Site-specific growth of oriented ZnO nanocrystal arrays

• Rekha Bai,
• Dinesh K. Pandya,
• Sujeet Chaudhary,
• Veer Dhaka,
• Vladislav Khayrudinov,
• Jori Lemettinen,
• Christoffer Kauppinen and
• Harri Lipsanen

Beilstein J. Nanotechnol. 2019, 10, 274–280, doi:10.3762/bjnano.10.26

• electrodeposition technique. Further, vertically aligned periodic nanocrystal (NC) growth is engineered at predefined positions on polymer-coated ITO substrates patterned with ordered pores. The vertical alignment of ZnO NCs along the c-axis is achieved via ion-by-ion nucleation-controlled growth for patterned

• ; growth kinetics; nanocrystals; nucleation; twinning; zinc oxide; Introduction Metal oxide semiconductor nanostructures are quite interesting not only in terms of the basic growth mechanism involved in their fabrication, but also due to the large number of applications based on them in the field of

• of a patterned pore size in controlling the growth of array vs branched ZnO NCs is shown. A mechanism based on the nucleation and growth is proposed to understand the oriented/branched twin ZnO NC morphologies. Experimental Growth of ZnO nanocrystals An electrodeposition technique was employed to

Relation between thickness, crystallite size and magnetoresistance of nanostructured La_1−xSr_xMn_yO_3±δ films for magnetic field sensors

• Rasuole Lukose,
• Valentina Plausinaitiene,
• Milita Vagner,
• Nerija Zurauskiene,
• Skirmantas Kersulis,
• Virgaudas Kubilius,
• Karolis Motiejuitis,
• Birute Knasiene,
• Voitech Stankevic,
• Zita Saltyte,
• Martynas Skapas,
• Algirdas Selskis and
• Evaldas Naujalis

Beilstein J. Nanotechnol. 2019, 10, 256–261, doi:10.3762/bjnano.10.24

• deposition temperature influences the magnetic properties of the films [17]. The increase of the deposition rate also results in changes in the crystallite dimensions, leading to a higher number of nucleation sites [18]. In our research, the pulsed-injection metal organic chemical vapour deposition (PI-MOCVD

• ) [19][20] was used to enable easy and reproducible control of the growth rate and nucleation site density by introducing the additional supply source of the precursor solution to the reaction chamber. The novelty of our investigations concerns the growth of La1−xSrxMnyO3±δ (LSMO) films on ceramic Al2O3

Raman study of flash-lamp annealed aqueous Cu₂ZnSnS₄ nanocrystals

• Yevhenii Havryliuk,
• Oleksandr Selyshchev,
• Mykhailo Valakh,
• Alexandra Raevskaya,
• Oleksandr Stroyuk,
• Constance Schmidt,
• Volodymyr Dzhagan and
• Dietrich R. T. Zahn

Beilstein J. Nanotechnol. 2019, 10, 222–227, doi:10.3762/bjnano.10.20

• probable nucleation of secondary phases as described in more detail in the following discussion. In a separate detailed investigation of the influence of film deposition and drying conditions on the formation of secondary phases we found the optimum substrate and environment for significantly reducing the

pH-mediated control over the mesostructure of ordered mesoporous materials templated by polyion complex micelles

• Emilie Molina,
• Mélody Mathonnat,
• Jason Richard,
• Patrick Lacroix-Desmazes,
• Martin In,
• Philippe Dieudonné,
• Thomas Cacciaguerra,
• Corine Gérardin and
• Nathalie Marcotte

Beilstein J. Nanotechnol. 2019, 10, 144–156, doi:10.3762/bjnano.10.14

• surfactants [38][39] as SDA of silica; it was ascribed to an increase of the polycondensation rate of silicic species with pH favoring fast nucleation of small flocs of surfactant and silica [40]. As emphasized by Berggren and Palmqvist [35], these small flocs further grow until reaching a final size that

Threshold voltage decrease in a thermotropic nematic liquid crystal doped with graphene oxide flakes

• Mateusz Mrukiewicz,
• Krystian Kowiorski,
• Paweł Perkowski,
• Rafał Mazur and
• Małgorzata Djas

Beilstein J. Nanotechnol. 2019, 10, 71–78, doi:10.3762/bjnano.10.7

• the phase transition temperature TI-N, the transmission of light starts to increase due to the nucleation of the nematic phase (bright state). In the experiment, the clearing temperature of the pure 5CB (33.0 °C) was 2 °C below that of previous reports [34][36]. The effect of the lower TI-N is related

Femtosecond laser-assisted fabrication of chalcopyrite micro-concentrator photovoltaics

• Franziska Ringleb,
• Stefan Andree,
• Berit Heidmann,
• Jörn Bonse,
• Katharina Eylers,
• Owen Ernst,
• Torsten Boeck,
• Martina Schmid and
• Jörg Krüger

Beilstein J. Nanotechnol. 2018, 9, 3025–3038, doi:10.3762/bjnano.9.281

• enhance the efficiency of planar-cell technologies while saving absorber material. Here, two laser-based bottom-up processes for the fabrication of regular arrays of CuInSe2 and Cu(In,Ga)Se2 microabsorber islands are presented, namely one approach based on nucleation and one based on laser-induced forward

• and opportunities of the novel approaches to realize this cell concept. The first approach for microabsorber fabrication summarized here is based on the growth of metallic precursors (indium islands) on laser-structured substrates (molybdenum on glass) by means of physical vapor deposition (nucleation

• thus summed up in a following joint part, which deals with the characterization of the resulting cells under different lighting conditions. Fabrication of metallic precursors Nucleation approach The nucleation approach is based on the arrangement of metallic precursors by island growth on laser

Hydrogen-induced plasticity in nanoporous palladium

• Markus Gößler,
• Eva-Maria Steyskal,
• Markus Stütz,
• Norbert Enzinger and
• Roland Würschum

Beilstein J. Nanotechnol. 2018, 9, 3013–3024, doi:10.3762/bjnano.9.280

• desorption the PdHβ-to-PdHα transition follows a classical nucleation-and-growth mechanism, i.e., the α-phase forms nuclei in the β-matrix that begin to grow [37]. During the hydride phase transition lattice constants of both phases may differ from their equilibrium values, which are quoted in the

• -phase in the PdHβ-matrix, as a bulk compression by the PdHβ-phase can also affect the PdHα-nuclei, provided they have the lower volume fraction. Nucleation of the PdHα on the sample surface attenuates the compressive effect by PdHβ, compared to nuclei surrounded by the β-phase. Overshooting behaviour is

Layered calcium phenylphosphonate: a hybrid material for a new generation of nanofillers

• Kateřina Kopecká,
• Ludvík Beneš,
• Klára Melánová,
• Vítězslav Zima,
• Petr Knotek and
• Kateřina Zetková

Beilstein J. Nanotechnol. 2018, 9, 2906–2915, doi:10.3762/bjnano.9.269

• as nucleation centers; however, these methods were not successful. Although the shape of the particles differs minimally as they are rod-shaped in each case, the thickness of the individual lamellas differs significantly with the selected procedure, as was confirmed by the atomic force microscopy

Site-controlled formation of single Si nanocrystals in a buried SiO₂ matrix using ion beam mixing

• Xiaomo Xu,
• Thomas Prüfer,
• Daniel Wolf,
• Hans-Jürgen Engelmann,
• Lothar Bischoff,
• René Hübner,
• Karl-Heinz Heinig,
• Wolfhard Möller,
• Stefan Facsko,
• Johannes von Borany and
• Gregor Hlawacek

Beilstein J. Nanotechnol. 2018, 9, 2883–2892, doi:10.3762/bjnano.9.267

• on the other hand leads to a concentration of the highly mixed volume in the center of the irradiated line and thus predefines the nucleation site of the NC near the position of the highest Si excess. The maximum mixing efficiency dM/dy in the buried oxide – in the center of the line – is

Comparative biological effects of spherical noble metal nanoparticles (Rh, Pd, Ag, Pt, Au) with 4–8 nm diameter

• Alexander Rostek,
• Marina Breisch,
• Kevin Pappert,
• Kateryna Loza,
• Marc Heggen,
• Manfred Köller,
• Christina Sengstock and
• Matthias Epple

Beilstein J. Nanotechnol. 2018, 9, 2763–2774, doi:10.3762/bjnano.9.258

• noble metals has been described in the literature [54]. The shape-controlled synthesis of noble metal nanostructures can be achieved by different experimental procedures that aim to control nucleation, crystal growth, and finally, colloidal stabilization [55][56][57][58]. A very prominent method is the

Oriented zinc oxide nanorods: A novel saturable absorber for lasers in the near-infrared

• Pavel Loiko,
• Tanujjal Bora,
• Josep Maria Serres,
• Haohai Yu,
• Magdalena Aguiló,
• Francesc Díaz,
• Uwe Griebner,
• Valentin Petrov,
• Xavier Mateos and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2018, 9, 2730–2740, doi:10.3762/bjnano.9.255

• a hydrothermal process [43]. A ZnO seed layer was initially deposited on cleaned glass slides by spraying 5 mM zinc acetate dehydrate solution in ethanol at 350 °C. The role of this seed layer was to provide nucleation sites for the subsequent growth of ZnO NRs. The seeded substrates were then

Optimization of Mo/Cr bilayer back contacts for thin-film solar cells

• Nima Khoshsirat,
• Fawad Ali,
• Vincent Tiing Tiong,
• Mojtaba Amjadipour,
• Hongxia Wang,
• Mahnaz Shafiei and
• Nunzio Motta

Beilstein J. Nanotechnol. 2018, 9, 2700–2707, doi:10.3762/bjnano.9.252

• such as glass or stainless steel [17][18][19][20][21]. Cr forms an oxide interface layer by scavenging the oxygen available on the glass surface during the sputtering process. This creates nucleation centers and promotes nucleation of the next deposited material (in this case Mo), leading to a strong

Size-selected Fe₃O₄–Au hybrid nanoparticles for improved magnetism-based theranostics

• Maria V. Efremova,
• Yulia A. Nalench,
• Eirini Myrovali,
• Anastasiia S. Garanina,
• Ivan S. Grebennikov,
• Polina K. Gifer,
• Maxim A. Abakumov,
• Marina Spasova,
• Makis Angelakeris,
• Alexander G. Savchenko,
• Michael Farle,
• Natalia L. Klyachko,
• Alexander G. Majouga and
• Ulf Wiedwald

Beilstein J. Nanotechnol. 2018, 9, 2684–2699, doi:10.3762/bjnano.9.251

• be adjusted by heterogeneous nucleation of NPs on noble metal seeds [21][22]. Additionally, such bifunctional Fe3O4–Au NPs are potentially applicable for targeted drug delivery, enhanced hyperthermia, multimodal imaging and theranostics [8][23][24][25][26][27]. In this work, we present the first size

Au–Si plasmonic platforms: synthesis, structure and FDTD simulations

• Anna Gapska,
• Marcin Łapiński,
• Paweł Syty,
• Wojciech Sadowski,
• Józef E. Sienkiewicz and
• Barbara Kościelska

Beilstein J. Nanotechnol. 2018, 9, 2599–2608, doi:10.3762/bjnano.9.241

• explained through dewetting. Dewetting of metallic thin and ultra-thin films, although known and widely studied for many years, it is still an interesting phenomenon [11][12][13][14][15][16][17][18]. Dewetting of films is driven by two main processes. The first of them is based on nucleation and growth of

• holes. The growth of holes occurs through the gathering of material from which the layer is made, along the perimeter of the hole, which results in a raised rim around the hole. Nucleation can occur in two ways, as homogeneous nucleation, when holes are caused by small thermal-density fluctuations

• (homogeneous dewetting), or as heterogeneous nucleation, which is caused by defects in the layer or on the interface of the layer and the substrate (heterogeneous dewetting). In the second process, called spinodal dewetting, instability of the film against thermally activated surface waves leads to spontaneous

Pattern generation for direct-write three-dimensional nanoscale structures via focused electron beam induced deposition

• Lukas Keller and
• Michael Huth

Beilstein J. Nanotechnol. 2018, 9, 2581–2598, doi:10.3762/bjnano.9.240

• applied. This process is not only challenging due to the need for accurate alignment of all consecutive slices, but also extremely time consuming, depending on the required resolution in the vertical dimension. Other methods are two-photon lithography [5], heterogeneous nucleation [6] or template-based

Nanocellulose: Recent advances and its prospects in environmental remediation

• Katrina Pui Yee Shak,
• Yean Ling Pang and
• Shee Keat Mah

Beilstein J. Nanotechnol. 2018, 9, 2479–2498, doi:10.3762/bjnano.9.232

• ) [101]. The abundant surface –OH groups act as hydrophilic sites to accelerate nucleation and growth of inorganic particles, consequently controlling the morphology, particle size, and crystallinity [107]. Such readily available surface –OH groups offer an ideal platform for the fabrication of hybrid

Evidence of friction reduction in laterally graded materials

• Roberto Guarino,
• Gianluca Costagliola,
• Federico Bosia and
• Nicola Maria Pugno

Beilstein J. Nanotechnol. 2018, 9, 2443–2456, doi:10.3762/bjnano.9.229

• have been used in many recent studies to describe aspects of the transition from static to dynamic friction, the nucleation of rupture wave fronts, and the effects of patterning [32][33][34][35][36]. The SBM method is usually computationally faster than FEM, thus it is more practical for a qualitative

Droplet-based synthesis of homogeneous magnetic iron oxide nanoparticles

• Christian D. Ahrberg,
• Ji Wook Choi and
• Bong Geun Chung

Beilstein J. Nanotechnol. 2018, 9, 2413–2420, doi:10.3762/bjnano.9.226

• nucleation and growth predicts a narrowing of the particle size distribution with increasing reaction time [35][36], the opposite is observed in our experiments. This is probably due to classical models not including effects such as Ostwald ripening and, in our case more significant, the aggregation of

Pinning of a ferroelectric Bloch wall at a paraelectric layer

• Vilgelmina Stepkova and
• Jiří Hlinka

Beilstein J. Nanotechnol. 2018, 9, 2356–2360, doi:10.3762/bjnano.9.220

• parallel to it. Since the domain wall has lower energy when located right at the SrTiO3 layer, one can speculate that a pair of such layers can be used as a nucleation center for favoring antiparallel ferroelectric domain with desirable crystallographic orientation of adjacent domain walls. For example

Electrospun one-dimensional nanostructures: a new horizon for gas sensing materials

• Muhammad Imran,
• Nunzio Motta and
• Mahnaz Shafiei

Beilstein J. Nanotechnol. 2018, 9, 2128–2170, doi:10.3762/bjnano.9.202

• ]. The average diameter of as-spun fibers is 412 nm which, after annealing, reduces to 315 nm. The fiber diameter increases with increasing Au content. The average diameters of the WO3–Au-0.01M, and WO3–Au-0.1M composite NFs are 350 nm, and 370 nm, respectively. Au NPs act as nucleation sites (seed) on

Spin-coated planar Sb₂S₃ hybrid solar cells approaching 5% efficiency

• Pascal Kaienburg,
• Benjamin Klingebiel and
• Thomas Kirchartz

Beilstein J. Nanotechnol. 2018, 9, 2114–2124, doi:10.3762/bjnano.9.200

• ] – especially when devices are compared that apply the same HTM and Sb2S3 deposition method [26][29][30][31]. Typically Sb2S3 is fabricated via chemical bath deposition (CBD) [2][39][40][41] with the drawback of a complex growth mechanism that includes heterogeneous nucleation and exponential growth which

Recent highlights in nanoscale and mesoscale friction

• Andrea Vanossi,
• Dirk Dietzel,
• Andre Schirmeisen,
• Ernst Meyer,
• Rémy Pawlak,
• Thilo Glatzel,
• Marcin Kisiel,
• Shigeki Kawai and
• Nicola Manini

Beilstein J. Nanotechnol. 2018, 9, 1995–2014, doi:10.3762/bjnano.9.190

• frictional sliding observed in the case of overlayer/substrate lattice mismatch. Nucleation dynamics characterizes the depinning mechanism of a stiff commensurate colloidal monolayer [167]. In contrast, if the interface is characterized by a lattice mismatch, the presence/absence of static friction depends

Synthesis of carbon nanowalls from a single-source metal-organic precursor

• André Giese,
• Sebastian Schipporeit,
• Volker Buck and
• Nicolas Wöhrl

Beilstein J. Nanotechnol. 2018, 9, 1895–1905, doi:10.3762/bjnano.9.181

• number of dangling bonds that act as nucleation sites for randomly orientated carbon nanoflakes. 2D growth and the subsequent formation of (few-layer) graphene sheets follow. The nanoflakes being almost vertically aligned on the substrate grow fastest to finally form vertically standing nanosheets. The

• carbon solubility, and it was expected, that this should have a strong influence on the nucleation and growth process of the CNWs. Three different substrate temperatures were used to investigate the influence on the growth process (350, 425 and 500 °C). Furthermore, the bias voltage was set to values of

• length for the growth species at the surface is larger and nucleation occurs more separated in space (similar to the Volmer–Weber growth). Nanoflakes can grow subsequently from these nucleation sites leading to the formation of straight CNWs. This process is similar to the model suggested by Kondo and co

Synthesis of hafnium nanoparticles and hafnium nanoparticle films by gas condensation and energetic deposition

• Irini Michelakaki,
• Nikos Boukos,
• Dimitrios A. Dragatogiannis,
• Spyros Stathopoulos,
• Costas A. Charitidis and
• Dimitris Tsoukalas

Beilstein J. Nanotechnol. 2018, 9, 1868–1880, doi:10.3762/bjnano.9.179

• target (99.95%). Due to collisions with Ar gas, cooling of the sputtered metal atoms takes place, leading to a supersaturated metal atom vapor. Collisions between the cooled metal atoms lead to nucleation and growth of initial clusters. Collisions between these initial cluster ‘seeds’ followed by

Controllable one-pot synthesis of uniform colloidal TiO₂ particles in a mixed solvent solution for photocatalysis

• Jong Tae Moon,
• Seung Ki Lee and
• Ji Bong Joo

Beilstein J. Nanotechnol. 2018, 9, 1715–1727, doi:10.3762/bjnano.9.163

• nucleation/growth rate of TBOT and its hydrolysate is finely controlled by regulating the ethanol–acetonitrile ratio. The spherical curvature and smoothness of the TiO2 layers was also tuned using the ethanol–acetonitrile solvent conditions that resulted from the controlled diffusion rate of TBOT and its

• hydrolysate in a mixed solvent [14][32][33]. Without a sacrificial core material, it should be noted that this sol–gel strategy allows the colloidal TiO2 particles to have finely tuned properties due to the well-controlled nucleation/growth rate of TBOT in mixed solvent conditions. Although this sol–gel

• the particle shape became irregular. These phenomena can be explained by not only the solubility of TBOT and the surfactant, but also by the nucleation-growth kinetics of TBOT in different solvent conditions. It is well-known that acetonitrile is more hydrophobic than ethanol [14]. As the relative ACN