Heterogeneous reactions in a HFCVD reactor: simulation using a 2D model

• Xochitl Aleyda Morán Martínez,
• José Alberto Luna López,
• Zaira Jocelyn Hernández Simón,
• Gabriel Omar Mendoza Conde,
• José Álvaro David Hernández de Luz and
• Godofredo García Salgado

Beilstein J. Nanotechnol. 2024, 15, 1627–1638, doi:10.3762/bjnano.15.128

• precursors quartz and hydrogen was carried out. The obtained equilibrium constants (Keq) were related to the temperature profile in the deposition zone and used in the proposed simulation. The validation of the model was carried out by measuring the temperature experimentally, where the temperature range on

• second one is the reaction zone, and the third one is the gas outlet. In the first zone, molecular hydrogen (H2) gas is pumped in through a stainless steel piping system that reaches a diffuser inside the reaction chamber. The gas gets in contact with eleven tungsten filaments from incandescent lamps

• , which are activated by an externally applied voltage generating a current; these filaments have a temperature of approximately 2300 K. The second zone includes the region where the chemical reactions takes place. Here, molecular hydrogen, exposed to the high temperature of the filaments, dissociates to

Natural nanofibers embedded in the seed mucilage envelope: composite hydrogels with specific adhesive and frictional properties

• Agnieszka Kreitschitz and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2024, 15, 1603–1618, doi:10.3762/bjnano.15.126

• features with synthetic hydrogels [2][9][10][11]. Hydrogels are 3D networks of polymers (i.e., polysaccharides in plant seeds) interacting via chemical bonds (ionic and covalent), physical interactions (hydrogen bonds), or van der Waals forces [3][11][12]. The ability to produce the mucilage envelope is a

• typical part of plant cells, and its basic chemical composition includes cellulose, hemicelluloses, and pectic polysaccharides [44][45][46][47]. Cellulose is a linear polymer composed of β-1,4-linked ᴅ-glucose [47]. The cellulose chains are held together by intramolecular hydrogen bonds, forming cellulose

• taxa studied. Critical point drying in studies of natural samples containing cellulose fibrils [40][41][81], other polysaccharides (cell wall, mucilage, and envelope) [7][13], and synthetic hydrogels [82] maintained the 3D network of the studied materials. During drying, the hydrogen bonds undergo

Effect of radiation-induced vacancy saturation on the first-order phase transformation in nanoparticles: insights from a model

• Aram Shirinyan and
• Yuriy Bilogorodskyy

Beilstein J. Nanotechnol. 2024, 15, 1453–1472, doi:10.3762/bjnano.15.117

• Aram Shirinyan Yuriy Bilogorodskyy “Laboratory of composite materials for nuclear-hydrogen energy”, Department of nuclear-physical research, Institute of Applied Physics of National Academy of Sciences of Ukraine (Sumy), room 606, building 3, Nauki avenue, 46, 03028, Kyiv - 28, Ukraine 10.3762

Strain-induced bandgap engineering in 2D ψ-graphene materials: a first-principles study

• Kamal Kumar,
• Nora H. de Leeuw,
• Jost Adam and
• Abhishek Kumar Mishra

Beilstein J. Nanotechnol. 2024, 15, 1440–1452, doi:10.3762/bjnano.15.116

• atoms arranged in 5,6,7-membered rings. The half and fully hydrogenated (hydrogen-functionalized) forms of ψ-graphene are called ψ-graphone and ψ-graphane. Like ψ-graphene, ψ-graphone has a zero bandgap, but ψ-graphane is a wide-bandgap semiconductor. In this study, we have applied in-plane and out-of

• pliable displays and as strengthening material in composites [2][3][4]. It has also gained considerable attention among researchers for its application in hydrogen storage, owing to its good adsorption capacity and controllable storage and re-release of hydrogen at efficient temperatures [4][5]. The

• ), and density functional theory (DFT) study suggests that the hydrogenation of graphene with atomic hydrogen leads to the formation of graphone [8]. The full hydrogenation of graphene (graphane) was experimentally obtained by Elias et al., and their TEM and Raman spectroscopy results evidence the

Lithium niobate on insulator: an emerging nanophotonic crystal for optimized light control

• Midhun Murali,
• Amit Banerjee and
• Tanmoy Basu

Beilstein J. Nanotechnol. 2024, 15, 1415–1426, doi:10.3762/bjnano.15.114

• with SiO2. The ion-slicing method has enabled the production of large-scale, high-quality, and submicron-thick crystalline LN films. First, a lithium niobate wafer undergoes ion implantation, typically using hydrogen or helium ions, to create a weakened layer at a controlled depth [30]. After the

Various CVD-grown ZnO nanostructures for nanodevices and interdisciplinary applications

• The-Long Phan,
• Le Viet Cuong,
• Vu Dinh Lam and
• Ngoc Toan Dang

Beilstein J. Nanotechnol. 2024, 15, 1390–1399, doi:10.3762/bjnano.15.112

• ], photocatalytic degradation [41], and water splitting for hydrogen technologies [38]. Figure 3a–d show SEM images of ZnO tetrapods. These various morphologies were grown at approx. 625–650 °C. The first one, named T1 in Figure 3a, has needle-like arms of ≈1 μm of length. The dimeter of the arms is less than 50 nm

Investigation of Hf/Ti bilayers for the development of transition-edge sensor microcalorimeters

• Victoria Y. Safonova,
• Anna V. Gordeeva,
• Anton V. Blagodatkin,
• Dmitry A. Pimanov,
• Anton A. Yablokov and
• Andrey L. Pankratov

Beilstein J. Nanotechnol. 2024, 15, 1353–1361, doi:10.3762/bjnano.15.108

• Physics and Mathematics, direction no. 8, “Hydrogen Isotope Physics”.

Nanoarchitectonics with cetrimonium bromide on metal nanoparticles for linker-free detection of toxic metal ions and catalytic degradation of 4-nitrophenol

• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2024, 15, 1312–1332, doi:10.3762/bjnano.15.106

Interaction of graphene oxide with tannic acid: computational modeling and toxicity mitigation in C. elegans

• Romana Petry,
• James M. de Almeida,
• Francine Côa,
• Felipe Crasto de Lima,
• Diego Stéfani T. Martinez and
• Adalberto Fazzio

Beilstein J. Nanotechnol. 2024, 15, 1297–1311, doi:10.3762/bjnano.15.105

• , phototransformation, and degradation [8]. Furthermore, because of the presence of sites for different types of interaction mechanisms (i.e., hydrogen bonding, van der Waals interaction, and π–π stacking), its structure favors the adsorption of different molecules (i.e., biomolecules and organic pollutants) and metal

• in hydrogen bonding as well as hydrophobic and electrostatic interactions; also, they are responsible for TA’s high solubility, reactivity to metal cations, binding capacity to molecules and surfaces, and significant reducing and radical scavenging properties [19][21][22][23][24]. This range of

• groups indicate that the interactions with TA occur through C=O, C–OH, C–O, and sp2 carbon structures present in GO. Such interactions may involve, for example, hydrogen bonds and interactions between π orbitals, which is in agreement with literature regarding humic and tannic acid interactions with GO

Dual-functionalized architecture enables stable and tumor cell-specific SiO₂NPs in complex biological fluids

• Iris Renata Sousa Ribeiro,
• Raquel Frenedoso da Silva,
• Romênia Ramos Domingues,
• Adriana Franco Paes Leme and
• Mateus Borba Cardoso

Beilstein J. Nanotechnol. 2024, 15, 1238–1252, doi:10.3762/bjnano.15.100

• at 100 °C and the percentages of carbon, nitrogen, and hydrogen were obtained. It is noteworthy that only the nitrogen percentages were considered for the calculations. The elemental composition of the NP surface was obtained using a K-Alpha XPS (Thermo Fisher Scientific) which operates with Al Kα X

AI-assisted models to predict chemotherapy drugs modified with C₆₀ fullerene derivatives

• Jonathan-Siu-Loong Robles-Hernández,
• Dora Iliana Medina,
• Katerin Aguirre-Hurtado,
• Marlene Bosquez,
• Roberto Salcedo and
• Alan Miralrio

Beilstein J. Nanotechnol. 2024, 15, 1170–1188, doi:10.3762/bjnano.15.95

• can be proposed as an orally delivered drug according to its physicochemical properties. According to this rule, a drug compound should have a molecular weight below 500 g/mol, a octanol–water partition coefficient (LogP) below 5, less than five hydrogen bond donor sites, and less than ten hydrogen

• secondary structural features were stabilized by TMpred [48] and HMMTOP [49] during energy minimization. Last, the protein was prepared by setting atomic charges and hydrogen atoms and merging the nonpolar groups. Once the structures were optimized, molecular docking was performed with the CXCR7 protein

• , using Autodock Vina 1.1, to obtain the docking score, established hydrogen bonds, and the binding site (pocket). The above was done for all drugs in the dataset and an external validation set. IBM Watson AI was used to build the models and to predict the docking score through the Extra Trees regressor

Unveiling the potential of alginate-based nanomaterials in sensing technology and smart delivery applications

• Shakhzodjon Uzokboev,
• Khojimukhammad Akhmadbekov,
• Ra’no Nuritdinova,
• Salah M. Tawfik and
• Yong-Ill Lee

Beilstein J. Nanotechnol. 2024, 15, 1077–1104, doi:10.3762/bjnano.15.88

• discussed, including drug delivery and environmental sensing applications for humidity, heavy metals, and hydrogen peroxide. Moreover, biomedical sensing applications of alginate-based nanoparticles regarding various analytes such as glucose, cancer cells, pharmaceutical drugs, and human motion will also be

• result, several researchers are working on alginate to create nanoparticles. One of the most appealing properties of alginate is its capacity to readily form a gel with divalent cations, particularly Ca2+ [31]. Divalent cations create hydrogen bonds with the alginate G residues, resulting in an egg-box

• contains a lot of hydroxy and carboxylic acid groups, it has the potential to purify water by adsorbing metal ions and organic dyes through hydrogen and chelate bonding. A carbonized carboxymethyl chitosan/SA hydrogel evaporator was able to remove phenol with 95.37% efficiency and simultaneously desalinate

Ca_n neutral clusters: a two-step G₀W₀ and DFT benchmark

• Sunila Bakhsh,
• Sameen Aslam,
• Muhammad Khalid,
• Muhammad Sohail,
• Sundas Zafar,
• Sumayya Abdul Wadood,
• Kareem Morsy and
• Muhammad Aamir Iqbal

Beilstein J. Nanotechnol. 2024, 15, 1010–1016, doi:10.3762/bjnano.15.82

• ; density functional theory; G0W0 approximation; ionization potentials; magic clusters; Introduction Calcium metal has a closed shell structure and belongs to the group IIA alkaline-earth metals [1]. It has been widely used in carbon-chemical engineering (coating fullerene in hydrogen storage), optics, and

• -capacity hydrogen storage [8]. As cluster size grows, the electronic configuration changes its semiconducting behavior from nonmetal to metallic due to the overlap between the s and p orbitals. Moreover, the geometry of clusters is related to their structural properties. Most of the studies on calcium

Recent progress on field-effect transistor-based biosensors: device perspective

• Billel Smaani,
• Fares Nafa,
• Mohamed Salah Benlatrech,
• Ismahan Mahdi,
• Hamza Akroum,
• Mohamed walid Azizi,
• Khaled Harrar and
• Sayan Kanungo

Beilstein J. Nanotechnol. 2024, 15, 977–994, doi:10.3762/bjnano.15.80

• increasing their use in daily life [38]. The first ion-sensitive field-effect transistor (IS FETs) biosensor combined the metal–oxide–semiconductor (MOS) structure with glass electrodes for measuring ion activities in electrochemical and biological environments [39]. Subsequently, hydrogen-sensitive MOSFET

Identification of structural features of surface modifiers in engineered nanostructured metal oxides regarding cell uptake through ML-based classification

• Indrasis Dasgupta,
• Totan Das,
• Biplab Das and
• Shovanlal Gayen

Beilstein J. Nanotechnol. 2024, 15, 909–924, doi:10.3762/bjnano.15.75

• descriptors were collected, including molecular weight (MW), n-octanol/water partition coefficient (ALogP), number of aromatic rings (nAR), number of rings (nR), number of rotatable bonds (nBonds), number of hydrogen bond donors (nHBDs), and the number of hydrogen bond acceptors (nHBAs) [36]. Extended

• definitions are given in Supporting Information File 1, Table S2. nHBDon_Lipinski was identified as the most highly contributing feature in the developed model for the PaCa2 cell line. The descriptor nHBDon_Lipinski is associated with Lipinski’s “rule of five” where “nHBDon” stands for the number of hydrogen

• bond donors present in a molecule [50]. Hydrogen bonds play an important role in interactions between molecules in various biological processes. However, for cellular uptake in the PaCa2 cell line, the contribution of hydrogen bonds has a negative impact as shown in Figure 7. A higher value of

Water-assisted purification during electron beam-induced deposition of platinum and gold

• Cristiano Glessi,
• Fabian A. Polman and
• Cornelis W. Hagen

Beilstein J. Nanotechnol. 2024, 15, 884–896, doi:10.3762/bjnano.15.73

• a two-step procedure, with an initial deposition from the deposition precursor and a successive purification in the presence of a reactant gas (post-deposition purification). Several reactant gases have been tried, either in pure form, such as water [22][23][24][25], oxygen [18][26][27], hydrogen

A review on the structural characterization of nanomaterials for nano-QSAR models

• Salvador Moncho,
• Eva Serrano-Candelas,
• Jesús Vicente de Julián-Ortiz and
• Rafael Gozalbes

Beilstein J. Nanotechnol. 2024, 15, 854–866, doi:10.3762/bjnano.15.71

• its interaction with other substances, as for example using the maximum salt concentration in the medium with no significant coagulation or the rate constant of its oxidation by hydrogen peroxide [68]. It should be noted that the use of experimental descriptors can be exclusive, and there are models

Intermixing of MoS₂ and WS₂ photocatalysts toward methylene blue photodegradation

• Maryam Al Qaydi,
• Nitul S. Rajput,
• Michael Lejeune,
• Abdellatif Bouchalkha,
• Mimoun El Marssi,
• Steevy Cordette,
• Chaouki Kasmi and
• Mustapha Jouiad

Beilstein J. Nanotechnol. 2024, 15, 817–829, doi:10.3762/bjnano.15.68

• electrons (e−), leading to the formation of superoxide anions (O2−) [43]. The adsorbed oxygen has the ability to undergo a reaction with two electrons, resulting in the formation of hydrogen peroxide (H2O2). Hydrogen peroxide subsequently reacts with an electron, forming hydroxyl radicals (•OH), which are

Synthesis of silver–palladium Janus nanoparticles using co-sputtering of independent sources: experimental and theorical study

• Maria J. Martínez-Carreón,
• Francisco Solís-Pomar,
• Abel Fundora,
• Claudio D. Gutiérrez-Lazos,
• Sergio Mejía-Rosales,
• Hector N. Fernández-Escamilla,
• Jonathan Guerrero-Sánchez,
• Manuel F. Meléndrez and
• Eduardo Pérez-Tijerina

Beilstein J. Nanotechnol. 2024, 15, 808–816, doi:10.3762/bjnano.15.67

• nanoparticles, by the wet reduction method using palladium and silver hydroxide colloids as precursors, to study hydrogen absorption; the size of these BNPs was 6–7 nm. However, inhomogeneous nanoparticles were obtained because Ag fractions were found on the surface, which were increased by heating the samples

Electron-induced ligand loss from iron tetracarbonyl methyl acrylate

• Hlib Lyshchuk,
• Atul Chaudhary,
• Thomas F. M. Luxford,
• Miloš Ranković,
• Jaroslav Kočišek,
• Juraj Fedor,
• Lisa McElwee-White and
• Pamir Nag

Beilstein J. Nanotechnol. 2024, 15, 797–807, doi:10.3762/bjnano.15.66

• Fe(CO)2H2+ requires removal of two hydrogen atoms from MA and their bond formation with iron, and, finally, this mass can have a stochiometry of (C4H6O2)CO+, two different ligands without the iron atom. We will return to the nature of this fragment below. There are interesting differences to the 70

Simultaneous electrochemical determination of uric acid and hypoxanthine at a TiO₂/graphene quantum dot-modified electrode

• Vu Ngoc Hoang,
• Dang Thi Ngoc Hoa,
• Nguyen Quang Man,
• Le Vu Truong Son,
• Le Van Thanh Son,
• Vo Thang Nguyen,
• Le Thi Hong Phong,
• Ly Hoang Diem,
• Kieu Chan Ly,
• Ho Sy Thang and
• Dinh Quang Khieu

Beilstein J. Nanotechnol. 2024, 15, 719–732, doi:10.3762/bjnano.15.60

• HYP using a TiO2/GQDs-modified electrode were addressed. Experimental Materials Coffee grounds were collected from the local area. Anatase (98%), hydrogen chloride (39%), hydrogen peroxide (30%), boric acid (99%), phosphoric acid (85%), acetic acid (99%), uric acid (99%), and hypoxanthine (99%) were

Laser synthesis of nanoparticles in organic solvents – products, reactions, and perspectives

• Theo Fromme,
• Sven Reichenberger,
• Katharine M. Tibbetts and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2024, 15, 638–663, doi:10.3762/bjnano.15.54

• nanoparticle synthesis in water is always accompanied by the production of gases [66][67]. Although gas formation has often been attributed to the vaporization of water, the formation of hydrogen and oxygen also occurs. Additionally, the formation of hydrogen peroxide was observed during LAL [50][51] and LRL

• nanoparticles [75][76]. Beyond the formation of carbon monoxide, the direct reduction of permanent solutes in liquids via LRL, sometimes termed laser bubbling in liquid (LBL), has been demonstrated recently for alternative reactants, such as hydrogen extraction from ammonia [77] or methanol [78], and direct

• oxygen species (ROS), for example, hydrogen peroxide, hydroxyl radicals, or dissolved oxygen, react with the particles leading to their surface oxidation. During irradiation of water with intense laser pulses, a weakly ionized plasma forms because of optical breakdown, supercontinuum emission, or both

Directed growth of quinacridone chains on the vicinal Ag(35 1 1) surface

• Niklas Humberg,
• Lukas Grönwoldt and
• Moritz Sokolowski

Beilstein J. Nanotechnol. 2024, 15, 556–568, doi:10.3762/bjnano.15.48

• sample temperature of 300 K, QA forms the same kind of molecular chains as on the nominally flat Ag(100) surface because of strong intermolecular hydrogen bonds, which we reported in a previous publication [Humberg, N.; Bretel, R.; Eslam, A.; Le Moal, E.; Sokolowski, M. J. Phys. Chem. C 2020, 124, 24861

• step edges. Keywords: Ag(100); intermolecular hydrogen bonds; one-dimensional aggregates; organic nanostructures; quinacridone; step-molecule interactions; vicinal surface; Introduction A versatile and powerful method to create nanostructures on surfaces is the self-assembly of atoms and molecules

• hydrogen bonds (H-bonds) [19] support the growth of long 1D chains of parallel oriented QA molecules, both in bulk crystals and on surfaces. It has been shown by Głowacki et al. that QA exhibits promising properties for applications in electronic and optoelectronic devices [20][21]. In particular, they

On the additive artificial intelligence-based discovery of nanoparticle neurodegenerative disease drug delivery systems

• Shan He,
• Julen Segura Abarrategi,
• Harbil Bediaga,
• Sonia Arrasate and
• Humberto González-Díaz

Beilstein J. Nanotechnol. 2024, 15, 535–555, doi:10.3762/bjnano.15.47

• solubility [90]. Most NDDs of this database are in the PSAdi range of 60–120 Å2. Stephen et al. suggested that CNS drugs should have a PSA value below 90 Å2 for a decent BBB permeability, among other physicochemical characteristics such as number of hydrogen bond donors, molecular size, and shape, with

• smaller contributions from hydrogen bond acceptors [89]. Although this type of graphic is clearly a simplification of the whole database, it offers simple guidelines for researchers concerned with designing NDD compounds or libraries with improved probability of BBB penetration. The size of the vast

Photocatalytic degradation of methylene blue under visible light by cobalt ferrite nanoparticles/graphene quantum dots

• Vo Chau Ngoc Anh,
• Le Thi Thanh Nhi,
• Le Thi Kim Dung,
• Dang Thi Ngoc Hoa,
• Nguyen Truong Son,
• Nguyen Thi Thao Uyen,
• Nguyen Ngoc Uyen Thu,
• Le Van Thanh Son,
• Le Trung Hieu,
• Tran Ngoc Tuyen and
• Dinh Quang Khieu

Beilstein J. Nanotechnol. 2024, 15, 475–489, doi:10.3762/bjnano.15.43

• benzoquinone (C6H4O2) was provided by Sigma-Aldrich, USA. Sodium hydroxide (NaOH, ≥96%) and hydrogen chloride (HCl, 38%) were purchased from Xilong, China. Instruments X-ray diffraction (XRD) patterns were recorded by using a D8 Advance (Bruker, Germany) with Cu Kα radiation (λ = 0.154 nm). Fourier-transform