Metal-organic framework-based nanomaterials for CO₂ storage: A review

• Ha Huu Do,
• Iqra Rabani and
• Hai Bang Truong

Beilstein J. Nanotechnol. 2023, 14, 964–970, doi:10.3762/bjnano.14.79

• linkers have been examined for CO2 capture. For instance, Shimizu et al. used 3-amino-1,2,4-triazolate as a linker to create Zn-based MOF nanomaterials, yielding a high efficiency in CO2 storage [29]. The result was attributed to the favorable interaction between CO2 and NH2 groups. Likewise, Panda

• enhances the efficiency of the cavity space. To exemplify this, Zhao et al. used a 2,4,6-tri(4-pyridyl)-1,3,5-triazine linker to split the pores of MIL-88, as shown in Figure 3 [34]. Consequently, a substantial CO2 adsorption capacity of 5.6 mmol·g−1 was recorded at 273 K and 1 bar, comparable to that of

Prediction of cytotoxicity of heavy metals adsorbed on nano-TiO₂ with periodic table descriptors using machine learning approaches

• Joyita Roy,
• Souvik Pore and
• Kunal Roy

Beilstein J. Nanotechnol. 2023, 14, 939–950, doi:10.3762/bjnano.14.77

• datasets with great efficiency [27]. It can be regarded as a dimensionality reduction method since it analyzes large input data and finds all important variables. While handling RF datasets, the model emphasizes the importance of parameters, which is a highly helpful aspect [28]. Adaptive boosting

Antibody-conjugated nanoparticles for target-specific drug delivery of chemotherapeutics

• Mamta Kumari,
• Amitabha Acharya and
• Praveen Thaggikuppe Krishnamurthy

Beilstein J. Nanotechnol. 2023, 14, 912–926, doi:10.3762/bjnano.14.75

• chemotherapeutics specifically to the targeted cancer cells. ACNPs combine the benefits of NPs and mAbs to provide high drug loads at the tumor site with better selectivity and delivery efficiency. The mAbs on the NP surfaces recognize their specific receptors expressed on the target cells and release the

• specifically to the target site and inhibit the cancer progression. Nanoparticle surface decoration strategies Surface functionalization of NPs through conjugation of functional groups with biomolecules is one method to enhance the targeting efficiency (Figure 2b). For effective antibody functionalization, the

• groups of the antibodies (Figure 4a) [35][47]. Neither N-hydroxysuccinimide (NHS) nor its water-soluble analogue (sulfo-NHS) are required for the single-step carbodiimide reaction. However, NHS or sulfo-NHS are generally added to produce dry-stable intermediates, which improves the conjugation efficiency

Ni, Co, Zn, and Cu metal-organic framework-based nanomaterials for electrochemical reduction of CO₂: A review

• Ha Huu Do and
• Hai Bang Truong

Beilstein J. Nanotechnol. 2023, 14, 904–911, doi:10.3762/bjnano.14.74

• carbon pastes, which serve as cathodes for CO2RR. To illustrate, Kornienko et al. deposited a Co-based MOF material onto an FTO substrate as a working electrode for CO2 conversion [40]. This material exhibited good performance in CO generation, achieving a faradaic efficiency (FE) of 76% (at −0.7 V vs

• nature, and high efficiency. Therefore, considerable interest has been directed towards exploring the potential of Zn-based MOFs in CO2RR applications. Wang and co-workers successfully prepared ZIF-8 from different metal salts for CO2RR [42]. ZIF-8 derived from ZnSO4 yielded the best performance for the

• . Mater. Chem. A, Vol. 10, Issue 11, © 2022); permission conveyed through Copyright Clearance Center, Inc. This content is not subject to CC BY 4.0.”. (a) Graphic representation of the synthesis of 2D Ni(Im)2, (b) Faradaic efficiency of 2D Ni(Im)2 with various thicknesses, (c) TOF of 2D Ni(Im)2-5 nm and

Industrial perspectives for personalized microneedles

• Remmi Danae Baker-Sediako,
• Benjamin Richter,
• Matthias Blaicher,
• Michael Thiel and
• Martin Hermatschweiler

Beilstein J. Nanotechnol. 2023, 14, 857–864, doi:10.3762/bjnano.14.70

• microneedles may become personalized according to a patient’s demographic in order to increase drug delivery efficiency and reduce healing times for patient-centric care. Keywords: 3D printing; microfabrication; microneedles; personalized medicine; transdermal drug delivery; two-photon polymerization

Biomimetics on the micro- and nanoscale – The 25th anniversary of the lotus effect

• Matthias Mail,
• Kerstin Koch,
• Thomas Speck,
• William M. Megill and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2023, 14, 850–856, doi:10.3762/bjnano.14.69

• , and therefore the surface is multifunctional. In the paper “Suspension feeding in Copepoda (Crustacea) – a numerical model of setae acting in concert”, Filippov et al. [20] present a numerical modelling approach to understand the influence of different parameters on the feeding efficiency of

• solution for a technical problem that has not been solved for a long time. In other cases, the biological systems, and therefore their related biomimetic solutions, often show a much higher efficiency than the majority of all previous non-biomimetic engineering solutions. The diversity of biomimetic

Nanostructured lipid carriers containing benznidazole: physicochemical, biopharmaceutical and cellular in vitro studies

• Giuliana Muraca,
• María Esperanza Ruiz,
• Rocío C. Gambaro,
• Sebastián Scioli-Montoto,
• María Laura Sbaraglini,
• Gisel Padula,
• José Sebastián Cisneros,
• Cecilia Yamil Chain,
• Vera A. Álvarez,
• Cristián Huck-Iriart,
• Guillermo R. Castro,
• María Belén Piñero,
• Matias Ildebrando Marchetto,
• Catalina Alba Soto,
• Germán A. Islan and
• Alan Talevi

Beilstein J. Nanotechnol. 2023, 14, 804–818, doi:10.3762/bjnano.14.66

• bioavailability by modifying the absorption, distribution, and elimination of the drug. In this study, BNZ was successfully loaded into nanocarriers composed of myristyl myristate/Crodamol oil/poloxamer 188 prepared by ultrasonication. A stable NLC formulation was obtained, with ≈80% encapsulation efficiency (%EE

• delivering active principles [19]. SLNs comprise a lipid core, solid at 25 °C, stabilized by steric effects with a surfactant. The addition of small amounts of a liquid lipid at 25 °C leads to the improvement of SLNs in terms of sustained drug release and encapsulation efficiency (EE%), enabling the

• homogeneous formulations were prepared. The encapsulation efficiency of NLC-BNZ was considerably high for the lipid formulations, reaching approx. 80%. The theoretical drug loading was 2.5%. Our results were in concordance with the encapsulation results of a previous study by Vinuesa et al., involving

Silver nanoparticles loaded on lactose/alginate: in situ synthesis, catalytic degradation, and pH-dependent antibacterial activity

• Nguyen Thi Thanh Tu,
• T. Lan-Anh Vo,
• T. Thu-Trang Ho,
• Kim-Phuong T. Dang,
• Van-Dung Le,
• Phan Nhat Minh,
• Chi-Hien Dang,
• Vinh-Thien Tran,
• Van-Su Dang,
• Tran Thi Kim Chi,
• Hieu Vu-Quang,
• Radek Fajgar,
• Thi-Lan-Huong Nguyen,
• Van-Dat Doan and
• Thanh-Danh Nguyen

Beilstein J. Nanotechnol. 2023, 14, 781–792, doi:10.3762/bjnano.14.64

• an in situ reduction process that requires no additional chemicals [16][17]. This technique using polysaccharides such as alginate [18] or chitosan [19] in conjunction with reducing agents enhanced cost efficiency and reduced the amounts of impurities or toxic compounds. AgNPs are widely used as

• agents [33]. The efficiency of the catalyst can be improved by studying different carrier materials [34][35]. Interface factors, including morphology and capping agents, play a significant role in the catalytic activity of AgNPs. The ionotropic gelation mechanism has been recently employed to create

• absorbance of the contaminant, respectively [43]. The catalytic efficiency of the nanocomposite was determined by calculating the rate constant from the slope of the straight line obtained from plots of ln(A/A0) versus reaction time. Effect of pH value and antibacterial assay The impact of pH value on the

In situ magnesiothermic reduction synthesis of a Ge@C composite for high-performance lithium-ion batterie anodes

• Ha Tran Huu,
• Ngoc Phi Nguyen,
• Vuong Hoang Ngo,
• Huy Hoang Luc,
• Minh Kha Le,
• Minh Thu Nguyen,
• My Loan Phung Le,
• Hye Rim Kim,
• In Young Kim,
• Sung Jin Kim,
• Van Man Tran and
• Vien Vo

Beilstein J. Nanotechnol. 2023, 14, 751–761, doi:10.3762/bjnano.14.62

• (plateau at 0.75 V vs Li/Li+) in the first cycle vanished in the next discharge, consistent with the CV observations. Compared to the pure Ge electrode, the Ge@C electrodes exhibit lower specific discharge capacity and Coulombic efficiency (CE) values in the first cycle. As summarized in Table 1, the pure

Cross-sectional Kelvin probe force microscopy on III–V epitaxial multilayer stacks: challenges and perspectives

• Mattia da Lisca,
• José Alvarez,
• James P. Connolly,
• Nicolas Vaissiere,
• Karim Mekhazni,
• Jean Decobert and
• Jean-Paul Kleider

Beilstein J. Nanotechnol. 2023, 14, 725–737, doi:10.3762/bjnano.14.59

• consisting of many layers and interfaces. The study and the comprehension of the mechanisms that take place at the interfaces is crucial for efficiency improvement. In this work, we apply frequency-modulated Kelvin probe force microscopy under ambient conditions to investigate the capability of this

• containing numerous layers and interfaces [1]. The capability to conduct local investigations at the nanoscale level that provide information on the electrical properties of materials and along physical interfaces is becoming crucial for solar photovoltaic device efficiency improvement [2]. Electrical

• enhancing device efficiency [10][11]. Consequently, the experimental demonstration of the sensitivity of KPFM to the narrower layers can be crucial for the investigation and comprehension of local surface properties and charge transport mechanisms at interfaces [12]. Within this context, this work presents

Nanomaterials for photocatalysis and applications in environmental remediation and renewable energy

• Viet Van Pham and
• Wee-Jun Ong

Beilstein J. Nanotechnol. 2023, 14, 722–724, doi:10.3762/bjnano.14.58

• semiconducting nanomaterials, perovskites, or Bi-based nanomaterials are presented to incentivize fine-tuning of current studies and research works on photocatalytic efficiency of nanomaterials [27]. In addition, this Thematic Issue will undoubtedly provide the reader with novel ideas for developing

Investigations on the optical forces from three mainstream optical resonances in all-dielectric nanostructure arrays

• Guangdong Wang and
• Zhanghua Han

Beilstein J. Nanotechnol. 2023, 14, 674–682, doi:10.3762/bjnano.14.53

• the system to break the symmetry, the coupling to external radiations can be enabled with the efficiency controlled by the level of perturbation. These quasi-BICs can provide higher Q-factors and usually higher field enhancement than those of the TD resonance and the anapole mode. As a result, the

Metal-organic framework-based nanomaterials as opto-electrochemical sensors for the detection of antibiotics and hormones: A review

• Akeem Adeyemi Oladipo,
• Saba Derakhshan Oskouei and
• Mustafa Gazi

Beilstein J. Nanotechnol. 2023, 14, 631–673, doi:10.3762/bjnano.14.52

Titania nanoparticles for photocatalytic degradation of ethanol under simulated solar light

• Evghenii Goncearenco,
• Iuliana P. Morjan,
• Claudiu Teodor Fleaca,
• Florian Dumitrache,
• Elena Dutu,
• Monica Scarisoreanu,
• Valentin Serban Teodorescu,
• Alexandra Sandulescu,
• Crina Anastasescu and
• Ioan Balint

Beilstein J. Nanotechnol. 2023, 14, 616–630, doi:10.3762/bjnano.14.51

• found that TiO2 shows a high photocatalytic efficiency in the decomposition of pollutant substances such as dye wastewater [8][9][10][11], soiling [12], and harmful organic materials [13][14][15]. Also, TiO2 powders show promising results for the decomposition of ethanol in various environments [16][17

• ][18]. Moreover, investigations have shown the possibility for applying TiO2 in hydrogen production by water decomposition [19][20][21][22][23]. Given the TiO2 bandgap, it is considered a low-efficiency material in photodriven water splitting, because only 3% of the solar light can be used. Different

• efficiency than rutile [14][31], while the highest photocatalytic activity has been found in mixed anatase/rutile TiO2 [13][32]. One possible explanation is that the difference in the crystal structure and chemical bonding results in different ionization potentials and electron affinities. Exploiting these

Suspension feeding in Copepoda (Crustacea) – a numerical model of setae acting in concert

• Alexander E. Filippov,
• Wencke Krings and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2023, 14, 603–615, doi:10.3762/bjnano.14.50

• mechanical property gradients, the mechanical behavior and the adhesion of setae, and the feeding efficiency of the system. In this context, we set-up a simple dynamic numerical model that takes all of these parameters into account and describes the interaction with food particles and their delivery into the

• field of filtration technologies. Keywords: adhesion; confocal laser scanning microscopy (CLSM); feeding efficiency; feeding structures; mechanical properties; Introduction Particle capture mechanisms are common in a huge variety of aquatic animals, such as polychaetes, bryozoans, bivalves, sponges

• particles, but to which extent is unknown since these parameters cannot be manipulated in living organisms. To test how the feeding efficiency depends on the mechanical property gradients and the adhesion forces of the setae, we here present a numerical model that simulates the interplay between setae

Observation of multiple bulk bound states in the continuum modes in a photonic crystal cavity

• Rui Chen,
• Yi Zheng,
• Xingyu Huang,
• Qiaoling Lin,
• Chaochao Ye,
• Meng Xiong,
• Martijn Wubs,
• Yungui Ma,
• Minhao Pu and
• Sanshui Xiao

Beilstein J. Nanotechnol. 2023, 14, 544–551, doi:10.3762/bjnano.14.45

• influence and to obtain clear Lorentzian resonances, we applied a low-power broadband light source and finely tuned the illumination spot to obtain maximum excitation and collection efficiency of the setup for each mode. Different from the method applied in [30], the illumination spot size is not the same

• as the cavity since the large cavity size (ca. 20 μm) would need a large defocus or an objective with low magnification, which seriously degrades the collection efficiency. By finely scanning the illumination position on the sample, resonances were obtained around 1555 and 1582 nm, as presented in

• Figure 4b and Figure 4c. Interestingly, the resonance peaks around 1582 nm shift in the spectra when the position of the excitation spot is gradually varied, as shown in Figure 4c. The reason of this dependence is the different excitation efficiency at the different illumination positions, which is

Nanoarchitectonics to entrap living cells in silica-based systems: encapsulations with yolk–shell and sepiolite nanomaterials

• Celia Martín-Morales,
• Jorge Fernández-Méndez,
• Pilar Aranda and
• Eduardo Ruiz-Hitzky

Beilstein J. Nanotechnol. 2023, 14, 522–534, doi:10.3762/bjnano.14.43

• bioactivity. Thus, the encapsulation efficiency is improved compared to the approach using a direct contact of cells in a silica matrix. Encapsulated yeast produced ethanol over a period of several days, pointing out the useful biocatalytic potential of the approach and suggesting further optimization of the

On the use of Raman spectroscopy to characterize mass-produced graphene nanoplatelets

• Keith R. Paton,
• Konstantinos Despotelis,
• Naresh Kumar,
• Piers Turner and
• Andrew J. Pollard

Beilstein J. Nanotechnol. 2023, 14, 509–521, doi:10.3762/bjnano.14.42

• step in order to minimise processing time and to maximise separation efficiency. To investigate if Raman spectroscopy can be used for this purpose, a fresh sample of GNPref was prepared as described above, using the same processing conditions. Instead of fresh graphite however, the sediment from the

A mid-infrared focusing grating coupler with a single circular arc element based on germanium on silicon

• Xiaojun Zhu,
• Shuai Li,
• Ang Sun,
• Yongquan Pan,
• Wen Liu,
• Yue Wu,
• Guoan Zhang and
• Yuechun Shi

Beilstein J. Nanotechnol. 2023, 14, 478–484, doi:10.3762/bjnano.14.38

• to a traditional FGC with all-focusing gratings. By optimizing the structural parameters of the CAE, the combination of a tapered linear grating and the CAE can improve the coupling efficiency to 8.61%, which is twice as large as that of the traditional MIR grating couplers. To the best of our

• knowledge, it is the highest coupling efficiency in a full-etch grating coupler based on Ge-on-Si. Moreover, the proposed grating coupler can be used for refractive index (RI) sensing, and the maximum sensitivity is 980.7 nm/RIU when the RI changes from 1 to 1.04. By comparing with traditional grating

• -Si grating coupler with an inverse taper excitation, operating near 3.8 μm wavelength with a maximum coupling efficiency of −11 dB (7.9%) [11]. In 2017, Kang et al. designed and experimentally demonstrated a focusing subwavelength grating (SWG) for an efficient coupling of MIR light to a suspended

Conjugated photothermal materials and structure design for solar steam generation

• Chia-Yang Lin and
• Tsuyoshi Michinobu

Beilstein J. Nanotechnol. 2023, 14, 454–466, doi:10.3762/bjnano.14.36

• on conjugated organic materials. Conjugated organic materials are processed into fibers, membranes, and porous structures. Therefore, nanostructure design based on the concept of nanoarchitectonics is crucial to achieve high SSG efficiency. We discuss the considerations for designing SSG absorbers

• efficiency in solar steam generation (SSG), three factors must be considered, namely solar light absorption, photothermal conversion efficiency, and vaporization efficiency (Figure 1). In addition, the cost of the materials must be taken into consideration as large quantities at low cost are required

• applications will be briefly discussed in the last part. Solar steam generation absorbers Numerous studies have been conducted of various materials and structures of solar energy absorbers for SSG. To achieve a high conversion efficiency in solar steam generation, three key factors must be considered. The

Evaluation of electrosynthesized reduced graphene oxide–Ni/Fe/Co-based (oxy)hydroxide catalysts towards the oxygen evolution reaction

• Karolina Cysewska,
• Marcin Łapiński,
• Marcin Zając,
• Jakub Karczewski,
• Piotr Jasiński and
• Sebastian Molin

Beilstein J. Nanotechnol. 2023, 14, 420–433, doi:10.3762/bjnano.14.34

• production of hydrogen energy is focused mainly on hydrocarbon reforming, which is a low-efficiency and environmentally unfriendly process [1][2]. As an alternative, water electrolysis using renewable energy sources has recently been extensively studied [3]. The main limitation to the efficiency of this

• process is primarily the oxygen evolution reaction (OER) due to its sluggish kinetics resulting in a high overpotential and low efficiency [4]. To overcome this problem, robust anode electrode catalyst materials are required. Since the Ru- and Pt-based catalysts used so far for OER are made using limited

• (η: 320 mV, Eonset: 1.52 V), but the overall activity of the CoNiFe-GO was lowered compared to CoNiFe alone (η: 224 mV, Eonset: 1.41 V). The catalytic efficiency towards the OER can be also assessed by analyzing the Tafel plots of the catalysts (Figure 5c). The Tafel slope for bare nickel foam was

Plasmonic nanotechnology for photothermal applications – an evaluation

• A. R. Indhu,
• L. Keerthana and
• Gnanaprakash Dharmalingam

Beilstein J. Nanotechnol. 2023, 14, 380–419, doi:10.3762/bjnano.14.33

• , a higher efficiency of photon absorption, facile tuning, as well as flexibility in the synthesis of plasmonic nanomaterials. This review of plasmonic PT (PPT) research begins with a theoretical discussion on the plasmonic properties of nanoparticles by means of the quasi-static approximation, Mie

• the dielectric surrounding the plasmonic nanoparticle, apart from the permittivity of the nanoparticle itself. The shift in resonance on incorporation of the nanoparticle into a dielectric will decide its absorbance and hence the efficiency of conversion of the resonance into heat. This has been

• initial thermalization step) up to 1000 °C, the increase in nanoparticle temperature was found to be only 20 °C [84]. This implies by no means a weak efficiency of heat production due to plasmon relaxation, as high temperatures (230 °C for AgNPs for example) are possible, depending on the various factors

Quercetin- and caffeic acid-functionalized chitosan-capped colloidal silver nanoparticles: one-pot synthesis, characterization, and anticancer and antibacterial activities

• Akif Hakan Kurt,
• Elif Berna Olutas,
• Fatma Avcioglu,
• Hamza Karakuş,
• Mehmet Ali Sungur,
• Cansu Kara Oztabag and
• Muhammet Yıldırım

Beilstein J. Nanotechnol. 2023, 14, 362–376, doi:10.3762/bjnano.14.31

• treatment, nanoparticles have an important place to overcome the physiological limitations and to improve therapeutic efficiency [8][9]. Chitosan is a natural polysaccharide biopolymer of different molecular weights bearing amino and hydroxy functional groups [10]. It is the main component of shellfish such

The steep road to nonviral nanomedicines: Frequent challenges and culprits in designing nanoparticles for gene therapy

• Yao Yao,
• Yeongun Ko,
• Grant Grasman,
• Jeffery E. Raymond and
• Joerg Lahann

Beilstein J. Nanotechnol. 2023, 14, 351–361, doi:10.3762/bjnano.14.30

• Need for Multimodal Characterization of Nanoparticles The methods chosen to investigate NP uptake and transfection can be biased towards particular properties and may provide limited insights into the efficiency of NP internalization and efficacy. Typically, cellular uptake and transfection efficiency

• Mechanism Currently, extensive research is focused on the improvement of NP carrier design and gene delivery efficiency [23][24][25][26]. Recent debates within the gene delivery field have highlighted the need for an improved understanding about what cellular/subcellular features underscore the success of

• taken to prevent artifacts [49]. New biological tools, such as SNAP-tag, could be used to label intracellular proteins with high efficiency and low fluorescence background, which would be promising for future co-localization studies investigating NP-mediated endocytic routes [50][51]. The combination of

Polymer nanoparticles from low-energy nanoemulsions for biomedical applications

• Santiago Grijalvo and
• Carlos Rodriguez-Abreu

Beilstein J. Nanotechnol. 2023, 14, 339–350, doi:10.3762/bjnano.14.29

• targeting Renilla luciferase mRNA. Gene inhibition showed an optimum efficiency (40%) at a given nanoparticle/antisense oligonucleotide ratio, which is promising for in vitro cell transfection. When water was replaced with PBS (0.16 M) for the PIC preparation of nanoemulsions starting from

• were obtained upon solvent removal. High colloidal stability (longer than three months without sedimentation), high encapsulation efficiency (>99%), slow drug release (only 15% of the drug after five days), and low cytotoxicity against HeLa cells (cell viability > 80%) were observed. In vivo tests