Measurements of dichroic bow-tie antenna arrays with integrated cold-electron bolometers using YBCO oscillators

• Leonid S. Revin,
• Dmitry A. Pimanov,
• Alexander V. Chiginev,
• Anton V. Blagodatkin,
• Viktor O. Zbrozhek,
• Andrey V. Samartsev,
• Anastasia N. Orlova,
• Dmitry V. Masterov,
• Alexey E. Parafin,
• Victoria Yu. Safonova,
• Anna V. Gordeeva,
• Andrey L. Pankratov,
• Leonid S. Kuzmin,
• Anatolie S. Sidorenko,
• Silvia Masi and
• Paolo de Bernardis

Beilstein J. Nanotechnol. 2024, 15, 26–36, doi:10.3762/bjnano.15.3

• temperature [20][21][22][23]. This advantage is important for space, balloon, and ground-based applications. While dilution refrigerators are able to cool down below 50 mK, they cannot operate in extreme or even slightly unstable conditions; even the small variation of a tilt angle can lead to the cryostat

Fluorescent bioinspired albumin/polydopamine nanoparticles and their interactions with Escherichia coli cells

• Eloïse Equy,
• Jordana Hirtzel,
• Sophie Hellé,
• Béatrice Heurtault,
• Eric Mathieu,
• Morgane Rabineau,
• Vincent Ball and
• Lydie Ploux

Beilstein J. Nanotechnol. 2023, 14, 1208–1224, doi:10.3762/bjnano.14.100

• to heat up under irradiation by non-radiative relaxation. This is favorable to minimize the superposition between absorption and emission peaks, but might lead to a low quantum yield and, thus, poor emission intensity. Indeed, the quantum yield of Ox-BSA/PDA NPs in water (Φ) was calculated to be 0.1

A combined gas-phase dissociative ionization, dissociative electron attachment and deposition study on the potential FEBID precursor [Au(CH₃)₂Cl]₂

• Elif Bilgilisoy,
• Ali Kamali,
• Thomas Xaver Gentner,
• Gerd Ballmann,
• Sjoerd Harder,
• Hans-Peter Steinrück,
• Hubertus Marbach and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2023, 14, 1178–1199, doi:10.3762/bjnano.14.98

• composition and morphology of FEBID deposits fabricated in an ultrahigh-vacuum (UHV) chamber were explored on different surfaces and at varied beam currents. In the gas phase, dissociative ionization was found to lead to significant carbon loss from this precursor, and about 50% of the chlorine was on average

• experiment, this would lead to a deposit composed of approx. 55 atom % Au, 29 atom % Cl, and 16 atom % C. With respect to the high gold content, this is in line with the UHV FEBID deposits. However, the carbon content is significantly lower than that observed in FEBID, and most noticeably, in both the UHV

Spatial variations of conductivity of self-assembled monolayers of dodecanethiol on Au/mica and Au/Si substrates

• Julian Skolaut,
• Jędrzej Tepper,
• Federica Galli,
• Wulf Wulfhekel and
• Jan M. van Ruitenbeek

Beilstein J. Nanotechnol. 2023, 14, 1169–1177, doi:10.3762/bjnano.14.97

• . All these indications lead to the conclusion that ordered DDT SAMs form on the surface with the chosen deposition technique. More importantly, the current maps in Figure 3 show that substrate and measurement technique are suitable for obtaining information on the conductivity of a molecular SAM, as

• in Figure 4 this is slightly distorted by a probe effect duplicating features, the systematic difference in surface structure between Au/Si and Au/mica, already observed in the bare substrates, is reproduced. Just as for the bare Au/Si, the substructures of the substrate lead to strong variations in

Hierarchically patterned polyurethane microgrooves featuring nanopillars or nanoholes for neurite elongation and alignment

• Lester Uy Vinzons,
• Guo-Chung Dong and
• Shu-Ping Lin

Beilstein J. Nanotechnol. 2023, 14, 1157–1168, doi:10.3762/bjnano.14.96

• wider, around 20–24 µm. The microridge height was 1.4–1.5 µm on the microgroove and hole–groove substrates, while it was 1.1 µm or 2 µm on the pillar–groove substrate if measured to the tip or base of the nanopillars, respectively. Water CA measurements on the grooved PU samples lead to two distinct CAs

Elasticity, an often-overseen parameter in the development of nanoscale drug delivery systems

• Agnes-Valencia Weiss and
• Marc Schneider

Beilstein J. Nanotechnol. 2023, 14, 1149–1156, doi:10.3762/bjnano.14.95

• radii lead to lower elastic values [33][35]. Figure 2 summarizes factors that impact the elasticity measurement results obtained by AFM. Due to the issues aforementioned discussed, it is tricky to compare different studies. In addition, it is not yet known which absolute elastic values should be chosen

A multi-resistance wide-range calibration sample for conductive probe atomic force microscopy measurements

• François Piquemal,
• Khaled Kaja,
• Pascal Chrétien,
• José Morán-Meza,
• Frédéric Houzé,
• Christian Ulysse and
• Abdelmounaim Harouri

Beilstein J. Nanotechnol. 2023, 14, 1141–1148, doi:10.3762/bjnano.14.94

• droplets (F42240, lead-free solder paste – class 5, CIF, France). The fused silica substrate was placed on a heating plate set to 270 °C, which required around 3 min to reach the melting temperature of the solder droplets (217 °C), as observed under an optical microscope. Upon cooling, 16 SMD resistors

Curcumin-loaded albumin submicron particles with potential as a cancer therapy: an in vitro study

• Nittiya Suwannasom,
• Netsai Sriaksorn,
• Chutamas Thepmalee,
• Krissana Khoothiam,
• Ausanai Prapan,
• Hans Bäumler and
• Chonthida Thephinlap

Beilstein J. Nanotechnol. 2023, 14, 1127–1140, doi:10.3762/bjnano.14.93

• addition, the removal of sericin, which requires a degumming process, is a prerequisite for using silk cocoons in biomedical applications to reduce the risk of an inflammatory response [18]. However, this degumming process can lead to damage to the silk structure, increase the polydispersity of the silk

A bifunctional superconducting cell as flux qubit and neuron

• Dmitrii S. Pashin,
• Pavel V. Pikunov,
• Marina V. Bastrakova,
• Andrey E. Schegolev,
• Nikolay V. Klenov and
• Igor I. Soloviev

Beilstein J. Nanotechnol. 2023, 14, 1116–1126, doi:10.3762/bjnano.14.92

• level convergence for short periods τLZ, the phases of the wave functions change significantly, leading to strong fluctuations of the level populations in the system, and can lead to quasi-random dynamics in the parametron. In addition, Landau–Zener interference has become a tool to access the

• scientific community to be a good flux qubit. We were also surprised by the possibility of controlling the qubit state using unipolar current pulses, which greatly simplifies all control electronics [51][52]. But won’t such a deliberately non-resonant (broadband) impact lead to a parasitic leakage of the

Density functional theory study of Au-fcc/Ge and Au-hcp/Ge interfaces

• Olga Sikora,
• Małgorzata Sternik,
• Benedykt R. Jany,
• Franciszek Krok,
• Przemysław Piekarz and
• Andrzej M. Oleś

Beilstein J. Nanotechnol. 2023, 14, 1093–1105, doi:10.3762/bjnano.14.90

• presented in Figure 4 and Appendix A. The comparison of our results with the available theoretical and experimental data shows that different theoretical approaches lead to discrepancies in absolute values of surface energies; however, the relative changes between the investigated crystal planes are very

• Ge surface that places the column of Au atoms right over the Ge atoms (Figure 6b) leads to a significant increase in the total energy of the system (supercell) by about 3.5 eV. Additionally, the forces induced to preserve the Ge–Au bond length on the appropriate level lead to an increase of the

• are maximal for a given distance between slabs, that is, extremely short bonds are avoided. It occurs that at each interface there are four short Au–Ge bonds, marked with circles in Figure 9b. As a consequence, DFT calculations with full atomic displacements lead to strong changes in the Au atomic

Dual-heterodyne Kelvin probe force microscopy

• Benjamin Grévin,
• Fatima Husainy,
• Dmitry Aldakov and
• Cyril Aumaître

Beilstein J. Nanotechnol. 2023, 14, 1068–1084, doi:10.3762/bjnano.14.88

• reference substrate, a bulk organic photovoltaic heterojunction thin film, and an optoelectronic interface obtained by depositing caesium lead bromide perovskite nanosheets on a graphite surface. The conclusion provides perspectives for future improvements and applications. Keywords: heterodyne

• optoelectronic interfaces formed between caesium lead bromide perovskite nanosheets and highly oriented pyrolytic graphite. Kelvin Probe Force Microscopy Background, Amplitude-Modulated Heterodyne KPFM Many KPFM modes rely on the detection of a modulated component of the electrostatic force proportional to the

• depositing caesium lead halide perovskite nanosheets (NSs) on a highly oriented pyrolytic graphite (HOPG) substrate. Lead halide perovskites have emerged recently as materials with unique optical and electronic properties, such as high absorption coefficients, high defect tolerance, and charge mobility. Due

Spatial mapping of photovoltage and light-induced displacement of on-chip coupled piezo/photodiodes by Kelvin probe force microscopy under modulated illumination

• Zeinab Eftekhari,
• Nasim Rezaei,
• Hidde Stokkel,
• Jian-Yao Zheng,
• Andrea Cerreta,
• Ilka Hermes,
• Minh Nguyen,
• Guus Rijnders and
• Rebecca Saive

Beilstein J. Nanotechnol. 2023, 14, 1059–1067, doi:10.3762/bjnano.14.87

• with atomic vertical resolution. In several studies, AFM has been used to determine photo-induced height/topography variation in organic–inorganic lead halide perovskites [15], nanosheets [16], and photosensitive polymers [17]. Kelvin probe force microscopy (KPFM), an electrostatic variant of AFM, can

• piezoelectric membrane as a reference sample, which can reveal its contribution to the piezo/photodiode device. Methodology Sample fabrication The device type-I employed in this study is a piezo/photodiode device, fabricated following a previously reported procedure [32], where the piezoelectric material, lead

• × 2.8) and (1.4 × 1.2) mm2 labeled as A, B, C, and D, respectively. In the process of fabrication, a 100 nm thick layer of LNO as the bottom electrode was first deposited, using pulsed laser deposition (PLD) technique, on a single crystal silicon wafer. Then, an 850 nm lead barium zirconia titanate

Exploring internal structures and properties of terpolymer fibers via real-space characterizations

• Michael R. Roenbeck and
• Kenneth E. Strawhecker

Beilstein J. Nanotechnol. 2023, 14, 1004–1017, doi:10.3762/bjnano.14.83

• crystallites, as random sequences of molecules including the DPE monomer (which locally changes chain orientation) would prevent neighboring molecules from forming cohesive extended crystals. This would lead to a mixture of ordered and disordered subdomains with varying alignment, as schematized in Figure 9

• . These unique molecular structures cannot lead to a truly crystalline fiber, but evidently, they are still strong and concentrated enough to form the nanoscale fibrils we repeatedly observe throughout Technora® fibers. At the same time, a random monomer sequence should result in a heterogeneous map of

• differentiation in Technora®, evidenced here via real-space scans, should also lead to more consistent strength values. Additional mechanical properties Significant connections can also be made between the structures of Technora® and Kevlar® fibers and other mechanical properties, such as creep and fatigue

Fragmentation of metal(II) bis(acetylacetonate) complexes induced by slow electrons

• Janina Kopyra and
• Hassan Abdoul-Carime

Beilstein J. Nanotechnol. 2023, 14, 980–987, doi:10.3762/bjnano.14.81

• , where they are decomposed under the focused kiloelectronvolt electron beam. In this technique, both the primary ionizing particles and the secondary species (e.g., ballistic electrons) with energies below 20 eV [6][7] lead to the decomposition of the molecules and the subsequent surface modification

• lenses and plates at oven temperature to prevent powder condensation, which otherwise may lead to undesirable changes in contact potentials during the measurements. The present experiments were carried out at temperatures typically 10–20 K below the temperatures for which the decomposition of the

Metal-organic framework-based nanomaterials for CO₂ storage: A review

• Ha Huu Do,
• Iqra Rabani and
• Hai Bang Truong

Beilstein J. Nanotechnol. 2023, 14, 964–970, doi:10.3762/bjnano.14.79

• bonds lead to a reduced pore size in UiO-66(Zr/Ti), thereby facilitating improved interactions between the MOF and CO2 molecules. MOF composites Post-synthetic functionalization was recognized as an effective strategy for enhancing the adsorption ability of nanosized MOF structures. However, it demands

Prediction of cytotoxicity of heavy metals adsorbed on nano-TiO₂ with periodic table descriptors using machine learning approaches

• Joyita Roy,
• Souvik Pore and
• Kunal Roy

Beilstein J. Nanotechnol. 2023, 14, 939–950, doi:10.3762/bjnano.14.77

• metals, upon release and emission, may interact with different environmental components, which may lead to co-exposure to living organisms. Nanoscale titanium dioxide (nano-TiO2) can adsorb heavy metals. The current idea is that nanoparticles (NPs) may act as carriers and facilitate the entry of heavy

• considerably high exposure TiO2 NPs may enter the food chain. Because of current industrialization processes, organisms are also exposed to heavy metal pollutants [7]. Emitted NPs may interact with the pollutants, and this may subsequently lead to bioaccumulation. The contamination of water and soil with heavy

• metals is also time- and dose-dependent. Among many other factors, the valence state plays an important role in toxicokinetics and toxicodynamics. Many studies have shown that an increased concentration of heavy metals is correlated with the severity of hepatotoxicity and nephrotoxicity [37]. Lead causes

Upscaling the urea method synthesis of CoAl layered double hydroxides

• Camilo Jaramillo-Hernández,
• Víctor Oestreicher,
• Martín Mizrahi and
• Gonzalo Abellán

Beilstein J. Nanotechnol. 2023, 14, 927–938, doi:10.3762/bjnano.14.76

• measurements. Despite the acute differences in the magnetic behavior of Co-based LDH and simonkolleite-like α-LH [46][54][55], the impurities do not lead to significant changes beyond slight variations in the DC magnetic susceptibility and the out-of-phase contribution of the dynamic susceptibility (Figure S7

• , regarding the obtained pure CoAl-LDHs, both scale-up processes lead to subtle modifications of the morphological aspects, which can be understood in terms of changes in nucleation, growth and precipitation (mass scale-up), and different alkalization rates (volumetric approach). Conclusion In this work, the

Antibody-conjugated nanoparticles for target-specific drug delivery of chemotherapeutics

• Mamta Kumari,
• Amitabha Acharya and
• Praveen Thaggikuppe Krishnamurthy

Beilstein J. Nanotechnol. 2023, 14, 912–926, doi:10.3762/bjnano.14.75

• resistance are the main causes of treatment failures in cancer [22]. Therefore, there is a need of smart delivery systems to eliminate even the last cancerous cell that might lead to tumor reoccurrence. Novel cancer targets have been identified based on the recent understanding of various molecular

• . The antibody-conjugated NPs were able to recognize the extracellular ligand-binding domain of EGFR and provided an effective targeted delivery of rapamycin. The ACNPs significantly increased the therapeutic effect of the chemotherapeutics [49]. The covalent binding can lead to a random immobilization

Green SPIONs as a novel highly selective treatment for leishmaniasis: an in vitro study against Leishmania amazonensis intracellular amastigotes

• Brunno R. F. Verçoza,
• Robson R. Bernardo,
• Luiz Augusto S. de Oliveira and
• Juliany C. F. Rodrigues

Beilstein J. Nanotechnol. 2023, 14, 893–903, doi:10.3762/bjnano.14.73

• reaction, catalyzing the formation of highly reactive hydroxyl radicals that lead to oxidative stress [28][29]. Thus, one of the possibilities for the observed antiproliferative effects could be the result of an imbalance in iron homeostasis with the consequent induction of oxidative stress and death of

• using a PT-PC PowerTome ultramicrotome (RMC Boeckeler, USA) stained with uranyl acetate and lead citrate and observed using a FEI TECNAI SPIRIT transmission electron microscope operating at 120 kV. Antiproliferative effects of SPIONs in Leishmania amazonensis promastigotes and intracellular amastigotes

Two-dimensional molecular networks at the solid/liquid interface and the role of alkyl chains in their building blocks

• Suyi Liu,
• Yasuo Norikane and
• Yoshihiro Kikkawa

Beilstein J. Nanotechnol. 2023, 14, 872–892, doi:10.3762/bjnano.14.72

• lead to different self-assembly behavior, which may be influenced by the structure of the molecular core. 3.3 Opening and closing of pores Changes in the size and appearance of the porous structures have also been reported for halogen-bonded molecular networks comprising linear molecular building

• representation of porphyrin substituted with (a) normal alkyl (P-N) and (b) alkynyl chains (P-A). The alkyl chains of P-N tend to extend in the solvent phase, whereas alkyne chains of P-A lead to a flat orientation. Figure 16 was adapted from [155], Copyright 2020 American Chemical Society. This content is not

N-Heterocyclic carbene-based gold etchants

• Robert B. Chevalier,
• Justin Pantano,
• Matthew K. Kiesewetter and
• Jason R. Dwyer

Beilstein J. Nanotechnol. 2023, 14, 865–871, doi:10.3762/bjnano.14.71

• clearly undesirable that an effort to form a stable monolayer could result in removal of underlying material, but similarly undesirable effects have been reported in the gold–thiol SAM literature. For example, gold–sulfur interactions can lead to a weaker bonding of gold surface atoms to the bulk. This

Ultralow-energy amorphization of contaminated silicon samples investigated by molecular dynamics

• Grégoire R. N. Defoort-Levkov,
• Alan Bahm and
• Patrick Philipp

Beilstein J. Nanotechnol. 2023, 14, 834–849, doi:10.3762/bjnano.14.68

• . The 500 subsequent bombardments with their collision cascades lead to the displacement of target atoms, creating disorder and point defects. Hydrogen and oxygen atoms get mixed into the target and can get trapped at interstitial or vacancy sites. The different kind of defects are not intrinsically

• was expected. Yet, we see that the highest angles lead to a minimal implantation of argon, while there are low counts for both oxygen and hydrogen for almost all angles. Since the irradiation process is limited to 500 impacts, statistical variations are obtained and lead to outliers in the counts for

A wearable nanoscale heart sound sensor based on P(VDF-TrFE)/ZnO/GR and its application in cardiac disease detection

• Yi Luo,
• Jian Liu,
• Jiachang Zhang,
• Yu Xiao,
• Ying Wu and
• Zhidong Zhao

Beilstein J. Nanotechnol. 2023, 14, 819–833, doi:10.3762/bjnano.14.67

• known as the positive piezoelectric effect. Most current electronic stethoscopes utilize the positive piezoelectric properties of rigid piezoelectric materials such as lead zirconate titanate (Pb(Zr1−xTix)O3, PZT). These materials convert sound wave vibrations into proportional electrical signals. After

• a series of processing steps, the heart sound signal is obtained. However, PZT has a brittle texture, does not fit the skin well, and lacks comfort when worn, making it unsuitable for wearable sensors [10]. Moreover, the lead in PZT is harmful to humans. In recent years, there has been a significant

• the ZnO particles, leading to stronger reflections of ZnO in the XRD pattern. However, an excessive addition of GR may lead to the formation of larger particles or agglomerates of GR. Consequently, this can compromise the alignment and arrangement of the ZnO crystals, thereby weakening the lattice

Nanostructured lipid carriers containing benznidazole: physicochemical, biopharmaceutical and cellular in vitro studies

• Giuliana Muraca,
• María Esperanza Ruiz,
• Rocío C. Gambaro,
• Sebastián Scioli-Montoto,
• María Laura Sbaraglini,
• Gisel Padula,
• José Sebastián Cisneros,
• Cecilia Yamil Chain,
• Vera A. Álvarez,
• Cristián Huck-Iriart,
• Guillermo R. Castro,
• María Belén Piñero,
• Matias Ildebrando Marchetto,
• Catalina Alba Soto,
• Germán A. Islan and
• Alan Talevi

Beilstein J. Nanotechnol. 2023, 14, 804–818, doi:10.3762/bjnano.14.66

• are used to establish cure criteria [8][9]. BNZ is associated with a variety of adverse reactions including allergic dermatitis, hypersensitivity syndrome, gastric pain, anorexia, insomnia, vomiting, which ultimately lead to withdrawal in 12–18% of the patients [10]. Additionally, the BENEFIT

Control of morphology and crystallinity of CNTs in flame synthesis with one-dimensional reaction zone

• Muhammad Hilmi Ibrahim,
• Norikhwan Hamzah,
• Mohd Zamri Mohd Yusop,
• Ni Luh Wulan Septiani and
• Mohd Fairus Mohd Yasin

Beilstein J. Nanotechnol. 2023, 14, 741–750, doi:10.3762/bjnano.14.61

• , such as fuel, catalyst, temperature, and diluent. However, the heterogeneous gas properties during combustion lead to a high temperature gradient and a wide distribution of chemical species within the flame. The interrelated processes of heat generation and carbon supply requires an optimum parametric

• across the radial locations. The shield at the outer annulus provides encapsulation of the primary flame and avoids the entrainment of ambient air into the reactant stream, which might lead to the formation of a secondary diffusion flame. Figure 1d indicates temperature uniformity at all HAB values and

• show a linear trend in diameter with a 44% variation between the lowest and highest HAB values and a 66% variation in crystallinity. The demonstrated control of CNT diameter and crystallinity based on the HAB is a unique capability of the present one-dimensional flame configuration, which might lead to