Metal–dielectric hybrid nanoantennas for efficient frequency conversion at the anapole mode

• Valerio F. Gili,
• Lavinia Ghirardini,
• Davide Rocco,
• Giuseppe Marino,
• Ivan Favero,
• Iännis Roland,
• Giovanni Pellegrini,
• Lamberto Duò,
• Marco Finazzi,
• Luca Carletti,
• Andrea Locatelli,
• Aristide Lemaître,
• Dragomir Neshev,
• Costantino De Angelis,
• Giuseppe Leo and
• Michele Celebrano

Beilstein J. Nanotechnol. 2018, 9, 2306–2314, doi:10.3762/bjnano.9.215

• realization of coherent light sources [2], SHG is a fundamental tool for the analysis and characterization of the crystal structure of solid materials [3][4][5]. The background-free character of SHG makes it an attractive tool for imaging biological tissues [6] and investigating structural and conformational

Hierarchical heterostructures of Bi₂MoO₆ microflowers decorated with Ag₂CO₃ nanoparticles for efficient visible-light-driven photocatalytic removal of toxic pollutants

• Shijie Li,
• Wei Jiang,
• Shiwei Hu,
• Yu Liu,
• Yanping Liu,
• Kaibing Xu and
• Jianshe Liu

Beilstein J. Nanotechnol. 2018, 9, 2297–2305, doi:10.3762/bjnano.9.214

• -10, ACO/BMO-20, ACO/BMO-30, and ACO/BMO-50, respectively. The crystal structure of Bi2MoO6, Ag2CO3, and Ag2CO3/Bi2MoO6 heterostructures were determined by XRD technique (Figure 1). The diffraction peaks of Ag2CO3 and Bi2MoO6 were indexed as orthorhombic Bi2MoO6 (JCPDS 76-2388) and monoclinic Ag2CO3

• -4800 scanning electron microscope (SEM) and a JEM-2010F transmission electron microscope (TEM). The corresponding chemical compositions were detected by energy-dispersive X-ray (EDX) spectroscopy equipped on the SEM. The crystal structure of catalysts was identified by X-ray diffractometry (XRD, Bruker

Surface energy of nanoparticles – influence of particle size and structure

• Dieter Vollath,
• Franz Dieter Fischer and
• David Holec

Beilstein J. Nanotechnol. 2018, 9, 2265–2276, doi:10.3762/bjnano.9.211

• thermodynamic quantities [18][19][20][21][22]. Similar estimations, using the number of broken bonds at the surface, were performed by Lu and Jiang [23]. The result of counting broken bonds or applying relative coordination numbers depends on the crystal structure and on the crystallographic plane. Therefore

Lead-free hybrid perovskites for photovoltaics

• Oleksandr Stroyuk

Beilstein J. Nanotechnol. 2018, 9, 2209–2235, doi:10.3762/bjnano.9.207

• % and 0.89% for 2D- and 0D-form, respectively [89]. This finding, along with a higher stability of 2D-HP-based devices, suggests that the layered form of Cs3Sb2I9 is preferable for photovoltaic applications. The incorporation of other halide ions allows the crystal structure and optoelectronic

• photovoltaic materials. Additionally, the cell fitted with an encapsulating protective layer showed a remarkable stability with the PCE unchanged in a more than 2500 h test trial (Figure 3d) [69]. Manganese(II) ions were found to substitute Pb(II) in MA-Pb-Cl-Br HPs, the perovskite preserving the crystal

• structure up to 90% Mn [99]. Up to 46% Pb2+ ions can be exchanged with Mn2+ in CsPbCl3 NCs produced by hot-injection, resulting in a highly increased photoluminescence (PL) efficiency [100]. Mixed MAPbxMn1−xI1+2xCl2−2x (x = 0.1–1.0) synthesized by a solid-state reaction displayed an unprecedentedly high

Light–Matter interactions on the nanoscale

• Mohsen Rahmani and
• Chennupati Jagadish

Beilstein J. Nanotechnol. 2018, 9, 2125–2127, doi:10.3762/bjnano.9.201

• , such as transition-metal dichalcogenides (TMDCs) or hexagonal boron nitride (hBN) [10] have also emerged as interesting platforms for nanophotonics. TMDCs, with their intrinsically broken inversion symmetry in crystal structure, have shown many advanced optical properties with potential applications

Phosphorus monolayer doping (MLD) of silicon on insulator (SOI) substrates

• Noel Kennedy,
• Ray Duffy,
• Luke Eaton,
• Dan O’Connell,
• Scott Monaghan,
• Shane Garvey,
• James Connolly,
• Chris Hatem,
• Justin D. Holmes and
• Brenda Long

Beilstein J. Nanotechnol. 2018, 9, 2106–2113, doi:10.3762/bjnano.9.199

• them in the crystal structure. By contrast, Ye et al. have recently proposed a monolayer contact doping (MLCD) process without the need for a capping layer [13]. This paper will examine the application of phosphorus MLD to silicon on insulator (SOI) substrates with nanoscale dimensions (sub-66 nm

Recent highlights in nanoscale and mesoscale friction

• Andrea Vanossi,
• Dirk Dietzel,
• Andre Schirmeisen,
• Ernst Meyer,
• Rémy Pawlak,
• Thilo Glatzel,
• Marcin Kisiel,
• Shigeki Kawai and
• Nicola Manini

Beilstein J. Nanotechnol. 2018, 9, 1995–2014, doi:10.3762/bjnano.9.190

• direct information on the crystal structure itself. Particularly when the FFM tip is subject to stick–slip advancement, this mode becomes especially efficient for resolving structural features. By mapping the power dissipated by these lateral forces, FFM can even detect such elusive structures as moiré

Synthesis of a MnO₂/Fe₃O₄/diatomite nanocomposite as an efficient heterogeneous Fenton-like catalyst for methylene blue degradation

• Zishun Li,
• Xuekun Tang,
• Kun Liu,
• Jing Huang,
• Yueyang Xu,
• Qian Peng and
• Minlin Ao

Beilstein J. Nanotechnol. 2018, 9, 1940–1950, doi:10.3762/bjnano.9.185

• seen in the magnified image (Figure 4c), a flower-like or urchin-like structure of the outer MnO2 shell can be easily observed. The crystal structure of the outer shell is analyzed by using HRTEM, as shown in Figure 4d. As a whole, the chaotic and unclear lattice fringes in the image illustrate the

A differential Hall effect measurement method with sub-nanometre resolution for active dopant concentration profiling in ultrathin doped Si_1−xGe_x and Si layers

• Richard Daubriac,
• Emmanuel Scheid,
• Hiba Rizk,
• Richard Monflier,
• Sylvain Joblot,
• Rémi Beneyton,
• Pablo Acosta Alba,
• Sébastien Kerdilès and
• Filadelfo Cristiano

Beilstein J. Nanotechnol. 2018, 9, 1926–1939, doi:10.3762/bjnano.9.184

• continuous amorphous layer. Then, we compare electrical parameters measured by conventional Hall effect with the evolution of the crystal structure imaged by TEM as functions of the laser energy densities. The TEM analysis (Figure S11, Supporting Information File 1) shows that for energies of 0.74 and 0.76 J

Synthesis of hafnium nanoparticles and hafnium nanoparticle films by gas condensation and energetic deposition

• Irini Michelakaki,
• Nikos Boukos,
• Dimitrios A. Dragatogiannis,
• Spyros Stathopoulos,
• Costas A. Charitidis and
• Dimitris Tsoukalas

Beilstein J. Nanotechnol. 2018, 9, 1868–1880, doi:10.3762/bjnano.9.179

• study the fabrication and characterization of hafnium nanoparticles and hafnium nanoparticle thin films. Hafnium nanoparticles were grown in vacuum by magnetron-sputtering inert-gas condensation. The as deposited nanoparticles have a hexagonal close-packed crystal structure, they possess truncated

• Hf NPs have been missing and the crystal structure has been only theoretically investigated [37]. In this study, Hf NPs were fabricated by inert-gas condensation (IGC) at room temperature. IGC is a single-step NP synthesis method in a high-vacuum environment. The method allows for a high degree of

• nanoindentation measurements, were utilized for their characterization. Hf nanoparticles were fabricated by magnetron sputtering inert-gas condensation. They exhibit a hexagonal close-packed crystal structure and the shape of truncated hexagonal biprisms, and form core–shell structures upon exposure to ambient

Nitrogen-doped carbon nanotubes coated with zinc oxide nanoparticles as sulfur encapsulator for high-performance lithium/sulfur batteries

• Yan Zhao,
• Zhengjun Liu,
• Liancheng Sun,
• Yongguang Zhang,
• Yuting Feng,
• Xin Wang,
• Indira Kurmanbayeva and
• Zhumabay Bakenov

Beilstein J. Nanotechnol. 2018, 9, 1677–1685, doi:10.3762/bjnano.9.159

• characterization Powder X-ray diffraction (XRD, SmartLab, Rigaku Corporation) with Cu Ka radiation was used to analyze the crystal structure of the S/ZnO@NCNT sample. The chemical status and elemental compositions of the sample were investigated by X-ray photoelectron spectroscopy (XPS, Shimadzu Axis Ultra

Light extraction efficiency enhancement of flip-chip blue light-emitting diodes by anodic aluminum oxide

• Yi-Ru Huang,
• Yao-Ching Chiu,
• Kuan-Chieh Huang,
• Shao-Ying Ting,
• Po-Jui Chiang,
• Chih-Ming Lai,
• Chun-Ping Jen,
• Snow H. Tseng and
• Hsiang-Chen Wang

Beilstein J. Nanotechnol. 2018, 9, 1602–1612, doi:10.3762/bjnano.9.152

• enhance the LEE of short-wavelength purple and ultraviolet LEDs by 1.4–2.5 times that of a traditional LED [14]. Ryu et al. adopted anodic aluminum oxide (AAO) to produce a photonic crystal structure at the n-GaN layer of LEDs, and transmission electron microscopy (TEM) images showed that screw

Sheet-on-belt branched TiO₂(B)/rGO powders with enhanced photocatalytic activity

• Huan Xing,
• Wei Wen and
• Jin-Ming Wu

Beilstein J. Nanotechnol. 2018, 9, 1550–1557, doi:10.3762/bjnano.9.146

• common but still draws much attention. Many types of TiO2(B) nanostructures have been synthesized, such as nanowires [9][10], nanotubes [11], nanobelts [12][13][14], nanofibers [15] and nanosheets [16]. TiO2(B) is mostly used in lithium-ion batteries due to its relatively open crystal structure, superior

Robust topological phase in proximitized core–shell nanowires coupled to multiple superconductors

• Tudor D. Stanescu,
• Anna Sitek and
• Andrei Manolescu

Beilstein J. Nanotechnol. 2018, 9, 1512–1526, doi:10.3762/bjnano.9.142

• the crystal structure [27]. The finite cross section of the wires used in the experiments may generate additional phenomena, which are not captured by ideal 1D models. In particular, the orbital effects of the magnetic field, which is oriented parallel to the nanowire, may reduce or even destroy the

Cr(VI) remediation from aqueous environment through modified-TiO₂-mediated photocatalytic reduction

• Rashmi Acharya,
• Brundabana Naik and
• Kulamani Parida

Beilstein J. Nanotechnol. 2018, 9, 1448–1470, doi:10.3762/bjnano.9.137

Computational exploration of two-dimensional silicon diarsenide and germanium arsenide for photovoltaic applications

• Sri Kasi Matta,
• Chunmei Zhang,
• Yalong Jiao,
• Anthony O'Mullane and
• Aijun Du

Beilstein J. Nanotechnol. 2018, 9, 1247–1253, doi:10.3762/bjnano.9.116

• various electronic applications. Crystal structure side view of (a) SiAs2 bulk (3 × 2 super cells) and (b) GeAs2 bulk (red: silicon, blue: germanium, green: arsenic). Phonon band structure of a monolayer of (a) SiAs2 and (b) GeAs2 along the high-symmetry points in the 1st Brillouin zone. (c) Energy of

Understanding the performance and mechanism of Mg-containing oxides as support catalysts in the thermal dry reforming of methane

• Nor Fazila Khairudin,
• Mohd Farid Fahmi Sukri,
• Mehrnoush Khavarian and
• Abdul Rahman Mohamed

Beilstein J. Nanotechnol. 2018, 9, 1162–1183, doi:10.3762/bjnano.9.108

• minimized with an increase in MgO concentration in the catalyst because MgO exhibits alkaline characteristics. Its high basicity and similar crystal structure with NiO render MgO as highly suitable for Ni-based catalyst supports. Strong metal–support interaction between MgO and NiO formed a basic solid

Review on nanoparticles and nanostructured materials: history, sources, toxicity and regulations

• Jaison Jeevanandam,
• Ahmed Barhoum,
• Yen S. Chan,
• Alain Dufresne and
• Michael K. Danquah

Beilstein J. Nanotechnol. 2018, 9, 1050–1074, doi:10.3762/bjnano.9.98

Magnetic characterization of cobalt nanowires and square nanorings fabricated by focused electron beam induced deposition

• Federico Venturi,
• Gian Carlo Gazzadi,
• Amir H. Tavabi,
• Alberto Rota,
• Rafal E. Dunin-Borkowski and
• Stefano Frabboni

Beilstein J. Nanotechnol. 2018, 9, 1040–1049, doi:10.3762/bjnano.9.97

• promise for reliable, high-capacity and high-performance devices [7]. However, in all of the proposed applications, the stability of the magnetic state of the nanostructure depends on factors such as its composition, crystal structure and shape [8]. Co-based magnetic nanostructures can be deposited by

Single-crystalline FeCo nanoparticle-filled carbon nanotubes: synthesis, structural characterization and magnetic properties

• Rasha Ghunaim,
• Maik Scholz,
• Christine Damm,
• Bernd Rellinghaus,
• Rüdiger Klingeler,
• Bernd Büchner,
• Michael Mertig and
• Silke Hampel

Beilstein J. Nanotechnol. 2018, 9, 1024–1034, doi:10.3762/bjnano.9.95

• -filled CNTs show significant enhancement in the coercive field as compared to the corresponding bulk material, which make them excellent candidates for several applications such as magnetic storage devices. Keywords: carbon nanotubes; crystal structure; encapsulation; Fe–Co binary nanoparticles

• equipped with an EDX analyzer (AMETEK, Oxford). The TEM samples were prepared by adding a few drops of the sample suspension in acetone on a copper grid with a carbon coating on one side. The crystal structure of the magnetic nanoparticles inside the CNT was identified using an X’Pert Pro MPD PW3040/60 X

Facile synthesis of a ZnO–BiOI p–n nano-heterojunction with excellent visible-light photocatalytic activity

• Mengyuan Zhang,
• Jiaqian Qin,
• Pengfei Yu,
• Bing Zhang,
• Mingzhen Ma,
• Xinyu Zhang and
• Riping Liu

Beilstein J. Nanotechnol. 2018, 9, 789–800, doi:10.3762/bjnano.9.72

• . Recently, bismuth oxyhalides have been proposed as a new kind of narrow band gap p-type semiconductor photocatalyst material whose general formula is BiOX, where X represents Cl, Br or I. They crystallize in the tetragonal matlockite structure with space group P4/NMMS. In the crystal structure of all these

Combined pulsed laser deposition and non-contact atomic force microscopy system for studies of insulator metal oxide thin films

• Daiki Katsube,
• Hayato Yamashita,
• Satoshi Abo and
• Masayuki Abe

Beilstein J. Nanotechnol. 2018, 9, 686–692, doi:10.3762/bjnano.9.63

• for checking the crystal structure, orientation plane, and crystallinity of a thin film. Once a single-atomic layer step is confirmed, a new sample is prepared under the same PLD conditions and in situ NC-AFM (and also STM) measurements can then be performed in UHV. As an example, a process flow for

Sensing behavior of flower-shaped MoS₂ nanoflakes: case study with methanol and xylene

• Maryam Barzegar,
• Masoud Berahman and
• Azam Iraji zad

Beilstein J. Nanotechnol. 2018, 9, 608–615, doi:10.3762/bjnano.9.57

• illustrated in Figure 1, there are two completely distinguishable peaks at 33.61° and 59.19° which are in good agreement with corresponding peaks of the (100) and (110) planes of MoS2 sheets with hexagonal crystal structure denoted as the 2H phase (JCPDS-37-1492). The measured d-spacings of 0.26 nm and 0.15

Towards 3D crystal orientation reconstruction using automated crystal orientation mapping transmission electron microscopy (ACOM-TEM)

• Aaron Kobler and
• Christian Kübel

Beilstein J. Nanotechnol. 2018, 9, 602–607, doi:10.3762/bjnano.9.56

• resolution and quality of crystal orientation data for the TEM. Conical dark field imaging (CDFI) was used in the 3D-orientation mapping in transmission electron microscope (3D-OMiTEM) method to first reconstruct the diffraction pattern and then the 3D crystal structure [19]. Spot Bragg diffraction, in

Electron interactions with the heteronuclear carbonyl precursor H₂FeRu₃(CO)₁₃ and comparison with HFeCo₃(CO)₁₂: from fundamental gas phase and surface science studies to focused electron beam induced deposition

• Ragesh Kumar T P,
• Paul Weirich,
• Lukas Hrachowina,
• Marc Hanefeld,
• Ragnar Bjornsson,
• Helgi Rafn Hrodmarsson,
• Sven Barth,
• D. Howard Fairbrother,
• Michael Huth and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2018, 9, 555–579, doi:10.3762/bjnano.9.53