C–H functionalization for materials science

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Editor: Prof. Kenichiro Itami
Nagoya University
 

Direct functionalization of C–H bonds has received significant attention in the synthetic chemistry community. In recent years, rapid and site-selective π-extension by C–H activation/functionalization has emerged as an ideal methodology for preparing organic π-materials. This issue focuses on π-extending C–H functionalization reactions directed toward new organic materials.

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Formal preparation of regioregular and alternating thiophene–thiophene copolymers bearing different substituents

  • Atsunori Mori,
  • Keisuke Fujita,
  • Chihiro Kubota,
  • Toyoko Suzuki,
  • Kentaro Okano,
  • Takuya Matsumoto,
  • Takashi Nishino and
  • Masaki Horie

Beilstein J. Org. Chem. 2020, 16, 317–324, doi:10.3762/bjoc.16.31

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Published 05 Mar 2020

Synthesis and circularly polarized luminescence properties of BINOL-derived bisbenzofuro[2,3-b:3’,2’-e]pyridines (BBZFPys)

  • Ryo Takishima,
  • Yuji Nishii,
  • Tomoaki Hinoue,
  • Yoshitane Imai and
  • Masahiro Miura

Beilstein J. Org. Chem. 2020, 16, 325–336, doi:10.3762/bjoc.16.32

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Published 06 Mar 2020

Room-temperature Pd/Ag direct arylation enabled by a radical pathway

  • Amy L. Mayhugh and
  • Christine K. Luscombe

Beilstein J. Org. Chem. 2020, 16, 384–390, doi:10.3762/bjoc.16.36

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Published 13 Mar 2020

Six-fold C–H borylation of hexa-peri-hexabenzocoronene

  • Mai Nagase,
  • Kenta Kato,
  • Akiko Yagi,
  • Yasutomo Segawa and
  • Kenichiro Itami

Beilstein J. Org. Chem. 2020, 16, 391–397, doi:10.3762/bjoc.16.37

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Published 13 Mar 2020

Synthesis of six-membered silacycles by borane-catalyzed double sila-Friedel–Crafts reaction

  • Yafang Dong,
  • Masahiko Sakai,
  • Kazuto Fuji,
  • Kohei Sekine and
  • Yoichiro Kuninobu

Beilstein J. Org. Chem. 2020, 16, 409–414, doi:10.3762/bjoc.16.39

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Published 17 Mar 2020

Synthesis of triphenylene-fused phosphole oxides via C–H functionalizations

  • Md. Shafiqur Rahman and
  • Naohiko Yoshikai

Beilstein J. Org. Chem. 2020, 16, 524–529, doi:10.3762/bjoc.16.48

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Published 27 Mar 2020

Copper-catalyzed remote C–H arylation of polycyclic aromatic hydrocarbons (PAHs)

  • Anping Luo,
  • Min Zhang,
  • Zhangyi Fu,
  • Jingbo Lan,
  • Di Wu and
  • Jingsong You

Beilstein J. Org. Chem. 2020, 16, 530–536, doi:10.3762/bjoc.16.49

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Published 30 Mar 2020

Efficient synthesis of 3,6,13,16-tetrasubstituted-tetrabenzo[a,d,j,m]coronenes by selective C–H/C–O arylations of anthraquinone derivatives

  • Seiya Terai,
  • Yuki Sato,
  • Takuya Kochi and
  • Fumitoshi Kakiuchi

Beilstein J. Org. Chem. 2020, 16, 544–550, doi:10.3762/bjoc.16.51

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Published 31 Mar 2020

Regioselectively α- and β-alkynylated BODIPY dyes via gold(I)-catalyzed direct C–H functionalization and their photophysical properties

  • Takahide Shimada,
  • Shigeki Mori,
  • Masatoshi Ishida and
  • Hiroyuki Furuta

Beilstein J. Org. Chem. 2020, 16, 587–595, doi:10.3762/bjoc.16.53

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Published 01 Apr 2020

Direct borylation of terrylene and quaterrylene

  • Haruka Kano,
  • Keiji Uehara,
  • Kyohei Matsuo,
  • Hironobu Hayashi,
  • Hiroko Yamada and
  • Naoki Aratani

Beilstein J. Org. Chem. 2020, 16, 621–627, doi:10.3762/bjoc.16.58

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Published 06 Apr 2020

Synthesis of C70-fragment buckybowls bearing alkoxy substituents

  • Yumi Yakiyama,
  • Shota Hishikawa and
  • Hidehiro Sakurai

Beilstein J. Org. Chem. 2020, 16, 681–690, doi:10.3762/bjoc.16.66

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Published 15 Apr 2020

One-pot synthesis of dicyclopenta-fused peropyrene via a fourfold alkyne annulation

  • Ji Ma,
  • Yubin Fu,
  • Junzhi Liu and
  • Xinliang Feng

Beilstein J. Org. Chem. 2020, 16, 791–797, doi:10.3762/bjoc.16.72

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Published 20 Apr 2020

Bipyrrole boomerangs via Pd-mediated tandem cyclization–oxygenation. Controlling reaction selectivity and electronic properties

  • Liliia Moshniaha,
  • Marika Żyła-Karwowska,
  • Joanna Cybińska,
  • Piotr J. Chmielewski,
  • Ludovic Favereau and
  • Marcin Stępień

Beilstein J. Org. Chem. 2020, 16, 895–903, doi:10.3762/bjoc.16.81

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Published 04 May 2020

Synthesis and properties of tetrathiafulvalenes bearing 6-aryl-1,4-dithiafulvenes

  • Aya Yoshimura,
  • Hitoshi Kimura,
  • Kohei Kagawa,
  • Mayuka Yoshioka,
  • Toshiki Itou,
  • Dhananjayan Vasu,
  • Takashi Shirahata,
  • Hideki Yorimitsu and
  • Yohji Misaki

Beilstein J. Org. Chem. 2020, 16, 974–981, doi:10.3762/bjoc.16.86

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Published 12 May 2020

Clickable azide-functionalized bromoarylaldehydes – synthesis and photophysical characterization

  • Dominik Göbel,
  • Marius Friedrich,
  • Enno Lork and
  • Boris J. Nachtsheim

Beilstein J. Org. Chem. 2020, 16, 1683–1692, doi:10.3762/bjoc.16.139

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Published 14 Jul 2020
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