Facile synthesis of Fe-based metal–organic frameworks from Fe₂O₃ nanoparticles and their application for CO₂/N₂ separation

• Van Nhieu Le,
• Hoai Duc Tran,
• Minh Tien Nguyen,
• Hai Bang Truong,
• Toan Minh Pham and
• Jinsoo Kim

Beilstein J. Nanotechnol. 2024, 15, 897–908, doi:10.3762/bjnano.15.74

• separation performance of the as-prepared MIL-100(Fe) samples were investigated. Using 1.80 g of trimesic acid in the reaction system yielded the sample M-100Fe@Fe2O3#1.80, which proved to be the optimal sample. This choice struck a balance between the amount of required trimesic acid and the quality of the

• (XPS). Subsequently, the gas separation performance of the as-prepared MIL-100(Fe) samples was assessed by studies regarding CO2 and N2 adsorption isotherms at various temperatures with pressures up to 1 bar. Experimental Materials Iron(III) oxide (Fe2O3, 96%) and benzene-1,3,5-tricarboxylic acid

• primarily correspond to bridges of benzene-1,3,5-tricarboxylate in the MIL-100(Fe) framework. CO2/N2 separation performance To evaluate the effectiveness of CO2/N2 separation in the as-prepared samples, the adsorption behavior of CO2 and N2 was investigated at pressures ranging from 0 to 100 kPa at 298 K

Water-assisted purification during electron beam-induced deposition of platinum and gold

• Cristiano Glessi,
• Fabian A. Polman and
• Cornelis W. Hagen

Beilstein J. Nanotechnol. 2024, 15, 884–896, doi:10.3762/bjnano.15.73

• ligands are removed. However, in most cases, a large amount of the carbon from the organic ligands is incorporated in the deposits. The removal of the carbonaceous material and, hence, the increase of metallic content of FEBID structures is ultimately important for the performance of the obtained

The effect of age on the attachment ability of stick insects (Phasmatodea)

• Marie Grote,
• Stanislav N. Gorb and
• Thies H. Büscher

Beilstein J. Nanotechnol. 2024, 15, 867–883, doi:10.3762/bjnano.15.72

• Hennemann, 2023 and elucidate the age effects on the material and microstructure of the attachment apparatus. Attachment performance (adhesion and friction forces) on substrates with different roughnesses was compared between two different age groups, and the change of attachment performance was monitored

• Heteropterygidae can reach impressive life expectancies [41][44], with anecdotal reports extending over five years. The change in attachment performance was quantified through attachment force measurements. Because of the different properties of arolium and euplantulae [31][33], the attachment forces of whole

• animals were compared in two directions. The pull-off force was measured perpendicular to the substrate, and the traction force parallel to the substrate, to assess the ability of the insect to attach itself in the respective direction and evaluate potential differences arising from performance decay of

A review on the structural characterization of nanomaterials for nano-QSAR models

• Salvador Moncho,
• Eva Serrano-Candelas,
• Jesús Vicente de Julián-Ortiz and
• Rafael Gozalbes

Beilstein J. Nanotechnol. 2024, 15, 854–866, doi:10.3762/bjnano.15.71

• toxicity of NMs, its significance in the performance of QSAR models seems debatable. For example, the original nano-QSAR models of Puzyn et al. [26] and Gazewicz et al. [30] used only core-related descriptors, and they argued that the size does not significantly affect the property investigated for NMs in

Investigation on drag reduction on rotating blade surfaces with microtextures

• Qinsong Zhu,
• Chen Zhang,
• Fuhang Yu and
• Yan Xu

Beilstein J. Nanotechnol. 2024, 15, 833–853, doi:10.3762/bjnano.15.70

• Qinsong Zhu Chen Zhang Fuhang Yu Yan Xu College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics & Astronautics, Nanjing, 210016, China 10.3762/bjnano.15.70 Abstract To enhance the aerodynamic performance of aero engine blades, simulations and experiments regarding

• the microtexture decreased energy loss by 3.7% for a single blade under 57° angle of attack and 136.24 m/s, which was favorable regarding the drag reduction performance of the impeller with 45 blades. Keywords: blade; drag-reducing microtexture; geometrical parameters; placement position; simulations

• of lotus leaves [4]. A thin gas film captured by the superhydrophobic structure creates a slip interface between gas and liquid, which effectively improves the drag reduction and antifouling performance of lotus leaves [5]. However, the structures on biological surfaces are rather complex and not

Intermixing of MoS₂ and WS₂ photocatalysts toward methylene blue photodegradation

• Maryam Al Qaydi,
• Nitul S. Rajput,
• Michael Lejeune,
• Abdellatif Bouchalkha,
• Mimoun El Marssi,
• Steevy Cordette,
• Chaouki Kasmi and
• Mustapha Jouiad

Beilstein J. Nanotechnol. 2024, 15, 817–829, doi:10.3762/bjnano.15.68

• are evaluated for photodegradation (PD) of methylene blue under solar simulator irradiation. Our findings revealed that WS2 exhibited the highest PD efficiency of 67.6% and achieved an impressive PD rate constant of 6.1 × 10−3 min−1. Conversely, MoS2 displayed a somewhat lower PD performance of 43.5

• of Mo and W, in Figure 5h and Figure 5i. As it can be seen, the WS2 catalyst appeared to be well embedded within the MoS2 matrix indicating a successful intermixing of both phases. Photodegradation measurements To examine the photocatalytic performance of MoS2 and WS2 towards the PD of MB, we first

• the presence of MoS2 and WS2 photocatalysts, respectively. Similarly, the PD efficiency decreased from 43.5% to 27.6% and 67.6% to 30.3% for MoS2 and WS2, respectively. These results suggest that despite the very good performance of WS2 at the first runs, MoS2 has shown a longer lifetime and stability

Synthesis of silver–palladium Janus nanoparticles using co-sputtering of independent sources: experimental and theorical study

• Maria J. Martínez-Carreón,
• Francisco Solís-Pomar,
• Abel Fundora,
• Claudio D. Gutiérrez-Lazos,
• Sergio Mejía-Rosales,
• Hector N. Fernández-Escamilla,
• Jonathan Guerrero-Sánchez,
• Manuel F. Meléndrez and
• Eduardo Pérez-Tijerina

Beilstein J. Nanotechnol. 2024, 15, 808–816, doi:10.3762/bjnano.15.67

• –palladium alloyed nanocrystals are currently materials of high interest in electronics, specifically because they can be used in the building of electrodes for multilayer ceramic capacitors, exhibiting better thermal performance than silver nanocrystals, partly, because Pd has a relatively high critical

• poisoning, resulting in an increase in the useful life of the catalyst. Chunling An et al. synthesized AgPd BNPs in aqueous solution with sizes from 4 to 5 nm and demonstrated that they exhibit greater electrocatalytic activity and better long-term performance than silver nanoparticles [9]. Janus

Electron-induced ligand loss from iron tetracarbonyl methyl acrylate

• Hlib Lyshchuk,
• Atul Chaudhary,
• Thomas F. M. Luxford,
• Miloš Ranković,
• Jaroslav Kočišek,
• Juraj Fedor,
• Lisa McElwee-White and
• Pamir Nag

Beilstein J. Nanotechnol. 2024, 15, 797–807, doi:10.3762/bjnano.15.66

• . These spectra were recorded on the TEM-QMS setup, which has a higher energy resolution and more reliable performance at low electron energies than the CLUB setup (as will be demonstrated below). The arrows in Figure 4 denote positions of the calculated thresholds, which are tabulated in Table 2. The two

Electrospun polysuccinimide scaffolds containing different salts as potential wound dressing material

• Veronika Pálos,
• Krisztina S. Nagy,
• Rita Pázmány,
• Krisztina Juriga-Tóth,
• Bálint Budavári,
• Judit Domokos,
• Dóra Szabó,
• Ákos Zsembery and
• Angela Jedlovszky-Hajdu

Beilstein J. Nanotechnol. 2024, 15, 781–796, doi:10.3762/bjnano.15.65

• high-performance scanning electron microscope (JSM-6380LV, JEOL, Japan), with a resolution of 3.0 nm. Before the measurements, all the samples were fixed on a tape and coated with gold using a JFC-1200 Sputter Coating System (JEOL, Japan). Images of the samples were taken at 1000×, 5000×, and 10000

• most critical mechanical parameters, such as the elongation at breakpoint, the specific maximum load capacity, and the Young’s modulus. Their values, presented in Table 4, describe the mechanical performance of different scaffolds. The specific load capacity values of the scaffolds were determined

Green synthesis of biomass-derived carbon quantum dots for photocatalytic degradation of methylene blue

• Dalia Chávez-García,
• Mario Guzman,
• Viridiana Sanchez and
• Rubén D. Cadena-Nava

Beilstein J. Nanotechnol. 2024, 15, 755–766, doi:10.3762/bjnano.15.63

• exposed to the sunlight in comparison with their performance under incandescent lamp. It is commonly known that the sunlight emission spectrum presents a higher intensity at the ultraviolet range if compared to that of the tungsten lamp. Considering the band gap of the CQDs, we can affirm that sunlight

• samples demonstrate higher catalytic activity, with sample M3 from grape pomace exhibiting superior performance compared to that of other reported CQDs. Conclusion The successful synthesis of luminescent and stable carbon quantum dots (CQDs) via the hydrothermal method using biomass as a precursor was

• incandescent light in catalyzing reactions, and smaller-sized CQDs (1–10 nm) displayed higher catalytic activity, particularly evident in grape-pomace-derived samples. The superior performance of certain samples highlights the critical role of synthesis parameters and biomass sources in tailoring CQD

Simultaneous electrochemical determination of uric acid and hypoxanthine at a TiO₂/graphene quantum dot-modified electrode

• Vu Ngoc Hoang,
• Dang Thi Ngoc Hoa,
• Nguyen Quang Man,
• Le Vu Truong Son,
• Le Van Thanh Son,
• Vo Thang Nguyen,
• Le Thi Hong Phong,
• Ly Hoang Diem,
• Kieu Chan Ly,
• Ho Sy Thang and
• Dinh Quang Khieu

Beilstein J. Nanotechnol. 2024, 15, 719–732, doi:10.3762/bjnano.15.60

• URI, associated with the risk of gout [5]. Hence, simple and selective methods to determine the purine content in food and dietary products are of interest among researchers [6][7]. At the present time, several techniques for the determination of URI and HYP are available, such as high-performance

• lithium-ion storage performance of C-GQDs/α-Fe2O3 composites in lithium batteries presented excellent cyclability and rate capability [19]. Among several chemical approaches for the synthesis of titania, sol–gel processes have been commonly used for practical application. In these sol–gel methods

• the performance of TiO2/GQDs-GCE is better than or comparable with other electrodes with low detection limit. Repeatability, stability and reproducibility The parameters for validity of the proposed approaches are the within-run precision (repeatability), reproducibility, and the within-laboratory

Reduced subthreshold swing in a vertical tunnel FET using a low-work-function live metal strip and a low-k material at the drain

• Kalai Selvi Kanagarajan and
• Dhanalakshmi Krishnan Sadhasivan

Beilstein J. Nanotechnol. 2024, 15, 713–718, doi:10.3762/bjnano.15.59

• research paper, a vertical tunnel field-effect transistor (TFET) structure containing a live metal strip and a material with low dielectric constant is designed, and its performance metrics are analyzed in detail. Low-k SiO2 is incorporated in the channel–drain region. A live molybdenum metal strip with

• ); tunnel field-effect transistor (TFET); Introduction Rapid miniaturization of electronic devices has led to an increase in leakage current. Leakage current is a big challenge in miniaturized circuits. Miniaturization, at the same time, increased the device performance and reduced the area occupied by the

• thermionic emission as the carrier injection mechanism [3]. Band-to-band tunneling enables TFETs to have SS < 60 mV/dec [4][5][6][7]. The gate-to-drain capacitance (Cgd) effect (Miller capacitance effect) has an impact on TFET performance. Unwanted effects such as overshoot/undershoot in the inverter

Enhancing higher-order modal response in multifrequency atomic force microscopy with a coupled cantilever system

• Wendong Sun,
• Jianqiang Qian,
• Yingzi Li,
• Yanan Chen,
• Zhipeng Dou,
• Rui Lin,
• Peng Cheng,
• Xiaodong Gao,
• Quan Yuan and
• Yifan Hu

Beilstein J. Nanotechnol. 2024, 15, 694–703, doi:10.3762/bjnano.15.57

• performance of the coupled system with that of traditional cantilevers and quantify the enhancement in higher-order modal response. Also, the optimal conditions for the enhancement of macroscale cantilever modal response are explored. Additionally, we also supplement the characteristics of this model

Gold nanomakura: nanoarchitectonics and their photothermal response in association with carrageenan hydrogels

• Nabojit Das,
• Vikas,
• Akash Kumar,
• Sanjeev Soni and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2024, 15, 678–693, doi:10.3762/bjnano.15.56

• gold nanorods is due to their ability to absorb light in the NIR/IR region, ultimately leading to thermoresponsive performance of hydrogel actuators. A concise review on several reports also discussed the potential application of gold nanoparticles in developing hydrogel actuators/sensors for

Functional fibrillar interfaces: Biological hair as inspiration across scales

• Guillermo J. Amador,
• Brett Klaassen van Oorschot,
• Caiying Liao,
• Jianing Wu and
• Da Wei

Beilstein J. Nanotechnol. 2024, 15, 664–677, doi:10.3762/bjnano.15.55

• performance. Examples are reversible adhesion in geckos (Figure 3A), anchoring in burrowing earthworms (Figure 3B), flying in bristled-wing insects, such as thrips, (Figure 3C), and swimming in unicellular microorganisms, such as microalgae (Figure 3D). Climbing Adhesive hairs have been observed on the foot

• with slow flight and stall [84]. Indeed, when these hairs are removed, bats alter their flight performance by increasing speed and reducing their turning radius [85]. The membranous wings of insects are covered with bristle (or “hair”) sensilla that act as airflow sensors [86][87]. In Odonata wings

• ]. The bristles (or setae) of these wings support flapping flight by reducing inertia, enhancing aerodynamic performance, and facilitating their deployment (i.e., folding and unfolding). The wing acts as a leaky paddle, and can produce 66–96% of the aerodynamic drag force of an equivalent membranous wing

Laser synthesis of nanoparticles in organic solvents – products, reactions, and perspectives

• Theo Fromme,
• Sven Reichenberger,
• Katharine M. Tibbetts and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2024, 15, 638–663, doi:10.3762/bjnano.15.54

Comparative analysis of the ultrastructure and adhesive secretion pathways of different smooth attachment pads of the stick insect Medauroidea extradentata (Phasmatodea)

• Julian Thomas,
• Stanislav N. Gorb and
• Thies H. Büscher

Beilstein J. Nanotechnol. 2024, 15, 612–630, doi:10.3762/bjnano.15.52

• , especially in Phasmatodea. Recent investigations of the ultrastructure and material properties of the smooth tarsal attachment pads of phasmids complement our information on the morphology of the droplets [38], biomechanics of their attachment performance [28][46][47][48][49][50][51], and the complementarity

• , Figure 7B) [86]. The hemispherical pattern reduces the contact area between the cuticle and the substrate, thus decreasing contact forces. Similar surface structures were observed in the wax coverage of plants where they decreased the attachment performance of insects [84]. A reduction of the contact

On the additive artificial intelligence-based discovery of nanoparticle neurodegenerative disease drug delivery systems

• Shan He,
• Julen Segura Abarrategi,
• Harbil Bediaga,
• Sonia Arrasate and
• Humberto González-Díaz

Beilstein J. Nanotechnol. 2024, 15, 535–555, doi:10.3762/bjnano.15.47

• IFPTML-LDA and IFPTML-ANN techniques showed satisfactory performance, achieving Sp values of 73.0%–86.1% and Sn values of 70.0%–86.2% in the training and validation series, comprising 375,000 and 125,000 cases, respectively. Moreover, both models are easily accessible and provide logical solutions for

Electron-induced deposition using Fe(CO)₄MA and Fe(CO)₅ – effect of MA ligand and process conditions

• Hannah Boeckers,
• Atul Chaudhary,
• Petra Martinović,
• Amy V. Walker,
• Lisa McElwee-White and
• Petra Swiderek

Beilstein J. Nanotechnol. 2024, 15, 500–516, doi:10.3762/bjnano.15.45

• electron beam-induced surface activation (EBISA) [24][25], it can compromise spatial control by the electron beam and selectivity when aiming for 3D nanostructures [3][26]. Strategies to suppress autocatalytic deposit growth are thus desirable to devise FEBID processes with optimum performance [27

• fabrication of iron nanostructures with optimum performance. Post-deposition purification approaches relying on O2 or H2O are not appropriate for iron deposits because they lead to oxidation [8]. The further improvement of iron deposition can, however, be tackled by rational design of the precursor molecules

• applied that enable beam-induced heating of the deposit and, thus, enhance additional thermal reactions [19]. Furthermore, the somewhat better performance of Fe2(CO)9 [19] is obtained at the cost of a significantly lower volatility as compared to Fe(CO)5 [48]. A strategy that has not been explored so far

Fabrication of nanocrystal forms of ᴅ-cycloserine and their application for transdermal and enteric drug delivery systems

• Hsuan-Ang Tsai,
• Tsai-Miao Shih,
• Theodore Tsai,
• Jhe-Wei Hu,
• Yi-An Lai,
• Jui-Fu Hsiao and
• Guochuan Emil Tsai

Beilstein J. Nanotechnol. 2024, 15, 465–474, doi:10.3762/bjnano.15.42

• showed good performance in the Franz diffusion test and rodent pharmacokinetic studies due to the nanoparticle size and faster dissolution as compared with the commercial DCS powder. These DCS nanocrystal formulations could offer a new approach for the development of an advanced drug delivery system for

• polymers can provide gastric protection against gastric-irritating compounds and/or stomach acidity, leading to improved drug release performance. We aimed to fabricate DCS nanocrystals and study their physicochemical and biological properties. The DCS already has great water solubility (Log P = −1.72), so

• were prepared for in vivo PK study. The detailed compositions for the capsule formulations are described next. Enteric capsule formulation F: Kollicoat MAE 30 DP (BASF pharma), a reliable, high-performance film coating based on methacrylic acid-ethyl acrylate copolymer (1:1), is specifically designed

Superconducting spin valve effect in Co/Pb/Co heterostructures with insulating interlayers

• Andrey A. Kamashev,
• Nadir N. Garif’yanov,
• Aidar A. Validov,
• Vladislav Kataev,
• Alexander S. Osin,
• Yakov V. Fominov and
• Ilgiz A. Garifullin

Beilstein J. Nanotechnol. 2024, 15, 457–464, doi:10.3762/bjnano.15.41

• verify the so far unconfirmed earlier results by Deutscher and Meunier on an F1/S/F2 heterostructure with oxidized interlayers [Deutscher, G.; Meunier, F. Phys. Rev. Lett. 1969, 22, 395. https://doi.org/10.1103/PhysRevLett.22.395] and suggest an alternative route to optimize the performance of

Potential of a deep eutectic solvent in silver nanoparticle fabrication for antibiotic residue detection

• Le Hong Tho,
• Bui Xuan Khuyen,
• Ngoc Xuan Dat Mai and
• Nhu Hoa Thi Tran

Beilstein J. Nanotechnol. 2024, 15, 426–434, doi:10.3762/bjnano.15.38

• NFT and SDZ, respectively. Besides, the linearity coefficients are extremely close to 1 in the range of 10−8 to 10−3 M of concentration, and the SERS substrate shows remarkable uniformity along with great selectivity. This powerful SERS performance indicates that DESs have tremendous potential in the

• biosensors are commonly made of LSPR materials [17]. With the development of synthesis techniques, numerous nanostructures of noble metals have been extensively studied to improve the intrinsic parameters of sensors. Silver nanoparticles (Ag NPs) exhibit great performance in sensing applications owing to the

• best LSPR properties among the noble metals [18]. One of the decisive factors regarding the SERS performance of Ag NP-based platforms is the agglomeration state of the nanoparticles [19], which directly affects the “hot spots”. There have been many studies in which agglomeration of Ag NPs was adjusted

Classification and application of metal-based nanoantioxidants in medicine and healthcare

• Nguyen Nhat Nam,
• Nguyen Khoi Song Tran,
• Tan Tai Nguyen,
• Nguyen Ngoc Trai,
• Nguyen Phuong Thuy,
• Hoang Dang Khoa Do,
• Nhu Hoa Thi Tran and
• Kieu The Loan Trinh

Beilstein J. Nanotechnol. 2024, 15, 396–415, doi:10.3762/bjnano.15.36

• sites. In this regard, nanomaterials exhibit CAT-like activity with the ability to generate O2 from H2O2 to increase the performance of PDT and PTT in tumors. For example, nano-MnO2 with acid-/redox-responsive properties could decompose acidic H2O2 at the tumor sites by exhibiting CAT activity [168

Insect attachment on waxy plant surfaces: the effect of pad contamination by different waxes

• Elena V. Gorb and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2024, 15, 385–395, doi:10.3762/bjnano.15.35

• decemlineata Say, Gastrophysa viridula De Geer, Chrysolina americana L. (all Chrysomelidae), C. septempunctata, and H. axyridis (both Coccinellidae) showing a distinct sexual dimorphism in structure and attachment performance of adhesive pads [15][17][24][25][39][40][41][42], as well as on mushroom-shaped

Nanomedicines against Chagas disease: a critical review

• Maria Jose Morilla,
• Kajal Ghosal and
• Eder Lilia Romero

Beilstein J. Nanotechnol. 2024, 15, 333–349, doi:10.3762/bjnano.15.30

• benznidazole. Nanomedicines reduce toxicity and increase the effectiveness of current oncological therapies. Could nanomedicines improve the treatment of the neglected CD? This question will be addressed in this review, first by critically discussing selected reports on the performance of benznidazole and

• BNZ, and their contribution is examined below. The in vitro performance of BNZ loaded into nanoparticles (Nps) is shown in Table 1. In many of these reports, formulations were tested on different parasite stages (epimastigote, trypomastigote, and amastigote), and their cytotoxicity was assessed on

• acute phase of the infection. The project eventually gave up on its attempts to formulate BNZ in nanomedicines and focused on clinical trials of reduced BNZ doses for the treatment of the chronic phase [23]. In parallel to the BERENICE project, several reports showed the in vivo performance of different