 1770–1781, doi:10.3762/bjnano.9.168

• : absorbent regeneration; CoAl layered double hydroxide; efficient adsorbent; hexagonal nanoplates; magnetic nanoparticles; polydopamine; Introduction Nanocomposites with unique electronic, mechanical, magnetic, and physicochemical properties have gained much attention because of their large specific surface

• area and high surface energy [1][2]. In the past few decades, researchers showed great interest in designing various nanocomposites for many potential applications, among which water pollution treatment has become an important issue for human health and environmental protection [3][4][5]. A large

• number of researches have demonstrated that carbon-based nanocomposites can serve as effective adsorbents for wastewater purification [6][7][8][9]. The introduction of transition metal nanoparticles into a mesoporous carbon matrix to form transition-metal-loaded mesoporous carbon nanocomposites (TM-MCNs

Nitrogen-doped carbon nanotubes coated with zinc oxide nanoparticles as sulfur encapsulator for high-performance lithium/sulfur batteries

• Yan Zhao,
• Zhengjun Liu,
• Liancheng Sun,
• Yongguang Zhang,
• Yuting Feng,
• Xin Wang,
• Indira Kurmanbayeva and
• Zhumabay Bakenov

Beilstein J. Nanotechnol. 2018, 9, 1677–1685, doi:10.3762/bjnano.9.159

• providing pathways for ion and electron transport. The as-prepared S/ZnO@NCNT composite is a promising cathode material for Li/S batteries. Keywords: batteries; nanocomposites; sol–gel processes; sulfur; zinc oxide (ZnO); Introduction Due to its high theoretical specific capacity of 1672 mAh·g−1 and

• this work, we synthesized nanocomposites of zinc oxide-coated nitrogen-doped carbon nanotubes with sulfur (S/ZnO@NCNT). ZnO was chosen because it is cheap, non-toxic and stable [14][15]. More importantly, ZnO demonstrates a strong affinity to polysulfides. In addition, NCNT was used due to its good

Nanocomposites comprised of homogeneously dispersed magnetic iron-oxide nanoparticles and poly(methyl methacrylate)

• Sašo Gyergyek,
• David Pahovnik,
• Ema Žagar,
• Alenka Mertelj,
• Rok Kostanjšek,
• Miloš Beković,
• Marko Jagodič,
• Heinrich Hofmann and
• Darko Makovec

Beilstein J. Nanotechnol. 2018, 9, 1613–1622, doi:10.3762/bjnano.9.153

• Powder Technology, Ecole Polytechniquie Fédérale de Lausane, Station 12, 1015 Lausane, Switzerland 10.3762/bjnano.9.153 Abstract Nanocomposites with a high, uniform loading of magnetic nanoparticles are very desirable for applications such as electromagnetic shielding and cancer treatment based on

• magnetically induced hyperthermia. In this study, a simple and scalable route for preparing nanocomposites with a high, uniform loading of magnetic nanoparticles is presented. The magnetic iron-oxide nanoparticles were functionalized with a methacrylate-based monomer that copolymerized in a toluene solution

• with the methyl methacrylate (MMA) monomer. The resulting suspension of magnetic nanoparticles decorated with poly(methyl methacrylate) (PMMA) chains in toluene were colloidal, even in the presence of a magnetic field gradient. Nanocomposites were precipitated from these suspensions. The transmission

Cr(VI) remediation from aqueous environment through modified-TiO₂-mediated photocatalytic reduction

• Rashmi Acharya,
• Brundabana Naik and
• Kulamani Parida

Beilstein J. Nanotechnol. 2018, 9, 1448–1470, doi:10.3762/bjnano.9.137

• with given organic compounds under suitable reaction conditions facilitates the selective organic transformations. For example, Hu et al. demonstrated that photocatalytic, selective oxidation of alcohol to aldehyde can be carried out by hVB+ and O2•− on the surface of CdS/TiO2 nanocomposites under

• facilitation by a RGO nanosheets, as shown in Figure 8. Shaikh et al. synthesized TiO2–RGO nanocomposites with uniformly dispersed 4–9 nm diameter TiO2 nanoparticles by a one-step solvothermal technique and evaluated its photocatalytic activity towards reduction of Cr(VI). The use of 1 wt % of RGO at acidic pH

• on TiO2 nanoparticles to form TiO2/Cu2O nanocomposites, a p–n nano-heterojunction having a built-in electric field at the interfaces. This built-in electric field largely prevented the recombination of photoexcited charge carriers, resulting in increased lifetime of photocarriers, induced higher

New 2D graphene hybrid composites as an effective base element of optical nanodevices

• Olga E. Glukhova,
• Igor S. Nefedov,
• Alexander S. Shalin and
• Мichael М. Slepchenkov

Beilstein J. Nanotechnol. 2018, 9, 1321–1327, doi:10.3762/bjnano.9.125

• the hybrid nanocomposite were approximately equal for both metallic and semiconductor nanotubes. Keywords: absorption coefficient; 2D CNT–graphene hybrid nanocomposite; optical conductivity; optical nanodevices; topological models; Findings The applicability of graphene hybrid nanocomposites in the

• field of optical communications has been hinted to by the active research for the last six years, in which the unique properties of these hybrid nanocomposites as electro-optic materials for optical modulators of different types has been demonstrated [1][2][3][4]. One of the newest and hitherto only

• the SCC DFTB2 method. Figure 3 and Figure 4 show the spectra of the real and imaginary parts of the diagonal elements of the surface conductivity tensor for four topological models of 2D CNT–graphene hybrid nanocomposites with an intertube distance of 13 hexagons and four types of CNTs. An analysis of

Ag₂WO₄ nanorods decorated with AgI nanoparticles: Novel and efficient visible-light-driven photocatalysts for the degradation of water pollutants

• Shijie Li,
• Shiwei Hu,
• Wei Jiang,
• Yanping Liu,
• Yu Liu,
• Yingtang Zhou,
• Liuye Mo and
• Jianshe Liu

Beilstein J. Nanotechnol. 2018, 9, 1308–1316, doi:10.3762/bjnano.9.123

• photocatalytic performance. Keywords: AgI/Ag2WO4; nanocomposites; photocatalysis; visible light; Introduction The development of high-performance novel photocatalysts for the degradation of pollutants has received great interest due to the worsening of environmental pollution [1][2][3][4][5][6][7][8][9][10][11

Electrodeposition of reduced graphene oxide with chitosan based on the coordination deposition method

• Mingyang Liu,
• Yanjun Chen,
• Chaoran Qin,
• Zheng Zhang,
• Shuai Ma,
• Xiuru Cai,
• Xueqian Li and
• Yifeng Wang

Beilstein J. Nanotechnol. 2018, 9, 1200–1210, doi:10.3762/bjnano.9.111

• ) nanocomposites have also gained growing interest in the development of advanced materials [6][7][8]. The electrodeposition technique has drawn extensive attention lately since it offers an effective convergent method to integrate biology with microelectronics to build the bio-device interface, which enables

• physical and electrochemical properties. In addition, there are great advantages in the use of graphene and graphene-based nanocomposites for the fabrication of electrochemical sensors with enhanced detection performance [39]. It has been reported that graphene-based materials can be enlisted for the

Single-crystalline FeCo nanoparticle-filled carbon nanotubes: synthesis, structural characterization and magnetic properties

• Rasha Ghunaim,
• Maik Scholz,
• Christine Damm,
• Bernd Rellinghaus,
• Rüdiger Klingeler,
• Bernd Büchner,
• Michael Mertig and
• Silke Hampel

Beilstein J. Nanotechnol. 2018, 9, 1024–1034, doi:10.3762/bjnano.9.95

• nanomaterials. At the same time, this ratio constitutes a major challenge, as a large surface area can trigger rapid oxidation, especially in metallic nanoscale objects [5]. The possibility to fabricate nanomaterials and nanocomposites opens the door to numerous applications in multidisciplinary fields, such as

• via capillary force [38][39][40]. Due to the attractive properties of Fe–Co nanoparticles, this work is directed towards the synthesis of CNT-based nanocomposites of Fe–Co based on a post-synthesis method, in which prefabricated multiwalled CNTs (MWCNTs) are used as templates. Two facile filling

Nanoscale mapping of dielectric properties based on surface adhesion force measurements

• Ying Wang,
• Yue Shen,
• Xingya Wang,
• Zhiwei Shen,
• Bin Li,
• Jun Hu and
• Yi Zhang

Beilstein J. Nanotechnol. 2018, 9, 900–906, doi:10.3762/bjnano.9.84

• : adhesion; atomic force microscopy (AFM); graphene oxide (GO); nanoscale dielectric properties; reduced graphene oxide (RGO); Introduction The local dielectric distribution is a key factor that influences the physical properties and functionalities of various materials such as polymer nanocomposites [1][2

Facile synthesis of a ZnO–BiOI p–n nano-heterojunction with excellent visible-light photocatalytic activity

• Mengyuan Zhang,
• Jiaqian Qin,
• Pengfei Yu,
• Bing Zhang,
• Mingzhen Ma,
• Xinyu Zhang and
• Riping Liu

Beilstein J. Nanotechnol. 2018, 9, 789–800, doi:10.3762/bjnano.9.72

• Zn/Bi, the morphology varies from nanoplates, flowers to nanoparticles. The heterojunction formed between ZnO and BiOI decreases the recombination rate of photogenerated carriers and enhances the photocatalytic activity of ZnO/BiOI composites. The obtained ZnO/BiOI heterostructured nanocomposites

• indicated that the ZnO/BiOI heterostructured nanocomposites not only exhibit remarkably enhanced and sustainable photocatalytic activity, but also show good recyclability. The excellent photocatalytic activity could be attributed to the high separation efficiency of the photoinduced electron–hole pairs as

• NH4HCO3 can homogenize the constituent in a relatively smaller range of pH. By tuning the ratio of Zn/Bi, the morphology, which also plays a vital role in photocatalytic dye degradation, varied from nanoplates, to flowers to nanoparticles. The obtained ZnO/BiOI heterostructured nanocomposites showed a

Perovskite-structured CaTiO₃ coupled with g-C₃N₄ as a heterojunction photocatalyst for organic pollutant degradation

• Ashish Kumar,
• Christian Schuerings,
• Suneel Kumar,
• Ajay Kumar and
• Venkata Krishnan

Beilstein J. Nanotechnol. 2018, 9, 671–685, doi:10.3762/bjnano.9.62

• heterojunctions are of great interest in the photocatalysis domain for achieving environmental sustainability [10][11]. These nanocomposites are known for their greater photogenerated electron–hole mobility across the heterojunction interface, which reduces the distance and time of charge transport to impede

• 2D–2D nanocomposites could effectively improve the specific surface area and provide abundant reaction sites to adsorb reactant species on their surface, which can significantly enhance the photocatalytic activity [15][16]. Recently, graphitic carbon nitride (g-C3N4), which is a metal-free polymeric

Facile phase transfer of gold nanorods and nanospheres stabilized with block copolymers

• Yaroslav I. Derikov,
• Georgiy A. Shandryuk,
• Raisa V. Talroze,
• Alexander A. Ezhov and
• Yaroslav V. Kudryavtsev

Beilstein J. Nanotechnol. 2018, 9, 616–627, doi:10.3762/bjnano.9.58

• toluene. Thermostability is known to be one of the critical issues for gold-containing nanocomposites. As reported in [53], polyvinylpyrrolidone-stabilized Au nanorods of 73 ± 4 nm length and 3.3 ± 0.3 aspect ratio are gradually transformed into spheres in the temperature range of 100–250 °C. At 150 °C

Anchoring Fe₃O₄ nanoparticles in a reduced graphene oxide aerogel matrix via polydopamine coating

• Błażej Scheibe,
• Radosław Mrówczyński,
• Natalia Michalak,
• Karol Załęski,
• Michał Matczak,
• Mateusz Kempiński,
• Zuzanna Pietralik,
• Mikołaj Lewandowski,
• Stefan Jurga and
• Feliks Stobiecki

Beilstein J. Nanotechnol. 2018, 9, 591–601, doi:10.3762/bjnano.9.55

• linked covalently [40]. Recently, scientific attention was turned to PDA nanocomposites, including those with GO and magnetite [41]. However, there are no reports related to the formation of hybrid aerogels based on the aforementioned compounds. In this work, GO-based aerogels with embedded PDA-coated

Ultralight super-hydrophobic carbon aerogels based on cellulose nanofibers/poly(vinyl alcohol)/graphene oxide (CNFs/PVA/GO) for highly effective oil–water separation

• Zhaoyang Xu,
• Huan Zhou,
• Sicong Tan,
• Xiangdong Jiang,
• Weibing Wu,
• Jiangtao Shi and
• Peng Chen

Beilstein J. Nanotechnol. 2018, 9, 508–519, doi:10.3762/bjnano.9.49

• ]. Therefore, CNFs can potentially be an excellent nanofiber for high-performance polymer nanocomposites, thereby presenting unprecedented opportunities for the development of durable engineering materials from a renewable resource for structural, consumer, and medical applications [11][12]. There is a long