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Search for "metal complexes" in Full Text gives 259 result(s) in Beilstein Journal of Organic Chemistry. Showing first 200.

Reusable and highly enantioselective water-soluble Ru(II)-Amm-Pheox catalyst for intramolecular cyclopropanation of diazo compounds

  • Hamada S. A. Mandour,
  • Yoko Nakagawa,
  • Masaya Tone,
  • Hayato Inoue,
  • Nansalmaa Otog,
  • Ikuhide Fujisawa,
  • Soda Chanthamath and
  • Seiji Iwasa

Beilstein J. Org. Chem. 2019, 15, 357–363, doi:10.3762/bjoc.15.31

Graphical Abstract
  • diazoamide; Ru(II)-Pheox; water-soluble catalyst; Weinreb amide; Introduction Water-soluble transition metal complexes have been attracting increasing interest for catalytic applications because of their many advantages such as simple product separation, low cost, safety, and environmentally friendly
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Published 06 Feb 2019

Gold-catalyzed ethylene cyclopropanation

  • Silvia G. Rull,
  • Andrea Olmos and
  • Pedro J. Pérez

Beilstein J. Org. Chem. 2019, 15, 67–71, doi:10.3762/bjoc.15.7

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  • = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) catalyzes the ethylene cyclopropanation with ethyl diazoacetate as the carbene precursor, under mild conditions, with moderate yields (ca. 70%, EDA-based). Results and Discussion Diazo compounds N2=CRR’ usually react with metal complexes of groups 8–11 with
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Published 07 Jan 2019

Organometallic vs organic photoredox catalysts for photocuring reactions in the visible region

  • Aude-Héloise Bonardi,
  • Frédéric Dumur,
  • Guillaume Noirbent,
  • Jacques Lalevée and
  • Didier Gigmes

Beilstein J. Org. Chem. 2018, 14, 3025–3046, doi:10.3762/bjoc.14.282

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  • Figure 3. Absorption band observable are very intense. 1.3.5 Metal to ligand charge transfer (MLCT): The MLCT transition is a second type of charge transfer observed with metal complexes. More particularly, it is observed for complexes whose ligands have relatively high-energy lone pairs or in case of
  • photoredox catalysts The first photoredox catalysts to emerge were the metal-based complexes. Indeed, metal complexes, also named coordination compounds, have been recognized in the photochemistry field since the second half of the last century [33][34][35]. However, these compounds are still the subject of
  • of the ligand is essential for good properties. 2.1.3 The latest generation of metal-based catalysts: Emergence of the TADF complexes: Metal complexes are still at the origin of numerous researches as photoredox catalysts, these researches being notably motivated by their remarkable long-lived
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Published 12 Dec 2018

Reactions of 3-(p-substituted-phenyl)-5-chloromethyl-1,2,4-oxadiazoles with KCN leading to acetonitriles and alkanes via a non-reductive decyanation pathway

  • Akın Sağırlı and
  • Yaşar Dürüst

Beilstein J. Org. Chem. 2018, 14, 3011–3017, doi:10.3762/bjoc.14.280

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  • ], transition metal complexes [25], and alkali metals in a variety of solvents [26]. Generally, they require mostly an inert atmosphere as well as harsh reaction conditions. These facts constitute challenges to the development of mild reaction conditions in the reduction of nitrilated compounds. In the light of
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Published 10 Dec 2018

The influence of the cationic carbenes on the initiation kinetics of ruthenium-based metathesis catalysts; a DFT study

  • Magdalena Jawiczuk,
  • Angelika Janaszkiewicz and
  • Bartosz Trzaskowski

Beilstein J. Org. Chem. 2018, 14, 2872–2880, doi:10.3762/bjoc.14.266

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  • either anionic or cationic carbenes [15][16][17][18]. Cationic ligands with a positive charge close to the coordinating atom are relatively rare, as their coordination ability of transition metals, bearing also a formal positive charge, is weakened. Nevertheless, stable metal complexes with cationic
  • recently and examples of their transition metal complexes are scarce. In 2013 Ganter described a cationic NHC with a fused pyridinium moiety and the formal +1 charge just one bond away from the imidazole core [27]. In 2017 César synthesized a cationic imidazolylidene NHC with an ammonium tag attached
  • interesting phenomenon, despite its very limited impact on their propensity to form transition metal complexes (Scheme 2) [50]. Many works have been devoted to the study of carbene dimerization and present evidence that mechanism of monomer–dimer equilibrium depends on the balance between the electronic and
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Published 20 Nov 2018

Olefin metathesis catalysts embedded in β-barrel proteins: creating artificial metalloproteins for olefin metathesis

  • Daniel F. Sauer,
  • Johannes Schiffels,
  • Takashi Hayashi,
  • Ulrich Schwaneberg and
  • Jun Okuda

Beilstein J. Org. Chem. 2018, 14, 2861–2871, doi:10.3762/bjoc.14.265

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  • [50]. Further mutations within the cavity of NB provide a hydrophobic cavity. Several studies reported on the utilization of NB as scaffold for incorporated metal complexes, including the work of Hayashi et al. capitalizing on the polymerization of phenylacetylene [50][51], the Diels–Alder reaction
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Published 19 Nov 2018

Copolymerization of epoxides with cyclic anhydrides catalyzed by dinuclear cobalt complexes

  • Yo Hiranoi and
  • Koji Nakano

Beilstein J. Org. Chem. 2018, 14, 2779–2788, doi:10.3762/bjoc.14.255

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  • developed based on well-defined metal complexes such as metalloporphyrins and metal–salen complexes [15][16][17][18][19][20][21]. In parallel to the development of catalysts, new polyester materials also were prepared by employing unprecedented monomers or by the combination with other polymerization
  • -workers reported that the dinuclear chromium–salan complex showed a much higher catalytic activity than the corresponding mononuclear chromium–salan complex in the copolymerization of epoxides with maleic anhydride (MA) [31]. Following this report, some dinuclear metal complexes have been reported to
  • catalytic activity than the corresponding mononuclear cobalt–salen complex. These results indicate that the design based on di- or multinuclear metal complexes is a promising strategy for the development of highly active catalysts. Our future studies will focus on the optimization of linker structures as
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Published 05 Nov 2018

DABCO- and DBU-promoted one-pot reaction of N-sulfonyl ketimines with Morita–Baylis–Hillman carbonates: a sequential approach to (2-hydroxyaryl)nicotinate derivatives

  • Soumitra Guin,
  • Raman Gupta,
  • Debashis Majee and
  • Sampak Samanta

Beilstein J. Org. Chem. 2018, 14, 2771–2778, doi:10.3762/bjoc.14.254

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  • products [4], medicines [5], chelating agents in transition metal complexes [6][7], and material science [8][9]. Pyridine derivatives such as vitamins B6, B3 (niacin), and nicotinamide adenine dinucleotide (NAD) play a significant role in the metabolism process of living organisms. Consequently, many
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Published 02 Nov 2018

Transition metal-free oxidative and deoxygenative C–H/C–Li cross-couplings of 2H-imidazole 1-oxides with carboranyl lithium as an efficient synthetic approach to azaheterocyclic carboranes

  • Lidia A. Smyshliaeva,
  • Mikhail V. Varaksin,
  • Pavel A. Slepukhin,
  • Oleg N. Chupakhin and
  • Valery N. Charushin

Beilstein J. Org. Chem. 2018, 14, 2618–2626, doi:10.3762/bjoc.14.240

Graphical Abstract
  • capture therapy (BNCT) of cancer [8][9][10][11][12], as well as agonists and antagonists of biological receptors [13][14][15][16][17], etc. In addition, azaheterocyclic carboranes are actively used as ligands in the synthesis of metal complexes of various architectures, possessing catalytic activity [18
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Published 12 Oct 2018

Efficient catalytic alkyne metathesis with a fluoroalkoxy-supported ditungsten(III) complex

  • Henrike Ehrhorn,
  • Janin Schlösser,
  • Dirk Bockfeld and
  • Matthias Tamm

Beilstein J. Org. Chem. 2018, 14, 2425–2434, doi:10.3762/bjoc.14.220

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  • cleaving the W≡W bond in W2F3 with 1-phenyl-1-propyne. The catalytic alkyne metathesis activity of these metal complexes was determined in the self-metathesis, ring-closing alkyne metathesis and cross-metathesis of internal and terminal alkynes, revealing an almost equally high metathesis activity for the
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Published 18 Sep 2018

Non-metal-templated approaches to bis(borane) derivatives of macrocyclic dibridgehead diphosphines via alkene metathesis

  • Tobias Fiedler,
  • Michał Barbasiewicz,
  • Michael Stollenz and
  • John A. Gladysz

Beilstein J. Org. Chem. 2018, 14, 2354–2365, doi:10.3762/bjoc.14.211

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  • ; crystal structures; homeomorphic isomerization; hydrogenation; in/out isomers; metathesis; phosphine boranes; Introduction We have found that a variety of metal complexes with trans-phosphine ligands of the formula P((CH2)mCH=CH2)3 (1; m = 4–14) undergo threefold interligand ring closing alkene
  • metatheses to give, after hydrogenations, metal complexes of in,in isomers of macrocyclic dibridgehead diphosphines [1][2][3][4][5][6][7][8][9][10][11][12][13]. Representative examples with square planar complexes are shown in Scheme 1. Analogous sequences with trigonal bipyramidal substrates proceed in
  • an isomer below. A white powder was obtained next. The 13C{1H} NMR spectrum exhibited fourteen signals, half of which were approximately twice as intense as the others. Two signals of each set exhibited phosphorus coupling. The overall pattern was quite similar to those shown by metal complexes with
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Published 07 Sep 2018

D-Fructose-based spiro-fused PHOX ligands: synthesis and application in enantioselective allylic alkylation

  • Michael R. Imrich,
  • Jochen Kraft,
  • Cäcilia Maichle-Mössmer and
  • Thomas Ziegler

Beilstein J. Org. Chem. 2018, 14, 2082–2089, doi:10.3762/bjoc.14.182

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  • -fused PHOX ligands. The described ligands can be prepared from literature-known carbohydrate derivatives in two steps. Preliminary tests of the spiro-fused PHOX ligands in Tsuji–Trost reaction showed promising results. Different metal complexes as well as further application of the ligands in asymmetric
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Published 08 Aug 2018

Graphitic carbon nitride prepared from urea as a photocatalyst for visible-light carbon dioxide reduction with the aid of a mononuclear ruthenium(II) complex

  • Kazuhiko Maeda,
  • Daehyeon An,
  • Ryo Kuriki,
  • Daling Lu and
  • Osamu Ishitani

Beilstein J. Org. Chem. 2018, 14, 1806–1812, doi:10.3762/bjoc.14.153

Graphical Abstract
  • phase. Keywords: artificial photosynthesis; heterogeneous photocatalysis; hybrid material; metal complexes; solar fuels; Introduction Carbon nitride is one of the oldest synthetic polymers [1], and has several allotropes. Among them, graphitic carbon nitride (g-C3N4) is the most stable form and is an
  • reduction systems using g-C3N4-based materials, in combination with functional metal complexes [8][9][10][11][12][13][14][15][16]. For example, mesoporous g-C3N4 (mpg-C3N4) modified with a mononuclear Ru(II) complex, such as trans-(Cl)-Ru{(PO3H2)2bpy(CO)2Cl2} (bpy: 2,2’-bipyridine), abbreviated as RuP, is
  • using cobalt-based metal complexes as reduction cocatalysts [17][18][19][20]. In these systems, structural properties of g-C3N4 such as specific surface area and porosity have a strong impact on activity, because they strongly affect the efficiency of electron/hole utilization to the surface chemical
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Published 17 Jul 2018

DFT calculations on the mechanism of copper-catalysed tandem arylation–cyclisation reactions of alkynes and diaryliodonium salts

  • Tamás Károly Stenczel,
  • Ádám Sinai,
  • Zoltán Novák and
  • András Stirling

Beilstein J. Org. Chem. 2018, 14, 1743–1749, doi:10.3762/bjoc.14.148

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  • route often observed for the 16 electron metal complexes. We could locate a crucial structure (Ic) where the incoming reactant and the leaving solvent molecule occupy the equatorial position of the trigonal bipyramid formed by the five ligands of the Cu(III) ion. We decided to characterise this step by
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Published 12 Jul 2018

Hypervalent organoiodine compounds: from reagents to valuable building blocks in synthesis

  • Gwendal Grelier,
  • Benjamin Darses and
  • Philippe Dauban

Beilstein J. Org. Chem. 2018, 14, 1508–1528, doi:10.3762/bjoc.14.128

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  • for the 1,2-benzoyloxy-azidation reaction. Based on a preliminary observation made during their study on catalytic trifluoromethylation of enamides [49], the group of Gillaizeau has reported the catalytic conversion of enamides with various ABX derivatives 44 [50]. A screening of various metal
  • complexes has led the authors to demonstrate the superior ability of cheap FeCl2 to mediate the 1,2-addition thereby allowing the formation of the trans-products 43 with complete regio- and diastereocontrol (Scheme 14). The group of Hamashima has reported that various 1,2-difunctionalizations of alkenes can
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Published 21 Jun 2018

Recent advances in phosphorescent platinum complexes for organic light-emitting diodes

  • Cristina Cebrián and
  • Matteo Mauro

Beilstein J. Org. Chem. 2018, 14, 1459–1481, doi:10.3762/bjoc.14.124

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  • organometallic compounds based on heavy transition metal complexes (TMCs) are an appealing research topic of enormous current interest. Amongst all different fields in which they found valuable application, development of emitting materials based on TMCs have become crucial for electroluminescent devices such as
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Published 18 Jun 2018

Synthesis of chiral 3-substituted 3-amino-2-oxindoles through enantioselective catalytic nucleophilic additions to isatin imines

  • Hélène Pellissier

Beilstein J. Org. Chem. 2018, 14, 1349–1369, doi:10.3762/bjoc.14.114

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  • ]. An extensively used two-component variant of this reaction consists in using a preformed imine. Among chiral metal complexes, a wide variety of organocatalysts [26][27][28][29][30][31][32][33][34] has been used to promote asymmetric Mannich reactions. Among them, cinchona alkaloid 1 was employed in
  • either chiral organocatalysts or chiral metal complexes. Among the organocatalysts, chiral bifunctional guanidine 50 was applied by Feng et al. in 2015 to promote the reaction of nitromethane 51 with N-Boc-isatin imines 3 (Scheme 18) [71]. The reaction performed at −30 °C using 10 mol % of this catalyst
  • trimethylsilyl ether. However, also metal complexes (Zn, Sn) derived from N,N’-dioxide and BINOL-derived ligands have been employed affording the products with enantioselectivities of up to 90–99% ee. Moreover, comparable enantioselectivities of up to 99% ee were reported in aza-Morita–Baylis–Hilman reactions
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Published 06 Jun 2018

Selective carboxylation of reactive benzylic C–H bonds by a hypervalent iodine(III)/inorganic bromide oxidation system

  • Toshifumi Dohi,
  • Shohei Ueda,
  • Kosuke Iwasaki,
  • Yusuke Tsunoda,
  • Koji Morimoto and
  • Yasuyuki Kita

Beilstein J. Org. Chem. 2018, 14, 1087–1094, doi:10.3762/bjoc.14.94

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  • reaction systems have been further elaborated to include elegant C–H coupling methodologies. Several important researches that provide a new benzylic C–H coupling strategy have been reported over the past few years, involving the promising catalytic activities of metal complexes [13][14]. On the other hand
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Published 16 May 2018

An overview of recent advances in duplex DNA recognition by small molecules

  • Sayantan Bhaduri,
  • Nihar Ranjan and
  • Dev P. Arya

Beilstein J. Org. Chem. 2018, 14, 1051–1086, doi:10.3762/bjoc.14.93

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  • exceptionally stable duplexes (ΔTm = +44.8 °C) and high selectivity [92]. Six novel 4-aminoantipyrine derived Schiff bases and their metal complexes with Cu(II), Ni(II), Zn(II) ions (conjugates 26–31) were synthesized and characterized and binding of these complexes with ct-DNA were analyzed by electronic
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Published 16 May 2018

Phosphodiester models for cleavage of nucleic acids

  • Satu Mikkola,
  • Tuomas Lönnberg and
  • Harri Lönnberg

Beilstein J. Org. Chem. 2018, 14, 803–837, doi:10.3762/bjoc.14.68

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Published 10 Apr 2018

An uracil-linked hydroxyflavone probe for the recognition of ATP

  • Márton Bojtár,
  • Péter Zoltán Janzsó-Berend,
  • Dávid Mester,
  • Dóra Hessz,
  • Mihály Kállay,
  • Miklós Kubinyi and
  • István Bitter

Beilstein J. Org. Chem. 2018, 14, 747–755, doi:10.3762/bjoc.14.63

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  • ], metal-complexes [21][22][23][24][25][26][27] and other direct sensing systems [28][29][30] have significant advantages over the classical, separation-based methods. The primary difficulties in the design of an ATP chemosensor are the structural similarity of ATP to other nucleotides (i.e., to guanosine
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Published 03 Apr 2018

Nanoreactors for green catalysis

  • M. Teresa De Martino,
  • Loai K. E. A. Abdelmohsen,
  • Floris P. J. T. Rutjes and
  • Jan C. M. van Hest

Beilstein J. Org. Chem. 2018, 14, 716–733, doi:10.3762/bjoc.14.61

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  • yield and output [23][24]. Indeed, such a strategy proved to be advantageous for performing reactions in water and minimizing both reaction waste and cost [25][26]. Attempts to support homogeneous metal complexes onto organic or inorganic surfaces to facilitate their removal/extraction from the reaction
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Published 29 Mar 2018

AuBr3-catalyzed azidation of per-O-acetylated and per-O-benzoylated sugars

  • Jayashree Rajput,
  • Srinivas Hotha and
  • Madhuri Vangala

Beilstein J. Org. Chem. 2018, 14, 682–687, doi:10.3762/bjoc.14.56

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  • -benzoylated disaccharides needed 2–3 h of heating at 55 °C. Keywords: acylated sugars; azidation; gold(III) bromide; N-glycoside; oxophilicity; Introduction The past few decades had seen the enrichment of transition metal complexes in various glycosylation strategies [1]. In particular, gold complexes with
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Published 22 Mar 2018

Recent advances on organic blue thermally activated delayed fluorescence (TADF) emitters for organic light-emitting diodes (OLEDs)

  • Thanh-Tuân Bui,
  • Fabrice Goubard,
  • Malika Ibrahim-Ouali,
  • Didier Gigmes and
  • Frédéric Dumur

Beilstein J. Org. Chem. 2018, 14, 282–308, doi:10.3762/bjoc.14.18

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  • % for phosphorescent OLEDs [5]. As drawback, triplet emitters are transition-metal complexes mostly based on iridium, platinum and osmium and the scarcity of these metals on Earth, their toxicity and high cost make these materials unsuitable candidates for a mass-production of OLEDs [6]. However
  • and triplet excitons for radiative transition, excepted that the emission occurs from the singlet state and not from the triplet state (as observed for metal complexes) and that the triplet–triplet annihilation commonly observed with phosphorescent OLEDs [10] can be drastically reduced (see Figure 1
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Published 30 Jan 2018

Synthesis and spectroscopic properties of β-meso directly linked porphyrin–corrole hybrid compounds

  • Baris Temelli and
  • Hilal Kalkan

Beilstein J. Org. Chem. 2018, 14, 187–193, doi:10.3762/bjoc.14.13

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  • used to obtain this product. In order to expand the scope of the reaction, metal complexes of formylated porphyrins were subjected to the reaction. While Zn-porphyrin containing hybrid compound 4f was isolated in 21%, the Cu(II) complex of β-formylated porphyrin underwent the reaction to produce the
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Published 22 Jan 2018
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