N₂⁺-implantation-induced tailoring of structural, morphological, optical, and electrical characteristics of sputtered molybdenum thin films

• Usha Rani,
• Kafi Devi,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 495–509, doi:10.3762/bjnano.16.38

• significant influence of nitrogen inclusion on the stress evolution of Mo thin films. The crystalline orientation of the Mo films along a particular (hkl) plane can be quantified by determining the texture coefficient (TChkl), which is determined by the following equation [39][40]: where hkl represents the

• (111), (200), (220), or (311) orientations. The calculated TChkl values for each Mo thin film are summarized in Table 2. The texture coefficients of as-deposited and N2+-implanted Mo thin films demonstrate a strong orientation preference in the (111) direction. The TC111 values of these films are

• significantly larger than those for other orientations. Also, the texture coefficient for the (200) plane, though less than that for the (111) plane, is larger than those for the (220) and (311) planes. These observations reveal that the plane (111) is the dominant crystalline orientation in both as-deposited

Tailoring of physical properties of RF-sputtered ZnTe films: role of substrate temperature

• Kafi Devi,
• Usha Rani,
• Arun Kumar,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 333–348, doi:10.3762/bjnano.16.25

• temperature are amorphous; those deposited at other substrate temperatures are polycrystalline with a cubic zincblende structure and a preferred orientation along the [111] direction. An increase in crystallite size (from 37.60 ± 0.42 Å to 68.88 ± 1.04 Å) is observed with increased substrate temperature. This

• deposition temperature affects the preferred crystallite orientation. To quantitatively analyse the impact of deposition temperature on the preferred orientation, the texture coefficient (TC(hkl)) was determined using the relation [25] where I(hkl) stands for the Lorentz-fitted peak intensity, Is(hkl

• orientation in that particular (hkl) direction, that is, more crystallites grow in this particular direction, while TC values less than one indicate that the orientation is random. The TC value of the (111) planes is greater than one, which indicates that [111] is the preferred orientation for all ZnT/Qz film

Enhancing mechanical properties of chitosan/PVA electrospun nanofibers: a comprehensive review

• Nur Areisman Mohd Salleh,
• Amalina Muhammad Afifi,
• Fathiah Mohamed Zuki and
• Hanna Sofia SalehHudin

Beilstein J. Nanotechnol. 2025, 16, 286–307, doi:10.3762/bjnano.16.22

• . Key strategies for improvement are analyzed, including material modifications through blending and structural modifications like fiber orientation and multilayer constructions, and surface modifications such as coating and functionalization. The review also covers advanced characterization methods to

• consideration [21]. Electrospun nanofibrous membranes typically have poor mechanical characteristics. The materials used, the non-Newtonian fluids in the electrospinning solutions, and the nanofibers’ random orientation are the three primary factors of the poor mechanical performance of electrospun nanofibers

• chains in the fibers are not properly aligned, resulting in non-uniform mechanical and structural properties [23]. The incomplete crystallization of the fibers caused by the short and weak stretch process gives the fibers poor mechanical properties [24]. Last, there is the fibers’ random orientation

Orientation-dependent photonic bandgaps in gold-dust weevil scales and their titania bioreplicates

• Norma Salvadores Farran,
• Limin Wang,
• Primoz Pirih and
• Bodo D. Wilts

Beilstein J. Nanotechnol. 2025, 16, 1–10, doi:10.3762/bjnano.16.1

• }-oriented domains exhibits polarization conversion, rotating the angle of linearly polarized light. The overall coloration, resulting from the reflections from many scales, is close to uniformly diffuse because of the random orientation of the domains. Using titania sol–gel chemistry, we produced negative

• replicas that exhibited a 70 to 120 nm redshift of the bandgap, depending on the lattice orientation. The wavelength shift in {100} orientation is supported by full-wave optical modeling of a dual diamond network with an exchanged fill fraction (0.56) of the material with the refractive index in the range

• . The domains in lattice orientation {100} exhibited polarization conversion. The structure inferred from optical measurements was confirmed using conventional and focused ion beam scanning electron microscopy (FIB-SEM). By averaging the reciprocal space images obtained from different lattice

Mechanistic insights into endosomal escape by sodium oleate-modified liposomes

• Ebrahim Sadaqa,
• Satrialdi,
• Fransiska Kurniawan and
• Diky Mudhakir

Beilstein J. Nanotechnol. 2024, 15, 1667–1685, doi:10.3762/bjnano.15.131

• integrity without inducing substantial changes in lipid orientation. The RDF data (Figure 8c) provides critical insights into the spatial distribution of OLA and AUR relative to the lipid components. OLA demonstrates a higher RDF peak, indicating a more structured and deeper association with the lipid

Fabrication of hafnium-based nanoparticles and nanostructures using picosecond laser ablation

• Abhishek Das,
• Mangababu Akkanaboina,
• Jagannath Rathod,
• R. Sai Prasad Goud,
• Kanaka Ravi Kumar,
• Raghu C. Reddy,
• Ratheesh Ravendran,
• Katia Vutova,
• S. V. S. Nageswara Rao and
• Venugopal Rao Soma

Beilstein J. Nanotechnol. 2024, 15, 1639–1653, doi:10.3762/bjnano.15.129

• liquid exceeds the vapour pressure exerted by HfO2, the cavitation bubble collapses, and the vapour rushes through the liquid in the form of a jet [23][24][41]. The lower temperature of the surrounding liquid leads to the formation of nuclei [23][42][43] with random crystallographic orientation, which

• properties make Hf metal suitable for laser patterning of sub-wavelength-size structures, and the choice of the liquid for LAL enables the variation of feature size. We have used linearly polarised light in the present study. The orientation of the LIPSS depends on the polarization and rotates with the input

• polarization. The available literature on LIPSS suggests that there will be no changes in the spacing or other morphological features except the orientation of the LIPSS with respect to the polarisation. Combined with the picosecond laser’s high precision processing and industrial scalability, Hf is a

Integrating high-performance computing, machine learning, data management workflows, and infrastructures for multiscale simulations and nanomaterials technologies

• Fabio Le Piane,
• Mario Vozza,
• Matteo Baldoni and
• Francesco Mercuri

Beilstein J. Nanotechnol. 2024, 15, 1498–1521, doi:10.3762/bjnano.15.119

Effect of radiation-induced vacancy saturation on the first-order phase transformation in nanoparticles: insights from a model

• Aram Shirinyan and
• Yuriy Bilogorodskyy

Beilstein J. Nanotechnol. 2024, 15, 1453–1472, doi:10.3762/bjnano.15.117

• simulations reveals that the critical irradiation dose for nanocrystallinity collapse varies among different simulation cells. Not only the size, but also the crystallographic orientation, shape of the grains, and structure of the grain boundaries have a strong impact on the stability of the nanocrystalline

A biomimetic approach towards a universal slippery liquid infused surface coating

• Ryan A. Faase,
• Madeleine H. Hummel,
• AnneMarie V. Hasbrook,
• Andrew P. Carpenter and
• Joe E. Baio

Beilstein J. Nanotechnol. 2024, 15, 1376–1389, doi:10.3762/bjnano.15.111

• in the bulk. A final mode was assigned to the CF3 asymmetric stretching at 1370 cm−1 [46]. Observed changes across the SFG spectra collected with different polarization combinations provide information about the orientation of molecular bonds at the interface [26][27]. Here, by collecting SFG spectra

• from the COC–PDA–FDT sample with ppp, ssp, and sps combinations, we acquired info about the general orientation of both the polymerized dopamine molecules and FDT after being bound to the surface. The CF3 asymmetric stretching, specifically in sps, at 1400 cm−1 provides evidence that the FDT molecule

New design of operational MEMS bridges for measurements of properties of FEBID-based nanostructures

• Bartosz Pruchnik,
• Krzysztof Kwoka,
• Ewelina Gacka,
• Dominik Badura,
• Piotr Kunicki,
• Andrzej Sierakowski,
• Paweł Janus,
• Tomasz Piasecki and
• Teodor Gotszalk

Beilstein J. Nanotechnol. 2024, 15, 1273–1282, doi:10.3762/bjnano.15.103

• . The silicon edges under the opMEMS bridge bases were defined to be vertical and precisely located, thanks to the lattice orientation. The opMEMS were 600 μm long, 100 μm wide, and 80 nm thick, with 40 nm of silicon nitride body and 40 nm of platinum paths on top. To reduce the stiffness of the opMEMS

The role of a tantalum interlayer in enhancing the properties of Fe₃O₄ thin films

• Hai Dang Ngo,
• Vo Doan Thanh Truong,
• Van Qui Le,
• Hoai Phuong Pham and
• Thi Kim Hang Pham

Beilstein J. Nanotechnol. 2024, 15, 1253–1259, doi:10.3762/bjnano.15.101

• the Fe3O4 thin films causes a shift in the peak observed in sample 3 [32]. Our results reveal that the growth orientation of the Fe3O4 thin film depends on the lattice mismatch between the Fe3O4 thin film and the substrate or buffer layer. When the Fe3O4 thin film is deposited on the amorphous SiO2

• substrate, the lattice mismatch between the amorphous substrate and the crystalline film is large. In this case, the growth orientation of Fe3O4 thin film is determined by the direction having the least internal energy, which is [111]. The energetically favored [111] direction also has the highest

• probability of occupying random dangling bonds from the amorphous substrate surface because it has the highest areal density [13][33]. In contrast, the small lattice mismatch between Fe3O4 thin film and MgO(100) substrate (≈0.3% [29]) results in the growth orientation controlled by the substrate and leads to

Realizing active targeting in cancer nanomedicine with ultrasmall nanoparticles

• André F. Lima,
• Giselle Z. Justo and
• Alioscka A. Sousa

Beilstein J. Nanotechnol. 2024, 15, 1208–1226, doi:10.3762/bjnano.15.98

• interaction with cell surface receptors on cancer cells, the incorporation of targeting ligands onto usNPs must optimize the exposure, orientation, and conformation of the functional portion. For small molecules and peptides in particular, the functional moiety must circumvent both steric hindrance from the

Photocatalytic methane oxidation over a TiO₂/SiNWs p–n junction catalyst at room temperature

• Qui Thanh Hoai Ta,
• Luan Minh Nguyen,
• Ngoc Hoi Nguyen,
• Phan Khanh Thinh Nguyen and
• Dai Hai Nguyen

Beilstein J. Nanotechnol. 2024, 15, 1132–1141, doi:10.3762/bjnano.15.92

• ) [43][44]. As expected, the crystal orientation of the TiO2/SiNWs catalyst obviously led to the creation of a robust p–n junction photocatalyst. The SEM analysis further confirms the morphological evolution during etching and TiO2 ALD. As revealed in Supporting Information File 1, Figure S1, the

• . Experimental Chemicals and materials Commercial p-type Si 3-inch wafers (⟨100⟩ orientation, boron-doped, resistivity = 0.01–1 Ω·cm) were purchased from Silicon Mitus Corporation, South Korea. Silver nitrate (AgNO3, 0.1 M), hydrofluoric acid HF (50 wt %), nitric acid (HNO3, 63%), acetone, and ethanol were

Bolometric IR photoresponse based on a 3D micro-nano integrated CNT architecture

• Yasameen Al-Mafrachi,
• Sandeep Yadav,
• Sascha Preu,
• Jörg J. Schneider and
• Oktay Yilmazoglu

Beilstein J. Nanotechnol. 2024, 15, 1030–1040, doi:10.3762/bjnano.15.84

• for non-cryogenic IR microbolometer technology, carbon nanotubes (CNTs) have emerged as highly promising candidates [2] with broadband blackbody absorption [3], high resistance perpendicular to the CNT orientation [4], low lateral thermal conductivity [5], a high temperature coefficient of resistance

• applications [3]. The device resistance perpendicular to the CNT orientation is mainly determined by the high junction resistances of the neighboring aligned CNTs [4]. This configuration allows for high device resistance, low thermal conductivity, and high temperature coefficient of resistance, thus, enabling

• customized specific requirements for various applications. While the thermal conductivity along the CNT orientation is large, it decreases dramatically in the perpendicular direction [5]. This thermal behavior varies significantly depending on structure, density, and fabrication of the CNTs. Single-walled

Water-assisted purification during electron beam-induced deposition of platinum and gold

• Cristiano Glessi,
• Fabian A. Polman and
• Cornelis W. Hagen

Beilstein J. Nanotechnol. 2024, 15, 884–896, doi:10.3762/bjnano.15.73

• orientation) with a native silicon oxide layer. Samples of 1 × 1 cm2 were used, on to which an array of annular patterns was lithographically defined, by laser lithography and etching using an SF6–O2 dry-etch, to facilitate location of the deposition areas. The substrates were roughly cleaned in acetone and

Intermixing of MoS₂ and WS₂ photocatalysts toward methylene blue photodegradation

• Maryam Al Qaydi,
• Nitul S. Rajput,
• Michael Lejeune,
• Abdellatif Bouchalkha,
• Mimoun El Marssi,
• Steevy Cordette,
• Chaouki Kasmi and
• Mustapha Jouiad

Beilstein J. Nanotechnol. 2024, 15, 817–829, doi:10.3762/bjnano.15.68

• orientation is indicated by the (103) direction. In the high-resolution image, some edge-related defects can also be seen which is common in CVD-grown MoS2 materials [34]. Similarly, the WS2 sample exhibits a flake shape along with a high crystalline nature of the flakes (Figure 5c, Figure 5d). Figure 5e and

Synthesis of silver–palladium Janus nanoparticles using co-sputtering of independent sources: experimental and theorical study

• Maria J. Martínez-Carreón,
• Francisco Solís-Pomar,
• Abel Fundora,
• Claudio D. Gutiérrez-Lazos,
• Sergio Mejía-Rosales,
• Hector N. Fernández-Escamilla,
• Jonathan Guerrero-Sánchez,
• Manuel F. Meléndrez and
• Eduardo Pérez-Tijerina

Beilstein J. Nanotechnol. 2024, 15, 808–816, doi:10.3762/bjnano.15.67

• carried out by molecular dynamics and TEM simulations to investigate the atomic ordering and orientation of the crystal lattice, while a detailed description of the atomic arrangement at the interface between the two metals was obtained using density functional theory (DFT). Experimental In this work, the

• this paper. Figure 2 shows two TEM micrographs. In Figure 2a, it can be seen that the nanoparticles have a Janus-type structure. Their growth in a preferential orientation in the assembly process enabled the formation of this complex and hierarchical structure. In addition, it is observed that, in the

• differences in intensity in the regions of a particle are unlikely to be due to differences in atomic number. We generated images based on the assumption that the intensity has a Z1.7 dependence; only when there is a small orientation mismatch, the Pd and and Ag regions can be distinguished. An example of one

Effect of repeating hydrothermal growth processes and rapid thermal annealing on CuO thin film properties

• Monika Ozga,
• Eunika Zielony,
• Aleksandra Wierzbicka,
• Anna Wolska,
• Marcin Klepka,
• Marek Godlewski,
• Bogdan J. Kowalski and
• Bartłomiej S. Witkowski

Beilstein J. Nanotechnol. 2024, 15, 743–754, doi:10.3762/bjnano.15.62

• additional peak indicates an improvement in the crystallographic quality of these layers. Regardless of the examined films, the preferred (111) orientation remains consistent. Analysis of its position shows a slight shift towards higher angles observed with each subsequent repetition of the HT+RTA procedure

Elastic modulus of β-Ga₂O₃ nanowires measured by resonance and three-point bending techniques

• Annamarija Trausa,
• Sven Oras,
• Sergei Vlassov,
• Mikk Antsov,
• Tauno Tiirats,
• Andreas Kyritsakis,
• Boris Polyakov and
• Edgars Butanovs

Beilstein J. Nanotechnol. 2024, 15, 704–712, doi:10.3762/bjnano.15.58

• orientation (e.g., E100 = 138 GPa, E010 = 263 GPa, E001 = 228 GPa [26]) emphasising directional differences in the mechanical properties of the material. Since our as-grown NWs tend to exhibit various growth directions, as was determined in the TEM studies, this elasticity anisotropy could be one of the

• into the various factors affecting the elastic properties of Ga2O3 NWs, a further study should be performed on individual nanostructures with advanced combinatory methods, such as in-situ TEM mechanical resonance, to precisely determine the geometrical parameters, crystalline orientation, and presence

Functional fibrillar interfaces: Biological hair as inspiration across scales

• Guillermo J. Amador,
• Brett Klaassen van Oorschot,
• Caiying Liao,
• Jianing Wu and
• Da Wei

Beilstein J. Nanotechnol. 2024, 15, 664–677, doi:10.3762/bjnano.15.55

• outside world or determine body or appendage orientation [128]. Mechanosensation Hairs, as mechanical receptors, are capable of perceiving and distinguishing a multitude of external stimuli such as touch, vibration, or fluid flows [129][130]. The mechanosensation of hairs relies on the sensory cells at

• the limbs of insects are used for proprioreception or to sense the orientation and motion of the limbs, which helps in their control of locomotion [131]. Furthermore, many insects, such as bees, can enhance their foraging speed by utilizing hairy mechanical receptors to detect physical characteristics

Directed growth of quinacridone chains on the vicinal Ag(35 1 1) surface

• Niklas Humberg,
• Lukas Grönwoldt and
• Moritz Sokolowski

Beilstein J. Nanotechnol. 2024, 15, 556–568, doi:10.3762/bjnano.15.48

• the vicinal Ag(35 1 1) surface was investigated by scanning tunneling microscopy and low-energy electron diffraction. The focus was on the influence of the steps on the QA structures and their preferential azimuthal orientations with the aim of achieving a selective orientation. After deposition at a

• –24873]. The vicinal surface leads to one additional chain orientation, which is parallel to the Ag step edges. However, most chains nucleate on the Ag terraces between steps with four distinct azimuthal orientations that are identical to those on Ag(100), and which are determined by the interactions

• the azimuthal orientation of the molecules, resulting in a preferential growth of the chains in two of the four azimuthal orientations. We explain this by the adaptation of favorable adsorption sites, which involve the replacement of Ag atoms by QA molecules with specific azimuthal orientations at the

Superconducting spin valve effect in Co/Pb/Co heterostructures with insulating interlayers

• Andrey A. Kamashev,
• Nadir N. Garif’yanov,
• Aidar A. Validov,
• Vladislav Kataev,
• Alexander S. Osin,
• Yakov V. Fominov and
• Ilgiz A. Garifullin

Beilstein J. Nanotechnol. 2024, 15, 457–464, doi:10.3762/bjnano.15.41

• full spin valve effect. A shift of the superconducting transition temperature Tc by switching the mutual orientation of the magnetizations of the two ferromagnetic Co layers from antiparallel to parallel amounted to ΔTc = 0.2 K at the optimal thickness of the superconducting Pb layer. Our findings

• structure based on the control of the average exchange field acting on the S layer by changing the mutual orientation of the magnetization vectors of the F layers and, thus, suppressing superconductivity to a different degree. Typically, the superconducting transition temperature Tc of the SSV is minimal

• . Several experimental works confirmed the predicted influence of the mutual orientation of the magnetization vectors of the F layers on Tc in the F1/S/F2 type of structures [4][5][6][23][24][25]. However, a full switching between the normal and the superconducting state was not achieved because in these

Unveiling the nature of atomic defects in graphene on a metal surface

• Karl Rothe,
• Nicolas Néel and
• Jörg Kröger

Beilstein J. Nanotechnol. 2024, 15, 416–425, doi:10.3762/bjnano.15.37

• laterally larger and deeper depression than type 2 (≈23%, Figure 1c). Moreover, type-1 defects occur nearly exclusively (≈100%) at valley sites of the moiré lattice. The hcp and fcc stacking of the valley sites defines the orientation of the triangular shape of the defect, pointing in opposite directions at

Classification and application of metal-based nanoantioxidants in medicine and healthcare

• Nguyen Nhat Nam,
• Nguyen Khoi Song Tran,
• Tan Tai Nguyen,
• Nguyen Ngoc Trai,
• Nguyen Phuong Thuy,
• Hoang Dang Khoa Do,
• Nhu Hoa Thi Tran and
• Kieu The Loan Trinh

Beilstein J. Nanotechnol. 2024, 15, 396–415, doi:10.3762/bjnano.15.36

• ]. Figure 2 shows the property of ceria nanoplates with multi-antioxidant activities and the relationship between lattice thickness, Ce3+ concentration, and the resulting strain in ceria with specific surface orientation (100) [32]. Similarly, a large number of different metal-based nanomaterials have been

• thickness, Ce3+ concentration, and the resulting strain in ceria with specific surface orientation (100). Figure 2 was adapted with permission from [32]. Copyright 2023 American Chemical Society. This content is not subject to CC BY 4.0. (a) Percent injected dose (%ID) in blood of EaNA and Cy5-labeled human

Investigating ripple pattern formation and damage profiles in Si and Ge induced by 100 keV Ar⁺ ion beam: a comparative study

• Indra Sulania,
• Harpreet Sondhi,
• Tanuj Kumar,
• Sunil Ojha,
• G R Umapathy,
• Ambuj Mishra,
• Ambuj Tripathi,
• Richa Krishna,
• Devesh Kumar Avasthi and
• Yogendra Kumar Mishra

Beilstein J. Nanotechnol. 2024, 15, 367–375, doi:10.3762/bjnano.15.33

• wavelength ranging from 400 to 740 nm (Figure 1B). The ripple patterns are more pronounced and have a preferential orientation perpendicular to the ion beam direction (shown by an arrow on each of the AFM images). The wavelength of the ripples obtained for initial fluences was ≈430 nm, and became wider (≈740

• attributed to the accumulation of defects produced by Ar irradiation. The RBS-c spectra recorded for Si and Ge single-crystal samples pre-damaged with 100 keV Ar+ ions at RT are presented in Figure 5A and Figure 5B, respectively. The RBS spectrum recorded for the pristine sample in random orientation