Effects of focused electron beam irradiation parameters on direct nanostructure formation on Ag surfaces

• Jānis Sniķeris,
• Vjačeslavs Gerbreders,
• Andrejs Bulanovs and
• Ēriks Sļedevskis

Beilstein J. Nanotechnol. 2022, 13, 1004–1010, doi:10.3762/bjnano.13.87

• material greatly affects the growth rate of the nanowires, with the Cu surface providing the fastest growth. Energy-dispersive X-ray spectroscopy (EDX) revealed the presence of both carbon and substrate materials in the nanowires. The effect of substrate material on nanowire growth rate could be attributed

Theoretical investigations of oxygen vacancy effects in nickel-doped zirconia from ab initio XANES spectroscopy at the oxygen K-edge

• Dick Hartmann Douma,
• Lodvert Tchibota Poaty,
• Alessio Lamperti,
• Stéphane Kenmoe,
• Abdulrafiu Tunde Raji,
• Alberto Debernardi and
• Bernard M’Passi-Mabiala

Beilstein J. Nanotechnol. 2022, 13, 975–985, doi:10.3762/bjnano.13.85

• and magnetic order in a typical diluted magnetic oxide. Such a finding may be crucial for spintronics-related applications. Keywords: defect; ligand field; nickel; oxidation state; oxides; spectroscopy; spintronics; vacancy; X-ray absorption; X-ray absorption near-edge structure (XANES); zirconia

• which is being currently employed in ultra-scaled electronics for its high dielectric constant [24][25] have received significant attention because of its practical applications. Thus, recently, exploiting first principles simulations and X-ray absorption near edge spectroscopy (XANES) in high magnetic

• photoelectron spectroscopy (XPS) [26], XANES spectra [27], and synchrotron radiation measurements [4], where it was suggested that for every two dopant atoms of Fe in zirconia, one single O vacancy is created. It is, thus, expected that in similarity to the effect of Fe doping in zirconia, substitutional Ni in

Solar-light-driven LaFe_xNi_1−xO₃ perovskite oxides for photocatalytic Fenton-like reaction to degrade organic pollutants

• Chao-Wei Huang,
• Shu-Yu Hsu,
• Jun-Han Lin,
• Yun Jhou,
• Wei-Yu Chen,
• Kun-Yi Andrew Lin,
• Yu-Tang Lin and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 882–895, doi:10.3762/bjnano.13.79

• . The UV–vis absorption capability with diffuse reflectance spectroscopy (DRS) and photographs of various LaFexNi1−xO3 perovskite oxides with different proportions were shown in Figure 5a and 5b. Except for LaFeO3, which was brown, the rest of the perovskite oxides doped with Ni became black. Since

• microscopy (FESEM). The light absorption spectra of the perovskite oxides were inspected using V-670 (Jasco, Japan) to examine the UV–vis absorption capability with diffuse reflectance spectroscopy (DRS) from 200 to 800 nm. The nitrogen adsorption–desorption analyzer, ASAP 2020 PLUS (ASAP, USA), was applied

Self-assembly of C₆₀ on a ZnTPP/Fe(001)–p(1 × 1)O substrate: observation of a quasi-freestanding C₆₀ monolayer

• Guglielmo Albani,
• Michele Capra,
• Alessandro Lodesani,
• Alberto Calloni,
• Gianlorenzo Bussetti,
• Marco Finazzi,
• Franco Ciccacci,
• Alberto Brambilla,
• Lamberto Duò and
• Andrea Picone

Beilstein J. Nanotechnol. 2022, 13, 857–864, doi:10.3762/bjnano.13.76

• tunneling microscopy/spectroscopy and ultraviolet photoemission spectroscopy. C60 nucleates compact and well-ordered hexagonal domains on top of the ZnTPP buffer layer, suggesting a high surface diffusivity of C60 and a weak coupling between the overlayer and the substrate. Accordingly, work function

• spectroscopy; ZnTPP; Introduction Vertical heterostructures composed by organic molecules interfaced with metallic substrates have been the subject of intense experimental and theoretical investigation during the last two decades [1][2][3]. The interest in these hybrid systems has been boosted by their

• W tips. Scanning tunneling spectroscopy (STS) data, that is, dI/dV curves for the investigation of the sample density of states (DOS), have been collected at room temperature, using a lock-in amplifier with a modulation amplitude of 60 mV. All STM and STS measurements have been carried out while

Ultrafast signatures of magnetic inhomogeneity in Pd_1−xFe_x (x ≤ 0.08) epitaxial thin films

• Andrey V. Petrov,
• Sergey I. Nikitin,
• Lenar R. Tagirov,
• Amir I. Gumarov,
• Igor V. Yanilkin and
• Roman V. Yusupov

Beilstein J. Nanotechnol. 2022, 13, 836–844, doi:10.3762/bjnano.13.74

• Abstract A series of Pd1−xFex alloy epitaxial films (x = 0, 0.038, 0.062, and 0.080), a material promising for superconducting spintronics, was prepared and studied with ultrafast optical and magneto-optical laser spectroscopy in a wide temperature range of 4–300 K. It was found that the transition to the

• state in the Pd1−xFex alloy at low temperatures is about 7–8 atom %. Keywords: magnetic inhomogeneities; PdFe alloy; thin epitaxial films; time-resolved magneto-optical Kerr effect; time-resolved optical spectroscopy; Introduction Superconductor-based technologies are promising for exaflop-scale

• iron at which the alloy would become magnetically homogeneous. This requires a method for detecting magnetic inhomogeneities, preferably with the possibility of being applied to thin films. We propose the use of ultrafast, time-resolved optical and magneto-optical spectroscopy methods for probing

Temperature and chemical effects on the interfacial energy between a Ga–In–Sn eutectic liquid alloy and nanoscopic asperities

• Yujin Han,
• Pierre-Marie Thebault,
• Corentin Audes,
• Xuelin Wang,
• Haiwoong Park,
• Jian-Zhong Jiang and
• Arnaud Caron

Beilstein J. Nanotechnol. 2022, 13, 817–827, doi:10.3762/bjnano.13.72

• interfacial energies between a eutectic Ga–In–Sn liquid alloy and single nanoscopic asperities of SiOx, Au, and PtSi have been determined in the temperature range between room temperature and 90 °C by atomic force spectroscopy. For all asperities used here, we find that the interfacial tension of the eutectic

• spectroscopy to determine the interfacial energy between eutectic Ga–In–Sn liquid alloy and single nanoscopic asperities of SiOx, Au, and PtSi in the temperature range between room temperature and 90 °C. The choice of the asperity materials was motivated by their relevance in electronics and micro

• -/nanotechnology. The surface chemical composition of the liquid alloy was measured by X-ray photoelectric spectroscopy before and after heating to 100 °C for 3 h. Furthermore, we imaged the nanoscopic asperities after measurements on the metallic liquid alloy by SEM to evidence possible liquid residues. For all

Optimizing PMMA solutions to suppress contamination in the transfer of CVD graphene for batch production

• Chun-Da Liao,
• Andrea Capasso,
• Tiago Queirós,
• Telma Domingues,
• Fatima Cerqueira,
• Nicoleta Nicoara,
• Jérôme Borme,
• Paulo Freitas and
• Pedro Alpuim

Beilstein J. Nanotechnol. 2022, 13, 796–806, doi:10.3762/bjnano.13.70

• average molecular weight (AMW) and weight concentration in anisole, to be deposited by spin coating. Optical microscopy and Raman spectroscopy showed that the amount of PMMA residues on transferred graphene is proportional to the AMW and concentration in the solvent. At the same time, the mechanical

• that the PMMA mixture features good mechanical strength and cleanness (i.e., the acetone bath can thoroughly remove it). The transferred graphene samples were investigated via Raman spectroscopy to evaluate crystallinity, layer number, and structural defect level [23]. The relative intensities of the G

• crystals were transferred using PMMA with different AMWs and weight percentages in anisole. Repeated transfer cycles among water baths revealed, as expected, that PMMA with higher AMW and weight percentage allowed for a better mechanical support to graphene. Optical microscopy, Raman spectroscopy, and XPS

Hierarchical Bi₂WO₆/TiO₂-nanotube composites derived from natural cellulose for visible-light photocatalytic treatment of pollutants

• Zehao Lin,
• Zhan Yang and
• Jianguo Huang

Beilstein J. Nanotechnol. 2022, 13, 745–762, doi:10.3762/bjnano.13.66

• (FTIR) spectra of the samples were recorded on the Nicolet iS10 spectrometer. The X-ray photoelectron spectroscopy (XPS) experiment was performed on the Thermo Scientific ESCALAB 250Xi spectrometer equipped with an Al Kα X-ray source at an energy value of 1486.6 eV. The XPS spectra were calibrated by

• , respectively. The transient photocurrent responses and electrochemical impedance spectroscopy (EIS) Nyquist plots (frequency: 0.01 Hz−100 kHz, alternate current: 5 mV) of a given sample were obtained on a CHI 760D (Shanghai, China) electrochemical workstation using a three-electrode system. The Pt plate (1.0

A nonenzymatic reduced graphene oxide-based nanosensor for parathion

• Sarani Sen,
• Anurag Roy,
• Ambarish Sanyal and
• Parukuttyamma Sujatha Devi

Beilstein J. Nanotechnol. 2022, 13, 730–744, doi:10.3762/bjnano.13.65

• performance of the nanosensor was validated by adding PT to natural samples and comparing the data via absorption spectroscopy. PT detection results encourage the design of easy-to-use nanosensor-based analytical tools for rapidly monitoring other environmental samples. Keywords: electrochemical nanosensor

• Technologies, USA), which was connected by a three-electrode system, including a modified and/or unmodified GCE as the working electrode, a saturated Ag/AgCl as the reference electrode (RE), and a platinum wire as the counter electrode (CE). The electrochemical impedance spectroscopy (EIS) study of the

• spectra of the samples were recorded in the 1000–3500 cm−1 region with a resolution of 1 cm−1 using a Renishaw via a Reflex micro-Raman spectrometer with an argon ion (514.6 nm) laser. The X-ray photoemission spectroscopy (XPS) data were obtained from a PHI 5000 Versa probe II scanning XPS microprobe

Direct measurement of surface photovoltage by AC bias Kelvin probe force microscopy

• Masato Miyazaki,
• Yasuhiro Sugawara and
• Yan Jun Li

Beilstein J. Nanotechnol. 2022, 13, 712–720, doi:10.3762/bjnano.13.63

• spectroscopy (KPFS) [75][76], as shown in Figure 4. Schematics of AC-KPFM for direct SPV measurements. (a) Block diagram of AC-KPFM in FM mode. FG is a function generator. (b, c) Scheme of the AC bias nullifying method by laser power modulation with (b) sinusoidal and (c) square waveforms, which are

Nanoarchitectonics of the cathode to improve the reversibility of Li–O₂ batteries

• Hien Thi Thu Pham,
• Jonghyeok Yun,
• So Yeun Kim,
• Sang A Han,
• Jung Ho Kim,
• Jong-Won Lee and
• Min-Sik Park

Beilstein J. Nanotechnol. 2022, 13, 689–698, doi:10.3762/bjnano.13.61

• spectroscopy (EDS) elemental mapping results (Supporting Information File 1, Figure S1) confirm that Zn and Co were uniformly distributed inside the as-grown ZnxCoy particles. We also found that the size of the ZnxCoy particles was decreased by increasing the ratio of Zn/Co during the synthesis due to the

• /CNT composites was further investigated by using X-ray photoelectron spectroscopy (XPS), as shown in Figure 4. The XPS spectra were carefully deconvoluted, based on the excitation of C 1s at the binding energy of 284.5 eV. According to the Co 2p spectra collected from the ZnxCoy–C/CNT composites

• microstructures of the materials. Powder XRD (PANalytical, Empyrean) and Raman spectroscopy (inVia Raman microscopes, Ar ion laser, 514 nm) were employed to analyze the structures. Their surface chemistry was investigated by XPS (Thermo Scientific, Sigma Probe), while their surface area and porosity were

Experimental and theoretical study of field-dependent spin splitting at ferromagnetic insulator–superconductor interfaces

• Peter Machon,
• Michael J. Wolf,
• Detlef Beckmann and
• Wolfgang Belzig

Beilstein J. Nanotechnol. 2022, 13, 682–688, doi:10.3762/bjnano.13.60

• density of states of the superconducting film by tunnel spectroscopy. Results and Discussion Theory The setup of the underlying experiment is shown in Figure 1a. It consists (bottom-up) of an EuS substrate, a superconducting (Al) film, and a normal metal film that is separated from the superconductor by

Reliable fabrication of transparent conducting films by cascade centrifugation and Langmuir–Blodgett deposition of electrochemically exfoliated graphene

• Teodora Vićentić,
• Stevan Andrić,
• Vladimir Rajić and
• Marko Spasenović

Beilstein J. Nanotechnol. 2022, 13, 666–674, doi:10.3762/bjnano.13.58

• graphene was varied. As the film of graphene formed on the surface of the water, the LB method was used to deposit the film onto the target substrate [32]. Film characterization To study optical properties of the fabricated samples, UV–vis spectroscopy was performed (Thermo Fisher Scientific EVO 60

Antibacterial activity of a berberine nanoformulation

• Hue Thi Nguyen,
• Tuyet Nhung Pham,
• Anh-Tuan Le,
• Nguyen Thanh Thuy,
• Tran Quang Huy and
• Thuy Thi Thu Nguyen

Beilstein J. Nanotechnol. 2022, 13, 641–652, doi:10.3762/bjnano.13.56

• of glycerol on the physicochemical properties of BBR NPs was investigated by UV–vis absorption and FTIR spectroscopy. The UV–vis absorption spectra of pure BBR and BBR NP solutions in distilled water at the same concentration are shown in Figure 1. Glycerol has no absorption band in the UV–vis

• , whereas the solubility of BBR NPs was significantly enhanced. The chemical characteristics of BBR and BBR NPs were analyzed through FTIR spectroscopy (Figure 2). In the FTIR spectrum of glycerol (Figure 2a), the absorption band appearing at 3287 cm−1 is characteristic for stretching vibrations of the –OH

• solution were determined using Fourier-transform infrared spectroscopy (FTIR, NEXUS 670 from Nicolet). The FTIR analysis was conducted in transmission mode in the wavenumber range of 400 to 4000 cm−1. Size and shape of BBR NPs were investigated by scanning electron microscopy (SEM, S-4800, Hitachi) and

Sodium doping in brookite TiO₂ enhances its photocatalytic activity

• Boxiang Zhuang,
• Honglong Shi,
• Honglei Zhang and
• Zeqian Zhang

Beilstein J. Nanotechnol. 2022, 13, 599–609, doi:10.3762/bjnano.13.52

• ). (1) Brookite—platy grains. Energy-dispersive X-ray spectroscopy (EDX) results of platy grains (Figure 4b) indicate that Na can be well identified besides Ti and O (note that the characteristic peak of C comes from the carbon conducting resin, Al from the sample holder, and Si from the silicon wafer

Revealing local structural properties of an atomically thin MoSe₂ surface using optical microscopy

• Lin Pan,
• Peng Miao,
• Anke Horneber,
• Alfred J. Meixner,
• Pierre-Michel Adam and
• Dai Zhang

Beilstein J. Nanotechnol. 2022, 13, 572–581, doi:10.3762/bjnano.13.49

• molybdenum diselenide (MoSe2) flake as surface-enhanced Raman spectroscopy (SERS) platform, we demonstrate the dependency of the Raman enhancement on laser beam polarization and local structure using copper phthalocyanine (CuPc) as probe. Second harmonic generation (SHG) and photoluminescence spectroscopy

• dichalcogenide. Keywords: copper phthalocyanine; local structure; molybdenum diselenide; optical spectroscopy; surface-enhanced Raman spectroscopy; Introduction Two-dimensional (2D) materials have garnered interest for the next generation of optoelectronic and electrochemical devices, mainly owing to their

• effects strongly influence the optical and electronic properties of 2D-TMDC materials. Optical second harmonic generation (SHG) spectroscopy has been recently used to study the presence of mid-gap states in the electronic band structure of WS2 flakes, which are induced by sulfur vacancies [14]. In

Effects of substrate stiffness on the viscoelasticity and migration of prostate cancer cells examined by atomic force microscopy

• Xiaoqiong Tang,
• Yan Zhang,
• Jiangbing Mao,
• Yuhua Wang,
• Zhenghong Zhang,
• Zhengchao Wang and
• Hongqin Yang

Beilstein J. Nanotechnol. 2022, 13, 560–569, doi:10.3762/bjnano.13.47

• maintained. An indentation area of 3 μm × 3 μm was selected at the nuclear region where 36 force curves were recorded for each cell in force spectroscopy mode. The indentation force of 1 nN, spring constant values of 0.01 N·m−1, Z length of 5 μm, and an approach speed of approximately 2 μm·s−1 were employed

Detection and imaging of Hg(II) in vivo using glutathione-functionalized gold nanoparticles

• Gufeng Li,
• Shaoqing Li,
• Rui Wang,
• Min Yang,
• Lizhu Zhang,
• Yanli Zhang,
• Wenrong Yang and
• Hongbin Wang

Beilstein J. Nanotechnol. 2022, 13, 549–559, doi:10.3762/bjnano.13.46

• concentration of electrolyte solution was increased. The GNPs-GSH-Rh6G2 have a lower fluorescence baseline in 0.10 M NaCl solution, which is important for the application in living organisms. Detection of Hg(II) We investigated the optical sensing properties of GNPs-GSH-Rh6G2 using fluorescence spectroscopy. To

Influence of thickness and morphology of MoS₂ on the performance of counter electrodes in dye-sensitized solar cells

• Lam Thuy Thi Mai,
• Hai Viet Le,
• Ngan Kim Thi Nguyen,
• Van La Tran Pham,
• Thu Anh Thi Nguyen,
• Nguyen Thanh Le Huynh and
• Hoang Thai Nguyen

Beilstein J. Nanotechnol. 2022, 13, 528–537, doi:10.3762/bjnano.13.44

• characterized by Raman spectroscopy. The Raman spectrum of the MoS2/FTO sample showed the characteristic peaks of the 2H and 1T phases of MoS2 (Figure 4b). The appearance of the J1, J2, and J3 peaks around 150, 226, and 326 cm−1 confirmed the presence of the 1T metallic phase. Whereas the two Raman vibration

• , respectively. For comparison, DSSCs based on Pt/FTO CE (DSSCs-Pt) were also fabricated under the same conditions. Characterizations of MoS2 thin films X-ray diffraction (XRD) analysis was carried out using a D8 Advance (Bruker, Germany) with a copper anode (λKα = 1.54 Å). Raman spectroscopy measurements were

• -Newport-USA, Model No. 94061A). Simulated sunlight of 100 mW·cm−2 (1 sun) was generated and corrected by a 1000 W Xe lamp and an AM 1.5 filter. The photocurrent density–voltage (J–V) curves of the DSSCs were measured using a Keithley model 2400 multisource meter. Electrochemical impedance spectroscopy

Design and characterization of polymeric microneedles containing extracts of Brazilian green propolis

• Camila Felix Vecchi,
• Rafaela Said dos Santos,
• Jéssica Bassi da Silva and
• Marcos Luciano Bruschi

Beilstein J. Nanotechnol. 2022, 13, 503–516, doi:10.3762/bjnano.13.42

• regarding in vitro and in vivo evaluation of the biological activity and cytotoxicity of the MNs, the vitro PRP release profile, the cutaneous permeation using porcine and human skin, and photoacoustic spectroscopy. Experimental Materials Poloxamer 407 (P407), gelatin, and propylene glycol were purchased

Zinc oxide nanostructures for fluorescence and Raman signal enhancement: a review

• Ioana Marica,
• Fran Nekvapil,
• Maria Ștefan,
• Cosmin Farcău and
• Alexandra Falamaș

Beilstein J. Nanotechnol. 2022, 13, 472–490, doi:10.3762/bjnano.13.40

• , Romania RDI Laboratory of Applied Raman Spectroscopy, RDI Institute of Applied Natural Sciences (IRDI-ANS), Babeş-Bolyai University, Fântânele 42, 400293, Cluj-Napoca, Romania 10.3762/bjnano.13.40 Abstract Since the initial discovery of surface-enhanced Raman scattering (SERS) and surface-enhanced

• noble metal nanoparticles and the molecular fluorescence enhancement in the presence of ZnO alone and in combination with metal nanoparticles are also reviewed. Keywords: fluorescence; surface-enhanced Raman spectroscopy; ZnO–metal nanomaterials; ZnO nanostructures; Introduction Over the last decades

Investigation of electron-induced cross-linking of self-assembled monolayers by scanning tunneling microscopy

• Patrick Stohmann,
• Sascha Koch,
• Yang Yang,
• Christopher David Kaiser,
• Julian Ehrens,
• Jürgen Schnack,
• Niklas Biere,
• Dario Anselmetti,
• Armin Gölzhäuser and
• Xianghui Zhang

Beilstein J. Nanotechnol. 2022, 13, 462–471, doi:10.3762/bjnano.13.39

• separation [36][37][38][39][40][41][42]. The interactions between aromatic SAMs and electrons have been studied by X-ray photoelectron spectroscopy (XPS), near-edge X-ray-absorption fine-structure (NEXAFS) technique [43][44][45][46][47][48][49], infrared spectroscopy [43][50][51][52], high-resolution

• electron energy loss spectroscopy (HREELS) [53][54], Raman spectroscopy [55], and low-energy electron microscopy (LEEM) [56] as well as by theoretical analysis [57][58][59]. It is now well established that electron irradiation leads to cleavage of C–H and S–H bonds, followed by the formation of C–C bonds

• K and the substrate was held at room temperature. The chamber pressure during the evaporation process was ≈10−8 mbar and the evaporation time was ≈30 min. X-ray photoelectron spectroscopy was employed to monitor the existence of thiolates as well as physisorbed thiols. To remove physisorbed

Tubular glassy carbon microneedles with fullerene-like tips for biomedical applications

• Sharali Malik and
• George E. Kostakis

Beilstein J. Nanotechnol. 2022, 13, 455–461, doi:10.3762/bjnano.13.38

• of these glassy carbon tubules shows long-range order with a d-spacing of 4.89 Å, which is indicative of glassy carbon. Raman spectroscopy shows the material to be graphitic in nature, and SEM shows the fullerene-like structure of the material. This work provides new insights into the structure of

• work, we have shown that the pyrolysis of methane leads to the formation of glassy carbon microneedles. These were characterized and identified using a combination of SEM, Raman spectroscopy, and XRD. This simple method of preparation provides an easy and efficient alternative to previously used

• Raman spectroscopy (WiTec CRM200, laser excitation at 632.8 nm), scanning electron microscopy (SEM Leo 1530, with a spatial resolution of 1 nm at 20 kV and 3 nm at 1 kV, equipped with an energy-dispersive X-ray analysis system EDX INCA 400 from Oxford Instruments), and X-ray diffraction (STOE STADI-P

The role of sulfonate groups and hydrogen bonding in the proton conductivity of two coordination networks

• Ali Javed,
• Felix Steinke,
• Stephan Wöhlbrandt,
• Hana Bunzen,
• Norbert Stock and
• Michael Tiemann

Beilstein J. Nanotechnol. 2022, 13, 437–443, doi:10.3762/bjnano.13.36

• , Germany 10.3762/bjnano.13.36 Abstract The proton conductivity of two coordination networks, [Mg(H2O)2(H3L)]·H2O and [Pb2(HL)]·H2O (H5L = (H2O3PCH2)2-NCH2-C6H4-SO3H), is investigated by AC impedance spectroscopy. Both materials contain the same phosphonato-sulfonate linker molecule, but have clearly

• the Pb-based metal-organic framework, in contrast, no extended hydrogen bonding occurs, as the sulfonate groups coordinate to Pb2+, without forming hydrogen bonds; the proton conductivity is much lower in this material. Keywords: coordination network; coordination polymer; impedance spectroscopy

• spectroscopy, samples of the materials were pressed into cylindrical pellets using a weight of 10 t. The pellets had thicknesses of ca. 1.8 mm ([Mg(H2O)2(H3L)]·H2O) and ca. 0.5 mm ([Pb2(HL)]·H2O), respectively; their external surface area was ca. 130 mm2. Impedance measurements were carried out using a

A non-enzymatic electrochemical hydrogen peroxide sensor based on copper oxide nanostructures

• Irena Mihailova,
• Vjaceslavs Gerbreders,
• Marina Krasovska,
• Eriks Sledevskis,
• Valdis Mizers,
• Andrejs Bulanovs and
• Andrejs Ogurcovs

Beilstein J. Nanotechnol. 2022, 13, 424–436, doi:10.3762/bjnano.13.35

• spectroscopy and X-ray diffractometry. The resulting nanostructured samples were used for electrochemical determination of the H2O2 content in a 0.1 M NaOH buffer solution using cyclic voltammetry, differential pulse voltammetry, and i–t measurements. A good linear relationship between the peak current and the

• of the nanostructured CuO samples was studied via field-emission scanning electron microscopy (FESEM, Tescan MAIA 3). The chemical composition analysis was performed via energy-dispersive spectroscopy (EDS, Inca Synergy) integrated into the FESEM system. The crystalline structure of the samples was

• following sections show the averaged data from all measurements. To determine the optimal scanning parameters that provide the maximum sensitivity of the sensor, the dependence of the electrochemical response on the pH of the buffer solution and on the scanning speed was studied. Impedance spectroscopy was