A novel approach to pulsed laser deposition of platinum catalyst on carbon particles for use in polymer electrolyte membrane fuel cells

• Bogusław Budner,
• Wojciech Tokarz,
• Sławomir Dyjak,
• Andrzej Czerwiński,
• Bartosz Bartosewicz and
• Bartłomiej Jankiewicz

Beilstein J. Nanotechnol. 2023, 14, 190–204, doi:10.3762/bjnano.14.19

• . Materials A, C, and D are characterized by a higher percentage of the two-electron reduction of oxygen in the mechanism than in the case of the commercial catalyst, which translates into a higher contribution of hydrogen peroxide in the reaction products (Figure 5d). Material C excels in this comparison

• , enough water to moisten the membrane. A self-propelling mechanism is created, but there are a low current, insufficient water in the diaphragm, a high internal diaphragm resistance, and a power drop. The attempt to support the cell by increasing the cathode hydration (to about 125% RH) did not improve

Structural, optical, and bioimaging characterization of carbon quantum dots solvothermally synthesized from o-phenylenediamine

• Zoran M. Marković,
• Milica D. Budimir,
• Martin Danko,
• Dušan D. Milivojević,
• Pavel Kubat,
• Danica Z. Zmejkoski,
• Vladimir B. Pavlović,
• Marija M. Mojsin,
• Milena J. Stevanović and
• Biljana M. Todorović Marković

Beilstein J. Nanotechnol. 2023, 14, 165–174, doi:10.3762/bjnano.14.17

• generate singlet oxygen. Both obtained results related to production of ROS indicate that there are no reactive centers in the structure of the carbon core that could enable the production of ROS. Antibacterial testing The antibacterial activity of CQDs differs from the antibacterial mechanism of

Batch preparation of nanofibers containing nanoparticles by an electrospinning device with multiple air inlets

• Dong Wei,
• Chengwei Ye,
• Adnan Ahmed and
• Lan Xu

Beilstein J. Nanotechnol. 2023, 14, 141–150, doi:10.3762/bjnano.14.15

• more uniform distribution of nanoparticles. The mechanism of batch preparation of functional nanofibers containing ZnO nanoparticles by the device was studied through experiments and theoretical analysis. The experimental data are in good agreement with the theoretical analysis results, which showed

• addition, experiments and theoretical analysis were used to discuss the spinning mechanism of this new device for the batch preparation of nanofibers, and the optimal spinning parameters were determined. Materials and Methods Materials Polyacrylonitrile (PAN, average molecular weight 15000) and zinc oxide

Formation of nanoflowers: Au and Ni silicide cores surrounded by SiO_x branches

• Feitao Li,
• Siyao Wan,
• Dong Wang and
• Peter Schaaf

Beilstein J. Nanotechnol. 2023, 14, 133–140, doi:10.3762/bjnano.14.14

• to developing different kinds of nanofabrication methods during the past decades. For example, silicon oxide (SiOx) nanostructures can be grown by the catalyzing effect of Au nanoparticles based on the vapor–liquid–solid (VLS) mechanism [1][2][3][4]. Au–SiOx nanoflowers consisting of Au nanoparticles

• ][24][25]. Apart from Au, both Ni and Ag can also catalyze the growth of NWs based on the VLS mechanism [26][27][28], and Si NWs have been grown using alloyed AuAg nanoparticles [29]. Au–SiOx nanoflowers have been fabricated by combining the dewetting of Au thin films and the growth of NWs based on the

• VLS mechanism [3][4]. This has inspired the possible fabrication of nanoflowers from multicomponent nanoparticles and surrounding SiOx NWs, on which, to date, there is no relevant research. The addition of the second element brings more tailorable properties and broadens the range of applications. For

Intermodal coupling spectroscopy of mechanical modes in microcantilevers

• Ioan Ignat,
• Bernhard Schuster,
• Jonas Hafner,
• MinHee Kwon,
• Daniel Platz and
• Ulrich Schmid

Beilstein J. Nanotechnol. 2023, 14, 123–132, doi:10.3762/bjnano.14.13

• , these improvements have yet to find a practical way to AFM. As a solution, we investigate here a mechanism in which individual mechanical eigenmodes of a microcantilever couple to one another, mimicking optomechanical techniques to reduce thermal noise. We have a look at the most commonly used modes in

Antimicrobial and mechanical properties of functionalized textile by nanoarchitectured photoinduced Ag@polymer coating

• Jessica Plé,
• Marine Dabert,
• Helene Lecoq,
• Sophie Hellé,
• Lydie Ploux and
• Lavinia Balan

Beilstein J. Nanotechnol. 2023, 14, 95–109, doi:10.3762/bjnano.14.11

• avoiding planktonic bacteria proliferation by the direct action of silver ions. The capacity of 3 wt % and 5 wt %-loaded textiles to inhibit the growth of E. coli is thought to be related to this mechanism. Concerning the fungus, similarly to bacteria, the amount of loaded silver does not have a

Atmospheric water harvesting using functionalized carbon nanocones

• Fernanda R. Leivas and
• Marcia C. Barbosa

Beilstein J. Nanotechnol. 2023, 14, 1–10, doi:10.3762/bjnano.14.1

• water. The cactus for example has spikes where droplets move from the tip to the base, or from the higher to the lower Laplace area. One mechanism developed by nature to capture liquid water from water vapor is present in the Namibian desert beetle, which collects water from morning steam in the desert

• approach, the variable that determines the wettability of the surface is the potential well defined by εr. The higher the value of εr, the more hydrophilic the surface is. Here we employed 1.5 ≥ εr ≥ 0.8. The water harvesting has been modeled according to the following mechanism: First, the vapor generated

Observation of collective excitation of surface plasmon resonances in large Josephson junction arrays

• Roger Cattaneo,
• Mikhail A. Galin and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2022, 13, 1578–1588, doi:10.3762/bjnano.13.132

• , the standing wave imprints its order on the array, facilitating mutual phase-locking of junctions. This provides an indirect coupling mechanism, allowing for the synchronization of junctions, which do not directly interact with each other. Our results demonstrate that electrodes can effectively work

• as a common external resonator, facilitating long-range phase-locking of large junction arrays with sizes larger than the emitted wavelength. Keywords: cavity modes; Josephson junctions; synchronization mechanism; THz radiation; Introduction Terahertz sources of electromagnetic waves (EMWs) in the

• matching with free space and improves the radiation power efficiency. The cavity modes in the electrodes are excited collectively by the JJs, which are, in turn, mutually phase-locked by the modes. This provides a positive feedback mechanism allowing for the synchronization of large arrays without direct

Induced electric conductivity in organic polymers

• Konstantin Y. Arutyunov,
• Anatoli S. Gurski,
• Vladimir V. Artemov,
• Alexander L. Vasiliev,
• Azat R. Yusupov,
• Danfis D. Karamov and
• Alexei N. Lachinov

Beilstein J. Nanotechnol. 2022, 13, 1551–1557, doi:10.3762/bjnano.13.128

• temperature of 150–200 °C for 45 min. Depending on the concentration of the solutions, it was possible to obtain films of various thicknesses from several nm to several μm. The formation of films from dilute solutions occurs according to the mechanism of linear or loop adsorption, when macromolecules at the

• is significantly different. In particular, as the voltage increases, there is the tendency for the current flowing through the heterostructure to saturate. Previously [2], it was found that at high temperatures, the mechanism of overcoming the barrier at the metal/polymer contact is satisfactorily

• described in terms of the injection current model limited by the space charge. At low temperatures, the tunneling mechanism is the predominant mechanism. Figure 3 shows the current–voltage characteristics of Pb–PDP–Pb structures with different PDP film thicknesses. With increase of the polymer film

Photoelectrochemical water oxidation over TiO₂ nanotubes modified with MoS₂ and g-C₃N₄

• Phuong Hoang Nguyen,
• Thi Minh Cao,
• Tho Truong Nguyen,
• Hien Duy Tong and
• Viet Van Pham

Beilstein J. Nanotechnol. 2022, 13, 1541–1550, doi:10.3762/bjnano.13.127

• with previous publications [50][51][52]. Figure 5 shows the results of electrochemical impedance spectroscopy (EIS), that is, Nyquist and Mott–Schottky plots of the materials, which give information about the charge transfer mechanism at the interface. In Figure 5a, the Nyquist plots of the samples all

• carrier concentration in MoS2/TNAs sample such in Figure 4. The mechanism for the enhanced activity of the heterojunctions can be explained by the Mott–Schottky results in Figure 5b,c. Generally, all samples show positive slopes, which proves that they are n-type semiconductors [53]. Equation 2 shows the

Non-stoichiometric magnetite as catalyst for the photocatalytic degradation of phenol and 2,6-dibromo-4-methylphenol – a new approach in water treatment

• Joanna Kisała,
• Anna Tomaszewska and
• Przemysław Kolek

Beilstein J. Nanotechnol. 2022, 13, 1531–1540, doi:10.3762/bjnano.13.126

• halogenated aromatic pollutants. The particularly high degradation efficiency regarding halogen-containing DBMP molecules and the yield of bromide ions indicate that DBMP degradation follows a mixed reduction–oxidation mechanism. DBMP molecules interact with the magnetite surface, enabling them to react with

• influenced by the interaction between the DBMP molecule and the magnetite surface. When bonded to the catalyst’s surface, molecules can react with the electrons being generated. Therefore, we postulate a mixed reductive–oxidative mechanism of DBMP degradation on magnetite. In conclusion, magnetite can be an

A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• photocatalytic, photoelectrochemical, and photovoltaic–photoelectrochemical systems. The features and the operating mechanism of photoelectrochemical water splitting are detailed in [10][11]. Photoelectrochemical water splitting has attracted much research interest because it has some outstanding advantages. The

In search of cytotoxic selectivity on cancer cells with biogenically synthesized Ag/AgCl nanoparticles

• Mitzi J. Ramírez-Hernández,
• Mario Valera-Zaragoza,
• Omar Viñas-Bravo,
• Ariana A. Huerta-Heredia,
• Miguel A. Peña-Rico,
• Erick A. Juarez-Arellano,
• David Paniagua-Vega,
• Eduardo Ramírez-Vargas and
• Saúl Sánchez-Valdes

Beilstein J. Nanotechnol. 2022, 13, 1505–1519, doi:10.3762/bjnano.13.124

• metalloproteinases (MMPs), the activity of which is favored by reactive species, and they have been shown to be directly involved in death mechanisms such as apoptosis, causing damage at the cell membrane level. In contrast, in monocytes, which are also high in MMPs, their activation mechanism is largely dependent

• on the production of NOs. Perhaps this fact is an explanation for the selectivity of the findings. However, a more in-depth study of this mechanism is necessary. These data have never been reported before, so their mechanistic interpretation and understanding requires further investigation. In order

Frequency-dependent nanomechanical profiling for medical diagnosis

• Santiago D. Solares and
• Alexander X. Cartagena-Rivera

Beilstein J. Nanotechnol. 2022, 13, 1483–1489, doi:10.3762/bjnano.13.122

• optical imaging, the device could be equipped with one or more piezoelectrically excited membranes coupled with a sensing mechanism, such as an AFM cantilever or other type of mechanical sensor (similar stand-alone developments already exist [31][32]). The mechanical response of the membrane could be

• piezoelectrically actuated membrane equipped with a mechanical response sensing mechanism [31][32]. Illustration of a 2D adherent cell indented by a micrometer-sized spherical AFM probe, as well as storage and loss modulus calculated from the parameterized Generalized Maxwell model for 2D adherent normal and

Structural studies and selected physical investigations of LiCoO₂ obtained by combustion synthesis

• Monika Michalska,
• Paweł Ławniczak,
• Tomasz Strachowski,
• Adam Ostrowski and
• Waldemar Bednarski

Beilstein J. Nanotechnol. 2022, 13, 1473–1482, doi:10.3762/bjnano.13.121

• conductivity and comparison of electrical properties of LCO powders) by using impedance spectroscopy (IS). Our studies provide important information on the mechanism of formation, particle growth, size, shape, and the control of these parameters during synthesis. Materials and Methods Synthesis of LiCoO2

Double-layer symmetric gratings with bound states in the continuum for dual-band high-Q optical sensing

• Chaoying Shi,
• Jinhua Hu,
• Xiuhong Liu,
• Junfang Liang,
• Jijun Zhao,
• Haiyan Han and
• Qiaofen Zhu

Beilstein J. Nanotechnol. 2022, 13, 1408–1417, doi:10.3762/bjnano.13.116

• ]. Particularly, the QBIC sensor enables highly accurate detection of environmental changes by reading variations in the spectrum. However, numerous research works have focused on the BIC mechanism of single-mode resonance [26][28], which may limit its application. In this work, we proposed a double-layer

• length h, which is necessary for refractive index sensing applications. When the QBIC is applied to refractive index sensing, it enables more sensitive detection owing to its high figure of merit (FOM), the physical mechanism of which uses resonant position variations to detect changes in the refractive

Orally administered docetaxel-loaded chitosan-decorated cationic PLGA nanoparticles for intestinal tumors: formulation, comprehensive in vitro characterization, and release kinetics

• Sedat Ünal,
• Osman Doğan and
• Yeşim Aktaş

Beilstein J. Nanotechnol. 2022, 13, 1393–1407, doi:10.3762/bjnano.13.115

• nanoparticle material is released from the polymeric structure on the basis of diffusion as the major mechanism. It has been confirmed by mathematical modeling that the release is based on diffusion [10][61]. In contrast, the Peppas–Sahlin model describes the drug release from CS/DCX-PLGA NPs. The Peppas

• diffusional exponent indicating the drug release mechanism is represented by “n” in the Korsmeyer–Peppas model while “m” represents the same parameter in the Peppas–Sahlin model [63]. In order to examine the Peppas–Sahlin model more deeply, the diffusional exponent value m was computed as 0.450 for the CS/DCX

LED-light-activated photocatalytic performance of metal-free carbon-modified hexagonal boron nitride towards degradation of methylene blue and phenol

• Nirmalendu S. Mishra and
• Pichiah Saravanan

Beilstein J. Nanotechnol. 2022, 13, 1380–1392, doi:10.3762/bjnano.13.114

• MBN-80 and other photocatalytic materials reported in the literature is discussed in Table 1. Photocatalytic mechanism The detailed photocatalytic mechanism is explained in Figure 8a,b. The CB potential of MBN-80 (−1.7 V vs NHE) is more negative than that of O2/O2−• (−0.33 V vs NHE) [44]. Conversely

• taking part in the degradation mechanism. The CTA was achieved by taking 1 mmol of p-benzoquinone, isopropyl alcohol (IPA), AgNO3, and triethanolamine (TEA) as quenching agents to trap O2−•, •OH, e−, and h+, respectively [46]. The outcome of CTA was depicted in Figure 8b. The addition of TEA demonstrated

Supramolecular assembly of pentamidine and polymeric cyclodextrin bimetallic core–shell nanoarchitectures

• Alexandru-Milentie Hada,
• Nina Burduja,
• Marco Abbate,
• Claudio Stagno,
• Guy Caljon,
• Louis Maes,
• Nicola Micale,
• Massimiliano Cordaro,
• Angela Scala,
• Antonino Mazzaglia and
• Anna Piperno

Beilstein J. Nanotechnol. 2022, 13, 1361–1369, doi:10.3762/bjnano.13.112

• the same experimental conditions showed poor stability [14]. Although we are currently unable to elucidate the comprehensive mechanism that occurs during the reduction processes, we suppose that the direct reduction of gold ions by PolyCD takes place at sites involved in the nucleation/growing process

• silver shell (Figure 2B, Figure 2C). To further investigate the extraordinary ability of PolyCD to produce and to stabilize gold-based NPs and to shed light on the mechanism of Au(III) reduction by PolyCD, NMR analyses were carried out. The colloidal solutions of nanoG and nanoGS were lyophilized and

Straight roads into nowhere – obvious and not-so-obvious biological models for ferrophobic surfaces

• Wilfried Konrad,
• Christoph Neinhuis and
• Anita Roth-Nebelsick

Beilstein J. Nanotechnol. 2022, 13, 1345–1360, doi:10.3762/bjnano.13.111

• network flow of water molecules is formed whose upper end is fastened within the leaves where transpiration takes place at the living leaf cells. From there it “hangs down” through twigs, trunks, stem and roots into the ground water. The stability of this transport mechanism relies on the comparatively

• , a mechanism was suggested that would be able to isolate a refilling conduit during the repair process [43]. An essential element of this special isolation mechanism is the formation of a stable interface (denoted “interface” in Figure 4e), which separates water and air within the pit cavity, thereby

• isolating the pit membrane from water (see appendix C). Various research was dedicated to this putative mechanism. Studies contributed by Konrad and Roth-Nebelsick [44][45], who considered the interfacial physics of the proposed mechanism, provided evidence that such an interface may be possible within pits

Near-infrared photoactive Ag-Zn-Ga-S-Se quantum dots for high-performance quantum dot-sensitized solar cells

• Roopakala Kottayi,
• Ilangovan Veerappan and
• Ramadasse Sittaramane

Beilstein J. Nanotechnol. 2022, 13, 1337–1344, doi:10.3762/bjnano.13.110

• AZGSSe QDs to TiO2 NFs with minimized charge recombination rate [35][36][37]. PV cell studies The electron transfer mechanism of the fabricated QDSC was examined by using impedance analysis. The impedance spectrum plotted in the form of a Nyquist plot (Figure 7) was fitted with the equivalent circuit

Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications

• Vishal Dutta,
• Ankush Chauhan,
• Ritesh Verma,
• C. Gopalkrishnan and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109

• purification [31][32][33][34][35]. However, the present report focuses on understanding the role of different Bi-based photocatalysts concerning their synthesis method and enhancement. The mechanism of photocatalysts for different applications has been described for the type or nature of the photocatalyst

• identifying the most active species led to a credible mechanism for RhB degradation (Figure 4b,c). It has been shown that the carrier combination centers may easily get doped at a deep level, considerably lowering photocatalytic activity. As a result, optimizing the electrical configuration by using suitable

• increased photocatalytic efficiency was the formation of heterojunctions together with the loading of quantum dots, which enhanced the light-harvesting efficiency and promoted the separation and migration of photogenerated carriers. The fabricated composites followed the S-scheme charge transfer mechanism

Enhanced electronic transport properties of Te roll-like nanostructures

• E. R. Viana,
• N. Cifuentes and
• J. C. González

Beilstein J. Nanotechnol. 2022, 13, 1284–1291, doi:10.3762/bjnano.13.106

• recaptured by acceptors and cannot be thermally excited back to the valence band [30][33]. In this case, the thermally activated conduction of free holes becomes less important, and hole hopping directly between acceptor states in the impurity band becomes the primary conduction mechanism [30][31][32][33

Studies of probe tip materials by atomic force microscopy: a review

• Ke Xu and
• Yuzhe Liu

Beilstein J. Nanotechnol. 2022, 13, 1256–1267, doi:10.3762/bjnano.13.104

• response mechanism was further explored to construct a highly selective and sensitive silver-doped gold-based bimetallic nanocluster fluorescent probe. Metal nanowire probe Nanowires have become a hot research topic as high aspect ratio structures [28][29][30]. In addition to their plain geometry, the

Role of titanium and organic precursors in molecular layer deposition of “titanicone” hybrid materials

• Arbresha Muriqi and
• Michael Nolan

Beilstein J. Nanotechnol. 2022, 13, 1240–1255, doi:10.3762/bjnano.13.103

• (MLD) allows the deposition of these hybrid films using sequential, self-limiting reactions, similar to atomic layer deposition (ALD). In this paper, we use first principles density functional theory (DFT) to investigate the growth mechanism of titanium-containing hybrid organic–inorganic MLD films

• density functional theory (DFT) simulations have recently been used to explore the reaction mechanism in Ti–organic MLD film growth [42], such a study that explores the surface reactions and the precursor chemistry in titanicone MLD film growth and the role of the precursor chemistries is still lacking

• . In this study we investigate the molecular mechanism of formation of titanicone films on anatase TiO2, rutile TiO2 and Al2O3 surfaces using TiCl4 or Ti(DMA)4 as Ti source and EG or GL as organic components. Calculated energetics suggest a higher reactivity of Ti(DMA)4 towards the selected surfaces