Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal–organic framework

• Manuel Souto,
• Joaquín Calbo,
• Samuel Mañas-Valero,
• Aron Walsh and
• Guillermo Mínguez Espallargas

Beilstein J. Nanotechnol. 2019, 10, 1883–1893, doi:10.3762/bjnano.10.183

• increased by two orders of magnitude due to the CT interactions between C60 and the TTF-based framework. Keywords: charge transfer; donor–acceptor; fullerene; metal–organic frameworks (MOFs); tetrathiafulvalene (TTF); Introduction Metal–organic frameworks (MOFs), which are crystalline porous materials

• (donor) and fullerene (acceptor) without a significant decrease in the porosity [36]. Tetrathiafulvalene (TTF) and its numerous derivatives are redox-active electron-donor molecules with unique electronic properties that have been widely used as important building units in the field of molecular

• ). The quantity of fullerene encapsulated in MUV-2 was estimated from the decrease in pore volume, obtaining a value of around 0.7 C60 per 3 TTF ligands, almost 1 fullerene per section of the void. This low encapsulation rate can be explained by diffusion issues or by weak interactions between the C60

Materials nanoarchitectonics at two-dimensional liquid interfaces

• Katsuhiko Ariga,
• Michio Matsumoto,
• Taizo Mori and
• Lok Kumar Shrestha

Beilstein J. Nanotechnol. 2019, 10, 1559–1587, doi:10.3762/bjnano.10.153

• by using solely very common apparatuses such as beaker, stirrer, and tweezers. Therefore, the proposed method can be more generalized and extended even to industrial applications. For the bottom-up fabrication of nanocarbon materials through self-assembly processes, the use of fullerene (especially

• , C60) molecules as assembling components are both technically and scientifically attractive [235]. In addition to the technical importance of fullerene in many applications including physical devices and biomedical usages, assembly processes from completely symmetrical zero-dimensional objects with

• single elemental composition (carbon) are an intriguing fundamental topic in supramolecular chemistry [236]. Miyazawa and co-workers initiated a simple but highly useful method, i.e., liquid–liquid interfacial precipitation, to fabricate fullerene assemblies (crystals) with various morphologies (Figure

Synthesis of P- and N-doped carbon catalysts for the oxygen reduction reaction via controlled phosphoric acid treatment of folic acid

• Rieko Kobayashi,
• Takafumi Ishii,
• Yasuo Imashiro and
• Jun-ichi Ozaki

Beilstein J. Nanotechnol. 2019, 10, 1497–1510, doi:10.3762/bjnano.10.148

• this point, it is worth noting that our previous investigations of the relationship between the ORR activity and oxygen adsorption properties of warped graphitic layers (obtained by oxidative heat treatment of fullerene extraction residues) demonstrated that these two parameters are well correlated [41

Warped graphitic layers generated by oxidation of fullerene extraction residue and its oxygen reduction catalytic activity

• Machiko Takigami,
• Rieko Kobayashi,
• Takafumi Ishii,
• Yasuo Imashiro and
• Jun-ichi Ozaki

Beilstein J. Nanotechnol. 2019, 10, 1391–1400, doi:10.3762/bjnano.10.137

• study employed a fullerene extraction residue as a starting material to construct WGLs. The oxidation of the material at 600 °C exposed the WGLs by removing the surrounding amorphous moieties. Transmission electron microscopy (TEM) observations revealed the formation of WGLs by oxidation treatment at

• maximum specific ORR activity after 1 h of oxidation time. WGLs were found to lower the heat of adsorption for O2 and to increase the occurrence of heterogeneous electron transfer. Keywords: carbon alloy catalysts; fullerene extraction residue; oxygen reduction reaction (ORR); polymer electrolyte fuel

• diamond phase, nitrogen, boron, phosphorus, sulfur, and transition metals like iron and cobalt. Such WGLs can be obtained from fullerene-related materials. We selected a commercial carbon, Nanom Black, which is a fullerene extraction residue from a fullerene soot prepared by a combustion method [40]. The

Synthesis and characterization of quaternary La(Sr)S–TaS₂ misfit-layered nanotubes

• Marco Serra,
• Erumpukuthickal Ashokkumar Anumol,
• Dalit Stolovas,
• Iddo Pinkas,
• Ernesto Joselevich,
• Reshef Tenne,
• Andrey Enyashin and
• Francis Leonard Deepak

Beilstein J. Nanotechnol. 2019, 10, 1112–1124, doi:10.3762/bjnano.10.111

• ]. Typically, these nanostructures are synthesized by means of high-temperature reactions that allow the formation of different metal sulfide nanotubes [4][5]. Another type of hollow nanostructure, inorganic fullerene-like structures (IFs), is the result of bending of a 2D layer of WS2 or any other 2D material

Tungsten disulfide-based nanocomposites for photothermal therapy

• Tzuriel Levin,
• Hagit Sade,
• Rina Ben-Shabbat Binyamini,
• Maayan Pour,
• Iftach Nachman and
• Jean-Paul Lellouche

Beilstein J. Nanotechnol. 2019, 10, 811–822, doi:10.3762/bjnano.10.81

• , 100 nm diameter) and inorganic fullerene-like nanoparticles (IFs) were reported in multiple literature sources [2][3][4][5][6][7][8], making them an excellent alternative to carbon nanotubes as additives for the mechanical enforcement of polymeric matrices [9][10][11][12][13][14][15][16][17]. An

Charged particle single nanometre manufacturing

• Philip D. Prewett,
• Cornelis W. Hagen,
• Claudia Lenk,
• Steve Lenk,
• Marcus Kaestner,
• Tzvetan Ivanov,
• Ahmad Ahmad,
• Ivo W. Rangelow,
• Xiaoqing Shi,
• Stuart A. Boden,
• Alex P. G. Robinson,
• Dongxu Yang,
• Sangeetha Hari,
• Marijke Scotuzzi and
• Ejaz Huq

Beilstein J. Nanotechnol. 2018, 9, 2855–2882, doi:10.3762/bjnano.9.266

• ”. Scanning helium ion beam lithography has the advantages of virtually zero proximity effect, nanoscale patterning capability and high sensitivity in combination with a novel fullerene resist based on the sub-nanometre C60 molecule. The shot noise-limited minimum linewidth achieved to date is 6 nm. The

• curing process in order to render it compatible with fluorine etch and other plasma chemistries [33]. These new resists include novel fullerene formulations from Irresistible Materials Ltd (IM) and Birmingham University, UK, which have demonstrated etch selectivity with respect to Si of 9:1 in fluorine

• carbons in a ring structure as possible, as is the case of a monoadduct methanofullerene derivative. The fullerene molecule gives the maximum possible value of ring parameter and the minimum possible Ohnishi number [37]. The sub-nanometre fullerene molecule forms amorphous films and has been shown

Pattern generation for direct-write three-dimensional nanoscale structures via focused electron beam induced deposition

• Lukas Keller and
• Michael Huth

Beilstein J. Nanotechnol. 2018, 9, 2581–2598, doi:10.3762/bjnano.9.240

• already long enough if a proximity correction, i.e., an optimized writing order within a frame, is used. As a second complex example we show in Figure 12 the buckyball motif (like in the C60 fullerene molecule). Since there is a very large range of different edge inclination angles in this structure it is

Lead-free hybrid perovskites for photovoltaics

• Oleksandr Stroyuk

Beilstein J. Nanotechnol. 2018, 9, 2209–2235, doi:10.3762/bjnano.9.207

• metal oxide electron transport layer (ETL) and then covered with an organic hole transport layer (HTL) and an “inverted” p–i–n design, where an HP layer is formed on an HTL support and covered with an organic ETL, such as fullerene derivatives (see below in Figure 2). The conventional n–i–p scheme

• mixed Sn–Pb perovskites can be further enhanced by the passivation with a C60 layer [98]. The fullerene was found to eliminate the surface trap states of MAPb0.75Sn0.25I3 crystals suppressing the electron–hole recombination as well as shielding the HP layer from the ambient moisture and oxygen. Solar

• ) in an inverted cell with a fullerene ETL [144]. The combination of Sn2+ and Ge2+ in single HPs results in solid-solution CH3NH3Sn(1−x)GexI3 compounds with a bandgap tunable from 1.3 eV (x = 0) to 2.0 eV (x = 1) [146]. A Mn2+-based analog of MAPI was produced by the spin-coating of a mixture of MnI2

Numerical analysis of single-point spectroscopy curves used in photo-carrier dynamics measurements by Kelvin probe force microscopy under frequency-modulated excitation

• Pablo A. Fernández Garrillo,
• Benjamin Grévin and
• Łukasz Borowik

Beilstein J. Nanotechnol. 2018, 9, 1834–1843, doi:10.3762/bjnano.9.175

• probe force microscopy under frequency-modulated excitation over a silicon nanocrystal solar cell, as well as against results obtained by intensity-modulated scanning Kelvin probe microscopy over a polymer/fullerene bulk heterojunction device. Moreover, we show how this simulation routine can complement

• the simulation routine against the results obtained by intensity-modulated scanning Kelvin probe microscopy on a polymer/fullerene bulk heterojunction device as presented by Shao and co-workers [4]. The outcome of these comparisons did not only provide additional evidence supporting results obtained

• results obtained by intensity-modulated scanning Kelvin probe microscopy over a polymer/fullerene bulk heterojunction device as presented by Shao and co-workers [4]. As stated above, SPECTY can be useful in the analysis of results obtained by several frequency-modulated KPFM techniques. Intensity

SO₂ gas adsorption on carbon nanomaterials: a comparative study

• Deepu J. Babu,
• Divya Puthusseri,
• Frank G. Kühl,
• Sherif Okeil,
• Michael Bruns,
• Manfred Hampe and
• Jörg J. Schneider

Beilstein J. Nanotechnol. 2018, 9, 1782–1792, doi:10.3762/bjnano.9.169

• present as characterized by TG, TEM, XPS and EDX (the remaining material being carbon materials such as fullerene fragments and graphite particles). SWNTs and MWNTs were obtained from NanoLab, Inc. MA, USA. According to the manufacturer, MWNTs have a purity of >95%, with an outer diameter of 15 ± 5 nm

P3HT:PCBM blend films phase diagram on the base of variable-temperature spectroscopic ellipsometry

• Barbara Hajduk,
• Henryk Bednarski,
• Bożena Jarząbek,
• Henryk Janeczek and
• Paweł Nitschke

Beilstein J. Nanotechnol. 2018, 9, 1108–1115, doi:10.3762/bjnano.9.102

• organic semiconductor poly(3-hexylthiophene) (P3HT) and the fullerene derivative [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) are extensively studied organic materials because of their important practical applications in organic electronics, especially in organic photovoltaic devices (OPV devices) [1

• polymer–fullerene layers. For this reason, the morphology of the active layer in OPV devices has been intensively studied [15][16]. In general, it can be modified by the blend composition [17], the type of solvent used in processing [18], the use of chemical additives to the solution [19], and diverse

Review on nanoparticles and nanostructured materials: history, sources, toxicity and regulations

• Jaison Jeevanandam,
• Ahmed Barhoum,
• Yen S. Chan,
• Alain Dufresne and
• Michael K. Danquah

Beilstein J. Nanotechnol. 2018, 9, 1050–1074, doi:10.3762/bjnano.9.98

Optimisation of purification techniques for the preparation of large-volume aqueous solar nanoparticle inks for organic photovoltaics

• Furqan Almyahi,
• Thomas R. Andersen,
• Nathan A. Cooling,
• Natalie P. Holmes,
• Matthew J. Griffith,
• Krishna Feron,
• Xiaojing Zhou,
• Warwick J. Belcher and
• Paul C. Dastoor

Beilstein J. Nanotechnol. 2018, 9, 649–659, doi:10.3762/bjnano.9.60

• state of the art large scale OPV, the organic materials (polymers, fullerene or other macromolecules) comprising the active layer are dissolved in organic solvents, i.e., chloroform or chlorobenzene [5]. The application of these solvents can be an issue for the large-scale production of OPV due to their

Effect of the fluorination technique on the surface-fluorination patterning of double-walled carbon nanotubes

• Lyubov G. Bulusheva,
• Yuliya V. Fedoseeva,
• Emmanuel Flahaut,
• Jérémy Rio,
• Christopher P. Ewels,
• Victor O. Koroteev,
• Gregory Van Lier,
• Denis V. Vyalikh and
• Alexander V. Okotrub

Beilstein J. Nanotechnol. 2017, 8, 1688–1698, doi:10.3762/bjnano.8.169

• ) approximation requires significantly less computer resources and well fits NEXAFS C K-spectra of fullerene C60, CNTs and their fluorinated derivatives [32][55][56]. Intensities of spectral lines were obtained by summing the squared coefficients at Ne 2p orbitals and broadened with Lorentzian functions of a

Parylene C as a versatile dielectric material for organic field-effect transistors

• Tomasz Marszalek,
• Maciej Gazicki-Lipman and
• Jacek Ulanski

Beilstein J. Nanotechnol. 2017, 8, 1532–1545, doi:10.3762/bjnano.8.155

• is not only connected to the dielectric/semiconductor interface. The effect of grain size and interface dependence of bias stress stability has been studied for C60-fullerene-based, n-type OFETs. It was revealed that, with an increasing grain size of C60, the bias stress induced shift of the

• fullerene transistors, where a comparison between the bottom-gate, top-gate and double-gate configuration with Parylene C as a dielectric layer is made [54]. The results are shown in Figure 10. The charge-carrier field-effect mobility for bottom-gate, top-gate, and dual-gate OFETs was determined to be 0.1

• discussed above were obtained for active materials that were not sensitive to ambient conditions. However, most n-type organic semiconductors do not show such stability. One example of an unstable material (characterized by considerable charge trapping) is the previously described fullerene C60. The

A nanocomplex of C₆₀ fullerene with cisplatin: design, characterization and toxicity

• Svitlana Prylutska,
• Svitlana Politenkova,
• Kateryna Afanasieva,
• Volodymyr Korolovych,
• Kateryna Bogutska,
• Andriy Sivolob,
• Larysa Skivka,
• Maxim Evstigneev,
• Viktor Kostjukov,
• Yuriy Prylutskyy and
• Uwe Ritter

Beilstein J. Nanotechnol. 2017, 8, 1494–1501, doi:10.3762/bjnano.8.149

• ., 25, 98693 Ilmenau, Germany 10.3762/bjnano.8.149 Abstract The self-organization of C60 fullerene and cisplatin in aqueous solution was investigated using the computer simulation, dynamic light scattering and atomic force microscopy techniques. The results evidence the complexation between the two

• compounds. The genotoxicity of С60 fullerene, Cis and their complex was evaluated in vitro with the comet assay using human resting lymphocytes and lymphocytes after blast transformation. The cytotoxicity of the mentioned compounds was estimated by Annexin V/PI double staining followed by flow cytometry

• . The results clearly demonstrate that water-soluble C60 fullerene nanoparticles (0.1 mg/mL) do not induce DNA strand breaks in normal and transformed cells. C60 fullerene in the mixture with Cis does not influence genotoxic Cis activity in vitro, affects the cell-death mode in treated resting human

Hierarchically structured nanoporous carbon tubes for high pressure carbon dioxide adsorption

• Julia Patzsch,
• Deepu J. Babu and
• Jörg J. Schneider

Beilstein J. Nanotechnol. 2017, 8, 1135–1144, doi:10.3762/bjnano.8.115

• areas (Figure 3c,d). These are typical for glassy carbon related materials as well as carbon structures containing fullerene- or carbon-onion-like fragments [41][42][43][44]. Figure 4 shows the Raman spectra of the carbon tubes (4) carbonized at different temperatures. The D-band at 1345 cm−1 is

• , the lowered D/G signal ratio indicates an increase in sp2 centers due to the growth of closed graphitic structures (onion-like or fullerene-type structures). SEM measurements have indicated that the tube morphology is still intact and unchanged after the CO2 adsorption cycling (not shown). Conclusion

• fibres (2), (c) silica@carbon composite fibres (3), (d) carbon tubes (4) and (e) silicon carbide tubes (5). TEM images of the carbon tubes (4) calcined at 950 °C (a,b), 1300 °C (c) and 1600 °C (d). Circles indicate graphitic regions with fullerene- or onion-like structural moieties. Raman spectra of the

Adsorption characteristics of Er₃N@C₈₀on W(110) and Au(111) studied via scanning tunneling microscopy and spectroscopy

• Sebastian Schimmel,
• Zhixiang Sun,
• Danny Baumann,
• Denis Krylov,
• Nataliya Samoylova,
• Alexey Popov,
• Bernd Büchner and
• Christian Hess

Beilstein J. Nanotechnol. 2017, 8, 1127–1134, doi:10.3762/bjnano.8.114

• conformations was demonstrated for Sc3N@C80 [6]. Furthermore, the magneto-optically active endohedral fullerene Er3N@C80 permits a direct non-cage-mediated optical interaction with the incarcerated Er3+ ion in near-infrared that might make its use as optical manipulable fullerene-qubit possible [7][8][9]. Due

• even attempts to induce self-assembling by surface diffusion via annealing (T = 670 K) were not successful. This means, the formation of monolayer islands is inhibited for this system. Apparently, the fullerene–W(110) bond is relatively strong. This is surprising in view of the well-known donation of

• disturbed and lose the straight long range zigzag course. This is the case for both, the one-dimensional molecular lines at the step edges as well as for the two-dimensional molecular layers. At the step edges (Figure 2a) the herring bones apparently cannot pass the single fullerene line. This is in

Stable Au–C bonds to the substrate for fullerene-based nanostructures

• Taras Chutora,
• Jesús Redondo,
• Bruno de la Torre,
• Martin Švec,
• Pavel Jelínek and
• Héctor Vázquez

Beilstein J. Nanotechnol. 2017, 8, 1073–1079, doi:10.3762/bjnano.8.109

• /bjnano.8.109 Abstract We report on the formation of fullerene-derived nanostructures on Au(111) at room temperature and under UHV conditions. After low-energy ion sputtering of fullerene films deposited on Au(111), bright spots appear at the herringbone corner sites when measured using a scanning

• tunneling microscope. These features are stable at room temperature against diffusion on the surface. We carry out DFT calculations of fullerene molecules having one missing carbon atom to simulate the vacancies in the molecules resulting from the sputtering process. These modified fullerenes have an

• adsorption energy on the Au(111) surface that is 1.6 eV higher than that of C60 molecules. This increased binding energy arises from the saturation by the Au surface of the bonds around the molecular vacancy defect. We therefore interpret the observed features as adsorbed fullerene-derived molecules with C

Needs and challenges for assessing the environmental impacts of engineered nanomaterials (ENMs)

• Michelle Romero-Franco,
• Hilary A. Godwin,
• Muhammad Bilal and
• Yoram Cohen

Beilstein J. Nanotechnol. 2017, 8, 989–1014, doi:10.3762/bjnano.8.101

• risk communication strategies. The use of NanoRiskCat was demonstrated for categorization of the following ENM containing products: cleansing soap (containing nano Ag), tennis rackets (CNTs), automotive oil (Fullerene C60), and sunblock (nano ZnO), among others [35]. NanoRiskCat analysis concluded that

Energy-level alignment at interfaces between manganese phthalocyanine and C₆₀

• Daniel Waas,
• Florian Rückerl,
• Martin Knupfer and
• Bernd Büchner

Beilstein J. Nanotechnol. 2017, 8, 927–932, doi:10.3762/bjnano.8.94

• fullerene C60. We show that this energy-level alignment depends upon the preparation sequence, which is explained by different molecular orientations. Moreover, our results demonstrate that MnPc/C60 interfaces are hardly suited for application in organic photovoltaic devices, since the energy difference of

• investigations a pre-cleaned Au(100) crystal, controlled by core-level PES spectra, was used as a substrate, on which the MnPc/C60 heterojunctions were prepared. The fullerene and manganese phthalocyanine films were grown step by step at room temperature via evaporation of the two materials from home-built

Investigation of growth dynamics of carbon nanotubes

• Marianna V. Kharlamova

Beilstein J. Nanotechnol. 2017, 8, 826–856, doi:10.3762/bjnano.8.85

• summarized. Finally, the growth properties of inner tubes inside SWCNTs filled with fullerene and organometallic molecules are considered. Synthesis of carbon nanotubes The SWCNTs can be synthesized by the arc-discharge, laser ablation and chemical vapour deposition (CVD) techniques. A detailed overview of

• can also be obtained by the “cloning growth” and organic synthesis, as described in detail in review [132]. Inner tube growth inside SWCNTs While the coalescence mechanism is generally accepted for the formation of inner tubes from fullerene-filled SWCNTs [133][134][135][136][137][138][139][140][141

Modeling adsorption of brominated, chlorinated and mixed bromo/chloro-dibenzo-p-dioxins on C₆₀ fullerene using Nano-QSPR

• Piotr Urbaszek,
• Agnieszka Gajewicz,
• Celina Sikorska,
• Maciej Haranczyk and
• Tomasz Puzyn

Beilstein J. Nanotechnol. 2017, 8, 752–761, doi:10.3762/bjnano.8.78

• bromine and/or chlorine in dibenzo-p-dioxins on their sorption ability on the C60 fullerene surface. Halogenated dibenzo-p-dioxins (PXDDs, where X = Br or Cl) are ever-present in the environment and accidently produced in many technological processes in only approximately known quantities. If all

• natural processes occurring in the environment, the total amount of chlorinated PXDD derivatives is constantly decreasing, while the amount of brominated and mixed congeners (molecules based on the same carbon skeleton differing by the number and type of substituents) is increasing [11]. Fullerene C60

• – opportunities and risks of possible surface interactions Fullerene C60 [12][13][14], discovered in 1985, has a soccer ball-like structure [15] with a chemical structure representative of carbon nanostructures. Its unique properties and shape make C60 and its derivatives promising candidates for various

Analysis and modification of defective surface aggregates on PCDTBT:PCBM solar cell blends using combined Kelvin probe, conductive and bimodal atomic force microscopy

• Hanaul Noh,
• Alfredo J. Diaz and
• Santiago D. Solares

Beilstein J. Nanotechnol. 2017, 8, 579–589, doi:10.3762/bjnano.8.62

• Hanaul Noh Alfredo J. Diaz Santiago D. Solares Department of Mechanical and Aerospace Engineering, The George Washington University, Washington, DC 20052, United States of America 10.3762/bjnano.8.62 Abstract Organic photovoltaic systems comprising donor polymers and acceptor fullerene