Properties of tin oxide films grown by atomic layer deposition from tin tetraiodide and ozone

• Kristjan Kalam,
• Peeter Ritslaid,
• Tanel Käämbre,
• Aile Tamm and
• Kaupo Kukli

Beilstein J. Nanotechnol. 2023, 14, 1085–1092, doi:10.3762/bjnano.14.89

• have been studied from many perspectives. For example, one can mention anodes for Li-ion batteries [1], gas sensors [2], catalytic activities [3], and stable buffer [4] or base [5] layers in solar cells. More applications can be found, when SnO2 is considered as constituent of a nanostructure or a

• nanocomposite layer. ZrO2–SnO2 stacked layers have been shown to perform as mechanically elastic and magnetizable films [6]. SnO2-coated carbon nanotubes have been studied as catalysts [7] and ZnO–SnO2 as functional composite in Li-ion batteries [8]. A recent review article from 2022 lists 27 different

Spatial mapping of photovoltage and light-induced displacement of on-chip coupled piezo/photodiodes by Kelvin probe force microscopy under modulated illumination

• Zeinab Eftekhari,
• Nasim Rezaei,
• Hidde Stokkel,
• Jian-Yao Zheng,
• Andrea Cerreta,
• Ilka Hermes,
• Minh Nguyen,
• Guus Rijnders and
• Rebecca Saive

Beilstein J. Nanotechnol. 2023, 14, 1059–1067, doi:10.3762/bjnano.14.87

• finalized by etching circular holes from the backside of the wafer to obtain thin membranes. The sizes of these holes were defined by applying and patterning a photoresist on the backside of the wafer, which was then anisotropically etched by deep reactive ion etching (DRIE) using SF6, O2, and C4F8 gases

Recognition mechanisms of hemoglobin particles by monocytes – CD163 may just be one

• Jonathan-Gabriel Nimz,
• Pichayut Rerkshanandana,
• Chiraphat Kloypan,
• Ulrich Kalus,
• Saranya Chaiwaree,
• Axel Pruß,
• Radostina Georgieva,
• Yu Xiong and
• Hans Bäumler

Beilstein J. Nanotechnol. 2023, 14, 1028–1040, doi:10.3762/bjnano.14.85

• = dilution factor (2.1); molar mass of Hb (tetrameric) = 64.5; (monomer) molar extinction coefficient (ε) = 6.945). Percentage of functional hemoglobin Each hemoglobin molecule contains an Fe2+ ion on which the ability of Hb to bind oxygen is based. Methemoglobin has undergone an oxidation process. The

• central iron ion is trivalent, and the Hb derivative has lost its ability to bind oxygen. Therefore, only bivalent Hb is functional. The “oxygen release method” was used to determine the percentage of functional hemoglobin, as previously described in detail by Kloypan and co-workers [33]. In brief, the

Exploring internal structures and properties of terpolymer fibers via real-space characterizations

• Michael R. Roenbeck and
• Kenneth E. Strawhecker

Beilstein J. Nanotechnol. 2023, 14, 1004–1017, doi:10.3762/bjnano.14.83

• investigated the processing and properties of high-performance terpolymer fibers, much remains to be understood about the internal nano- and microstructures of these fibers, and how these morphologies relate to fiber properties. Here we use a focused ion beam notch technique and multifrequency atomic force

• features at different length scales and verify the applicability of analytical structural models used to date. Over the last several years, a “focused ion beam (FIB) notch” technique has been developed and employed to address these gaps in understanding of the internal structures of fibers such as Kevlar

• chamber [9]. Kevlar® K29 fibers also discussed in this report underwent the same preparation techniques. Focused ion beam notching Conductively coated fibers were cut with a FIB as discussed in detail in an earlier study [9]. In summary, 2–3 μm wide through-cuts were notched into each fiber (Figure 1b

Fragmentation of metal(II) bis(acetylacetonate) complexes induced by slow electrons

• Janina Kopyra and
• Hassan Abdoul-Carime

Beilstein J. Nanotechnol. 2023, 14, 980–987, doi:10.3762/bjnano.14.81

• fragmentation arises from a resonant mechanism known as dissociative electron attachment (DEA) producing exclusively a negative fragment ion and one or more neutral counterparts, as it will be discussed below. The contribution of each of the processes may depend on the nature of the organometallic precursors

• summarizes all the observed anion products. As the anion yields shown below in Figures 1–6 show structures characteristic of resonant mechanisms, Table 1 also reports the peak positions of the fragment anions and their branching ratios derived by integration of the ion yield over the respective peaks. At the

• incoming scattering electron is captured by the precursor molecule to form a transient negative ion, TNI or [ML2]#−. If the electron autodetachment time of the TNI is longer than the dissociation time, the transient anion undergoes dissociation into a negative fragment and one or more neutral counterpart(s

Isolation of cubic Si₃P₄ in the form of nanocrystals

• Polina K. Nikiforova,
• Sergei S. Bubenov,
• Vadim B. Platonov,
• Andrey S. Kumskov,
• Nikolay N. Kononov,
• Tatyana A. Kuznetsova and
• Sergey G. Dorofeev

Beilstein J. Nanotechnol. 2023, 14, 971–979, doi:10.3762/bjnano.14.80

• precursor for diffusion doping of wafers and as anode material for Li-ion batteries. A similar method with a hydrogenation step offers the possibility to obtain other compounds, such as silicon selenides, arsenides, and sulfides. Keywords: ampoule annealing; defective zinc blende structure; DFT

• number of potential benefits to both science and industry. These methods often employ new strategies for the synthesis of specific classes of substances. For example, the widely known development of perovskite synthesis through ion exchange reactions has attracted attention in scientific as well as

• ) Si3P4 to be energetically favored [9][10][11][12][13][14]. The calculated lattice constant a and the ratio c/a lie within the ranges of 4.961–5.093 Å and 0.994–1.003, respectively. Among the properties of silicon-based materials, one may note a high specific capacity, which is crucial for Li-ion

Metal-organic framework-based nanomaterials for CO₂ storage: A review

• Ha Huu Do,
• Iqra Rabani and
• Hai Bang Truong

Beilstein J. Nanotechnol. 2023, 14, 964–970, doi:10.3762/bjnano.14.79

• the linker molecules but have also involved the metal ions. For example, Lau et al. used an ion exchange strategy to boost the amount of adsorbed CO2 in UiO-66 (Figure 4) [38]. After replacing approximately 50% of the Zr4+ ions in UiO-66 with Ti4+, a significant increase in CO2 adsorption capacity (81

• view of the channels displaying the cylindrical pores. Figure 3 was reprinted with permission from [34]. Copyright 2015 American Chemical Society. This content is not subject to CC BY 4.0. Graphic illustration of the ion exchange by Ti(IV) in UiO-66. Figure 4 was republished with permission of The

Ni, Co, Zn, and Cu metal-organic framework-based nanomaterials for electrochemical reduction of CO₂: A review

• Ha Huu Do and
• Hai Bang Truong

Beilstein J. Nanotechnol. 2023, 14, 904–911, doi:10.3762/bjnano.14.74

• metal ion doping in ZIF-8, aiming to enhance the performance of CO2 conversion, as recently reported (Figure 4a). Cho et al. revealed that Cu-doped ZIF-8 exhibited the highest catalytic activity, surpassing both Fe- and Ni-doped ZIF-8 [44]. Specifically, Cu0.5Zn0.5/ZIF-8 yielded a large FECO of 88.5% at

• /by/4.0/). (a) A graphic representation of the preparation of MzZny/ZIF-8, (b) Faradaic efficiency for the CO production using different materials, (c) diagram of free energy for CO2RR. Figure 4 was adapted from [44], J. H. Cho et al., “Transition Metal Ion Doping on ZIF-8 Enhances the Electrochemical

Ultralow-energy amorphization of contaminated silicon samples investigated by molecular dynamics

• Grégoire R. N. Defoort-Levkov,
• Alan Bahm and
• Patrick Philipp

Beilstein J. Nanotechnol. 2023, 14, 834–849, doi:10.3762/bjnano.14.68

• , Luxembourg Thermo Fisher Scientific, Hillsboro, OR, 97124, USA 10.3762/bjnano.14.68 Abstract Ion beam processes related to focused ion beam milling, surface patterning, and secondary ion mass spectrometry require precision and control. Quality and cleanliness of the sample are also crucial factors

• . Furthermore, several domains of nanotechnology and industry use nanoscaled samples that need to be controlled to an extreme level of precision. To reduce the irradiation-induced damage and to limit the interactions of the ions with the sample, low-energy ion beams are used because of their low implantation

• depths. Yet, low-energy ion beams come with a variety of challenges. When such low energies are used, the residual gas molecules in the instrument chamber can adsorb on the sample surface and impact the ion beam processes. In this paper we pursue an investigation on the effects of the most common

Silver nanoparticles loaded on lactose/alginate: in situ synthesis, catalytic degradation, and pH-dependent antibacterial activity

• Nguyen Thi Thanh Tu,
• T. Lan-Anh Vo,
• T. Thu-Trang Ho,
• Kim-Phuong T. Dang,
• Van-Dung Le,
• Phan Nhat Minh,
• Chi-Hien Dang,
• Vinh-Thien Tran,
• Van-Su Dang,
• Tran Thi Kim Chi,
• Hieu Vu-Quang,
• Radek Fajgar,
• Thi-Lan-Huong Nguyen,
• Van-Dat Doan and
• Thanh-Danh Nguyen

Beilstein J. Nanotechnol. 2023, 14, 781–792, doi:10.3762/bjnano.14.64

• values up to 140 min. Throughout the synthesis process, the λmax values showed a slight increase, which confirms the critical role of reaction time in the synthesis of stable nanocomposites. To assess the impact of silver ion concentration, ratios of silver ions to gel in the range of 0.1–0.7 (w/w) were

• in the absorbance value in the UV–vis spectra. Minor changes in λmax values were noted from the absorption data, indicating a slight influence of the silver-ion-to-nanocomposite ratio on the physicochemical properties of the synthesized AgNPs. Considering these findings, two ratios of silver ions to

• (left) and plots of absorbance and wavelength (λmax) data (right) recorded as a function of temperature (A and B), reaction time (C and D) and the ratio of silver ion to blank Lac/Alg (E and F). Zeta potentials (A) and size distribution obtained from DLS measurements (B) of AgNPs@Lac/Alg with different

In situ magnesiothermic reduction synthesis of a Ge@C composite for high-performance lithium-ion batterie anodes

• Ha Tran Huu,
• Ngoc Phi Nguyen,
• Vuong Hoang Ngo,
• Huy Hoang Luc,
• Minh Kha Le,
• Minh Thu Nguyen,
• My Loan Phung Le,
• Hye Rim Kim,
• In Young Kim,
• Sung Jin Kim,
• Van Man Tran and
• Vien Vo

Beilstein J. Nanotechnol. 2023, 14, 751–761, doi:10.3762/bjnano.14.62

• report an in situ magnesiothermic reduction to synthesize a composite of Ge@C as an anode material for lithium-ion batteries. The obtained electrode delivered a specific capacity of 454.2 mAh·g−1 after 200 cycles at a specific current of 1000 mA·g−1. The stable electrochemical performance and good rate

• contact formation during in situ synthesis. Keywords: Ge anode; in situ synthesis; lithium-ion batteries; magnesiothermic reduction; Introduction The significantly increasing energy consumption leads to the exhaustion of fossil fuel sources such as coal, oil, and natural gas. Additionally, there are

• number of electric vehicles (EVs) [5][6]. The most important component of EVs are suitable energy storage systems, the further development of which will be key to a more widespread use of this kind of transportation [7]. Commercialized first by Sony company, lithium-ion batteries (LIBs) and related

The microstrain-accompanied structural phase transition from h-MoO₃ to α-MoO₃ investigated by in situ X-ray diffraction

• Zeqian Zhang,
• Honglong Shi,
• Boxiang Zhuang,
• Minting Luo and
• Zhenfei Hu

Beilstein J. Nanotechnol. 2023, 14, 692–700, doi:10.3762/bjnano.14.55

• , making them multifunctional electronic and optical materials for applications in ion batteries [3][4], lubricants [5], gas detectors [6][7], photochromism [8][9], photocatalysis [10][11], and superconductors [12][13]. The molybdenum oxide MoO3 can crystalize into several structures, including α-MoO3 [14

Metal-organic framework-based nanomaterials as opto-electrochemical sensors for the detection of antibiotics and hormones: A review

• Akeem Adeyemi Oladipo,
• Saba Derakhshan Oskouei and
• Mustafa Gazi

Beilstein J. Nanotechnol. 2023, 14, 631–673, doi:10.3762/bjnano.14.52

• more accessible excited states of the ligand to the suitable metal energy level. The “antenna effect”, which is the name given to this coupling, causes a significant rise in luminescence [85]. Particularly, the lanthanide ion emits its distinctive luminescence as a result of being indirectly activated

• behaviour [86]. The metal ion can have different levels of impact on the emission depending on the electronic structure of the metal and the relative energy of the metal and linker orbitals. To develop luminescent MOFs, a variety of transition metals have also been combined with different ligands. Note that

Nanoarchitectonics to entrap living cells in silica-based systems: encapsulations with yolk–shell and sepiolite nanomaterials

• Celia Martín-Morales,
• Jorge Fernández-Méndez,
• Pilar Aranda and
• Eduardo Ruiz-Hitzky

Beilstein J. Nanotechnol. 2023, 14, 522–534, doi:10.3762/bjnano.14.43

• culture medium and used immediately for gel synthesis. In parallel, the gel precursor was prepared from 37% (v/v) commercial sodium silicate, which was ion-exchanged using a custom-made acidic ion exchange column. After ion exchange, the resulting silica precursor was mixed with LUDOX® TMA silica

Mixed oxides with corundum-type structure obtained from recycling can seals as paint pigments: color stability

• Dienifer F. L. Horsth,
• Julia de O. Primo,
• Nayara Balaba,
• Fauze J. Anaissi and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2023, 14, 467–477, doi:10.3762/bjnano.14.37

• assignment is based on the intrinsic light absorption characteristics of the pigment due to the presence of a chromophore ion [8]. Different transition metals such as V, Cr, Mn, Fe, Co, Ni, and Cu have been used for this purpose [9]. Using inorganic compounds in the synthesis tends to increase the chemical

• to use chromium as a coloring ion to obtain the same color result, without using toxic precursors. Remarkably, iron oxide red belongs to the class of yellow, red, and brown ocher, whose color depends on the crystallographic phase [11]. The hematite phase (α-Fe2O3) is the most stable, and its shade

• band from 600 nm. Reflection bands become more pronounced and defined with increasing colorant ion concentration (Figure S4, Supporting Information File 1). Pigment application Colorimetry The colorimetric parameters of the samples after dispersion in commercial white paint and application on plaster

Evaluation of electrosynthesized reduced graphene oxide–Ni/Fe/Co-based (oxy)hydroxide catalysts towards the oxygen evolution reaction

• Karolina Cysewska,
• Marcin Łapiński,
• Marcin Zając,
• Jakub Karczewski,
• Piotr Jasiński and
• Sebastian Molin

Beilstein J. Nanotechnol. 2023, 14, 420–433, doi:10.3762/bjnano.14.34

• slopes reveal a similar trend as the OER η: the higher Qdep of NiFe in NiFe-GO, the lower the slope (valid for Qdep < 200 mC). Any change or deterioration of the OER catalytic activity of NiFe-GO for Qdep > 200 mC may be due to the overgrow of deposited NiFe, which begins to block the ion and electron

• of the catalyst surface and the ion and electron transport became inhibited. The value of Cdl/ECSA for NiFe-GO(100–300 mC) progressively increased as the deposition charge of GO in NiFe-GO increased, which was a different trend compared to NiFe(50–300 mC)-GO. Because of this, the data indicate that

New trends in nanobiotechnology

• Pau-Loke Show,
• Kit Wayne Chew,
• Wee-Jun Ong,
• Sunita Varjani and
• Joon Ching Juan

Beilstein J. Nanotechnol. 2023, 14, 377–379, doi:10.3762/bjnano.14.32

• properties associated with the process and yielded products are highlighted. The self-assembly methods in focus included single amino acid self-assembly, functional amino acid self-assembly, amino acid and metal ion coordination self-assembly, and amino acid regulatory functional molecule self-assembly. Many

Nanotechnology – a robust tool for fighting the challenges of drug resistance in non-small cell lung cancer

• Filip Gorachinov,
• Fatima Mraiche,
• Diala Alhaj Moustafa,
• Ola Hishari,
• Yomna Ismail,
• Jensa Joseph,
• Maja Simonoska Crcarevska,
• Marija Glavas Dodov,
• Nikola Geskovski and
• Katerina Goracinova

Beilstein J. Nanotechnol. 2023, 14, 240–261, doi:10.3762/bjnano.14.23

• targeting. Transient PEGylation facilitates not only the localization and interaction with the target cell but also improves ion pair formation between the ionizable lipid (which will become cationic at pH 4) and the anionic endogenous endosomal phospholipids. This will enable the fast release of the

A novel approach to pulsed laser deposition of platinum catalyst on carbon particles for use in polymer electrolyte membrane fuel cells

• Bogusław Budner,
• Wojciech Tokarz,
• Sławomir Dyjak,
• Andrzej Czerwiński,
• Bartosz Bartosewicz and
• Bartłomiej Jankiewicz

Beilstein J. Nanotechnol. 2023, 14, 190–204, doi:10.3762/bjnano.14.19

• [27]. Direct deposition of PtNPs can be attained by the use of various physical vapor deposition techniques such as magnetron sputtering [28], sputtering [29], e-beam evaporation [30], dual ion-beam assisted deposition [31], and pulsed laser deposition (PLD) [27][32][33]. Previously, PLD has been used

• ™ (1100 e.w., Ion Power Inc., United States) by ultrasonic mixing. The ratio of the ionomer to the studied Pt-based catalyst mass in a dry electrode was 0.1. The disc-ring electrode surfaces were polished and checked for purity before applying the catalyst layer by cyclic voltammetry in a 0.5 M H2SO4

• W, Cole-Parmer, United States) impulse sonication with 150 W energy for approximately 1 min by mixing Pt-coated carbon material, 5% alcohol suspension of Nafion (1100 e.w., Ion Power, United States) and double distilled water. The suspension was prepared in an airtight tube cooled with ice. The

High–low Kelvin probe force spectroscopy for measuring the interface state density

• Ryo Izumi,
• Masato Miyazaki,
• Yan Jun Li and
• Yasuhiro Sugawara

Beilstein J. Nanotechnol. 2023, 14, 175–189, doi:10.3762/bjnano.14.18

• show that the analysis of electrostatic forces in the depletion region at high- and low-frequency AC bias voltages provides information about the interface state density in the semiconductor bandgap. As a preliminary experiment, high-low KPFS measurements were performed on ion-implanted silicon

Combining physical vapor deposition structuration with dealloying for the creation of a highly efficient SERS platform

• Adrien Chauvin,
• Walter Puglisi,
• Damien Thiry,
• Cristina Satriano,
• Rony Snyders and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2023, 14, 83–94, doi:10.3762/bjnano.14.10

• studied. For this purpose, two other solutions were selected (i.e., H3PO4 and NaOH). Undoubtedly, anions play an important role during the dealloying process due to the intricate reaction between anions and Ag or Al [47][48]. It has been reported that during dealloying in HCl, the Cl− ion accelerates the

Upper critical magnetic field in NbRe and NbReN micrometric strips

• Zahra Makhdoumi Kakhaki,
• Antonio Leo,
• Federico Chianese,
• Loredana Parlato,
• Giovanni Piero Pepe,
• Angela Nigro,
• Carla Cirillo and
• Carmine Attanasio

Beilstein J. Nanotechnol. 2023, 14, 45–51, doi:10.3762/bjnano.14.5

• voltage contacts of L = 90 μm. The NbReN films were structured by using direct laser writer exposure followed by argon ion etching into constriction-type bridges with w = 2 μm and L = 700 μm. Further details on the fabrication procedure of the films are reported elsewhere [4][8]. The superconducting

Observation of collective excitation of surface plasmon resonances in large Josephson junction arrays

• Roger Cattaneo,
• Mikhail A. Galin and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2022, 13, 1578–1588, doi:10.3762/bjnano.13.132

• using photolithography and reactive ion etching. The JJ sensor with variable thickness and a width of ≈100 nm is made by Ga+ focused ion beam etching. The JJ is made small in order to increase its resistance Rn to approx. 50 Ω, which is needed for a good impedance matching with the antenna. In order to

Utilizing the surface potential of a solid electrolyte region as the potential reference in Kelvin probe force microscopy

• Nobuyuki Ishida

Beilstein J. Nanotechnol. 2022, 13, 1558–1563, doi:10.3762/bjnano.13.129

• electrode placed on a solid electrolyte (Li-ion conductor) substrate. The surface-potential distribution in the region across the solid electrolyte was measured with a DC voltage applied between the Au electrodes. During the KPFM measurements, the potential of each Au electrodes relative to the Li electrode

• toward the negatively biased electrode, resulting in an ionic current flow. The ion current decays with time and, in principle, becomes zero when the electric field in the solid electrolyte is shielded by the accumulation and depletion of Li ions. Before starting each KPFM measurement, we waited 2–4 min

• electrolyte sample was a Li-ion conducting glass ceramic purchased from OHARA Inc. (LICGCTM AG-01) [20]. The size and thickness of the substrate were 25.4 mm × 25.4 mm and 150 μm, respectively. The main crystalline phase was Li1+x+yAlx(Ti,Ge)2−xSiyP3−yO12 [20]. The substrate was cut into pieces of

Non-stoichiometric magnetite as catalyst for the photocatalytic degradation of phenol and 2,6-dibromo-4-methylphenol – a new approach in water treatment

• Joanna Kisała,
• Anna Tomaszewska and
• Przemysław Kolek

Beilstein J. Nanotechnol. 2022, 13, 1531–1540, doi:10.3762/bjnano.13.126

• for photocatalysis (11 × 10−3 min−1 for M1 and 6.2 × 10−3 min−1 for M2), a higher kapp value can be observed for ozonolysis. As shown in Figure 6, bromide ions were released from the benzene ring by the ozonation reaction. The bromide ion concentration increased with an increasing level of degradation

• bromide; Figure 6). However, a normalized bromide ion concentration smaller than 0.5 for ozonolysis may denote the production of brominated organic by-products. Release yields of bromine in the form of bromide ions as high as 90% showed eventual mineralization. The half-live of DBMP in photocatalytic

• 1 × 10−4 to 1 × 10−2 mol·L−1 were used to quantify PhOH and DBMP. The concentration of dissolved bromide ions was determined potentiometrically with a bromide ion-selective electrode (EBr-01, Hydromet, Poland) with a silver chloride electrode (RL-100, Hydromet, Poland) as a reference electrode and a