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Search for "donor/acceptor" in Full Text gives 182 result(s) in Beilstein Journal of Organic Chemistry.

Active-metal template clipping synthesis of novel [2]rotaxanes

  • Cătălin C. Anghel,
  • Teodor A. Cucuiet,
  • Niculina D. Hădade and
  • Ion Grosu

Beilstein J. Org. Chem. 2023, 19, 1776–1784, doi:10.3762/bjoc.19.130

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  • ) [30][31], metal-ion template (coordination bonds [22][32], ion-dipol [16], donoracceptor (charge transfer, π–π stacking) [30][33], and oligoamide macrocycle-hydrogen acceptors (hydrogen bonding) [20][34]. In active-metal template methods (Figure 1) the metal ion acts both as template and catalyst for
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Published 20 Nov 2023

Quinoxaline derivatives as attractive electron-transporting materials

  • Zeeshan Abid,
  • Liaqat Ali,
  • Sughra Gulzar,
  • Faiza Wahad,
  • Raja Shahid Ashraf and
  • Christian B. Nielsen

Beilstein J. Org. Chem. 2023, 19, 1694–1712, doi:10.3762/bjoc.19.124

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  • compounds exhibited good coplanarity through intramolecular interactions, narrow bandgaps, broad absorption in the NIR region and PCEs above 10% [32]. Ayub et al. decorated the central donoracceptor–donor unit of Qx17 and Qx18 with five new terminal end groups, resulting in the Qx19 series, and predicted
  • morphology on Qx26 and Qx27, employing indacenodithiophene, Qx and rhodanine as donor, acceptor and end group, respectively. The incorporation of specific side chains facilitated improved thermal stability, solubility, and broad absorption spectra (300–750 nm), narrow bandgaps (1.68–1.74 eV) and PCEs in the
  • quinone unit on quinoxaline to achieve donoracceptor interactions and desirable electronic properties. The compounds exhibited absorption, emission, electrochemical, and thermal properties suitable for n-type materials. Theoretical properties were also investigated using time-dependent DFT. The HOMO and
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Published 09 Nov 2023

A deep-red fluorophore based on naphthothiadiazole as emitter with hybridized local and charge transfer and ambipolar transporting properties for electroluminescent devices

  • Suangsiri Arunlimsawat,
  • Patteera Funchien,
  • Pongsakorn Chasing,
  • Atthapon Saenubol,
  • Taweesak Sudyoadsuk and
  • Vinich Promarak

Beilstein J. Org. Chem. 2023, 19, 1664–1676, doi:10.3762/bjoc.19.122

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  • Frontier Research Center, Vidyasirimedhi Institute of Science and Technology, Wangchan, Rayong 21210, Thailand 10.3762/bjoc.19.122 Abstract Herein, we report the synthesis and characterization of an efficient ambipolar charge-carrier-transporting deep-red fluorophore (TPECNz) based on a donoracceptor
  • extended π-conjugation lengths which eventually favor the undesired formation of poorly emissive molecular aggregates must be overcome. Alternatively, donoracceptor (D–A)-type organic fluorophores have been introduced and successfully exploited for the development of fluorophores with DR/NIR emissions
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Published 03 Nov 2023

A series of perylene diimide cathode interlayer materials for green solvent processing in conventional organic photovoltaics

  • Kathryn M. Wolfe,
  • Shahidul Alam,
  • Eva German,
  • Fahad N. Alduayji,
  • Maryam Alqurashi,
  • Frédéric Laquai and
  • Gregory C. Welch

Beilstein J. Org. Chem. 2023, 19, 1620–1629, doi:10.3762/bjoc.19.119

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  • investigation of the processes involved in the formation of the interfacial layer between the donoracceptor and the charge transport layer. Nevertheless, based on all the optoelectrical characterization, proposed N-annulated perylene diimides-based CILs are suitable candidates for CILs that can be replaced
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Published 26 Oct 2023

Visible-light-induced nickel-catalyzed α-hydroxytrifluoroethylation of alkyl carboxylic acids: Access to trifluoromethyl alkyl acyloins

  • Feng Chen,
  • Xiu-Hua Xu,
  • Zeng-Hao Chen,
  • Yue Chen and
  • Feng-Ling Qing

Beilstein J. Org. Chem. 2023, 19, 1372–1378, doi:10.3762/bjoc.19.98

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  • ., Zibo 256401, China 10.3762/bjoc.19.98 Abstract A visible-light-induced nickel-catalyzed cross coupling of alkyl carboxylic acids with N-trifluoroethoxyphthalimide is described. Under purple light irradiation, an α-hydroxytrifluoroethyl radical generated from a photoactive electron donoracceptor
  • -difluoroethoxyphthalimide as the fluoroalkylating reagent failed to afford the desired product. According to our previous work [39] and literature precedent [27][35][38], a possible mechanism is proposed in Figure 2. The interaction between 2 and HE generates an electron donoracceptor (EDA) complex A, which undergoes a
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Published 11 Sep 2023

Organic thermally activated delayed fluorescence material with strained benzoguanidine donor

  • Alexander C. Brannan,
  • Elvie F. P. Beaumont,
  • Nguyen Le Phuoc,
  • George F. S. Whitehead,
  • Mikko Linnolahti and
  • Alexander S. Romanov

Beilstein J. Org. Chem. 2023, 19, 1289–1298, doi:10.3762/bjoc.19.95

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  • performance in OLED devices [1]. 4CzIPN is a donoracceptor-type system where carbazole donor ligands are bound to the benzonitrile acceptor core moiety. In this work we have substituted the carbazole donors with 5H-benzo[d]benzo[4,5]imidazo[1,2-a]imidazole (benzoguanidine) ligands to give 4BGIPN, see Figure
  • of 55.1(2)–60.2(2)º for 4CzIPN thus indicating that various carbazole donor ligands possess a very similar twist orientation [12]. The donoracceptor twist angle has been demonstrated to be one of the key structural parameters enabling fast radiative rates for purely organic TADF materials since it’s
  • matrices regardless of numerous efforts and cooling the films down to 16 K and applying long time delays. Conclusion We have synthesized and characterized a donoracceptor-type thermally activated delayed fluorescent emitter 4BGIPN with four terminal benzoguanidine donor moieties surrounding the
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Published 07 Sep 2023

Exploring the role of halogen bonding in iodonium ylides: insights into unexpected reactivity and reaction control

  • Carlee A. Montgomery and
  • Graham K. Murphy

Beilstein J. Org. Chem. 2023, 19, 1171–1190, doi:10.3762/bjoc.19.86

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  • include nucleophile σ-hole selectivity, and how ylide structural modifications and intramolecular halogen bonding (e.g., the ortho-effect) can improve ylide stability or solubility, and alter reaction outcomes. Keywords: electron donoracceptor complex; halogen bonding; σ-holes; iodonium ylides; ortho
  • as an electron donoracceptor complex) [121], and this bonding description has recently been used to support proposals for single electron transfer (SET) reaction pathways between iodonium ylides and various halogen bond acceptors. Alternatively, halogen-bonded complexes of iodonium ylides could lead
  • to changes in an ylide’s UV–vis absorption profile, or to its overall basicity or nucleophilicity, both of which could lead new and unexpected reactivity. The first example that specifically invoked electron donoracceptor complexes of iodonium ylides was reported in 2018 by Wang and co-workers [122
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Published 07 Aug 2023

The effect of dark states on the intersystem crossing and thermally activated delayed fluorescence of naphthalimide-phenothiazine dyads

  • Liyuan Cao,
  • Xi Liu,
  • Xue Zhang,
  • Jianzhang Zhao,
  • Fabiao Yu and
  • Yan Wan

Beilstein J. Org. Chem. 2023, 19, 1028–1046, doi:10.3762/bjoc.19.79

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  • intersystem crossing (rISC) is slow, without coupling with an approximate 3LE state. These studies are useful for an in-depth understanding of the photophysical mechanisms of the TADF emitters, as well as for molecular structure design of new electron donoracceptor TADF emitters. Keywords: charge-transfer
  • for this kind of emitters is an electron donoracceptor dyad, and the molecular geometry is usually orthogonal, i.e., the planes of the π-conjugation systems of the electron donor and acceptor are perpendicular to each other. As a result, the highest occupied molecular orbital (HOMO) and lowest
  • is far from mature [19][20][21]. Initially a two-state model was used for understanding of the photophysical processes of the electron donoracceptor TADF emitters [9][22][23][24][25][26]. Soon it was realized this over simplified model is nonsufficient. For instance, the singlet/triplet charge
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Published 19 Jul 2023

First synthesis of acylated nitrocyclopropanes

  • Kento Iwai,
  • Rikiya Kamidate,
  • Khimiya Wada,
  • Haruyasu Asahara and
  • Nagatoshi Nishiwaki

Beilstein J. Org. Chem. 2023, 19, 892–900, doi:10.3762/bjoc.19.67

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  • , but a dihydrofuran, so the cyclopropane 1b’ reported in the literature [12][13][19] is presumably incorrect [22]. In the cases of donoracceptor cyclopropanes possessing an electron-donating group such as an alkoxy or amino group, ring expansion caused by an intramolecular attack of nitro oxygen
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Published 21 Jun 2023

Synthesis, structure, and properties of switchable cross-conjugated 1,4-diaryl-1,3-butadiynes based on 1,8-bis(dimethylamino)naphthalene

  • Semyon V. Tsybulin,
  • Ekaterina A. Filatova,
  • Alexander F. Pozharskii,
  • Valery A. Ozeryanskii and
  • Anna V. Gulevskaya

Beilstein J. Org. Chem. 2023, 19, 674–686, doi:10.3762/bjoc.19.49

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  • -conjugation of 1,8-bis(dimethylamino)naphthalene (DMAN) fragments through a butadiyne linker and a donoracceptor aryl–C≡C–DMAN conjugation path. The conjugation path can be “switched” simply by protonation of DMAN fragments. X-ray diffraction, UV–vis spectroscopy and cyclic voltammetry are applied to analyze
  • the extent of π-conjugation and the efficiency of particular donoracceptor conjugation path in these new compounds. X-ray structures and absorption spectra of doubly protonated tetrafluoroborate salts of the oligomers are also discussed. Keywords: 1,8-bis(dimethylamino)naphthalene; cross-conjugated
  • systems; 1,4-diaryl-1,3-butadiynes; donoracceptor systems; Glaser–Hay reaction; Introduction π-Conjugated oligomers and polymers attracted considerable attention from the very start as a promising class of semiconductors, chemosensors, and various electronic devices [1][2]. Although silicon and
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Published 15 May 2023

Nucleophile-induced ring contraction in pyrrolo[2,1-c][1,4]benzothiazines: access to pyrrolo[2,1-b][1,3]benzothiazoles

  • Ekaterina A. Lystsova,
  • Maksim V. Dmitriev,
  • Andrey N. Maslivets and
  • Ekaterina E. Khramtsova

Beilstein J. Org. Chem. 2023, 19, 646–657, doi:10.3762/bjoc.19.46

Graphical Abstract
  • -aminothiophenol with donoracceptor cyclopropanes (Scheme 2, entry 10) [27], condensations of o-aminothiophenol with 4-oxo acids or their derivatives (Scheme 2, entry 11) [2][28][29][30][31] and cascade reactions of o-aminothiophenol, furfural and anhydrides of 2,3-unsaturated carboxylic acids (Scheme 2, entry 12
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Published 11 May 2023

Direct C2–H alkylation of indoles driven by the photochemical activity of halogen-bonded complexes

  • Martina Mamone,
  • Giuseppe Gentile,
  • Jacopo Dosso,
  • Maurizio Prato and
  • Giacomo Filippini

Beilstein J. Org. Chem. 2023, 19, 575–581, doi:10.3762/bjoc.19.42

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  • tool to guide the development of greener and more convenient synthetic protocols [7][8][9][10][11][12]. In this context, photochemical approaches based on electron donoracceptor (EDA) complexes have been successfully exploited to drive the direct C–H functionalization of a large number of organic
  • yield the final products "A–D". This approach is not limited to reagents with appropriate donoracceptor characteristics [13][19]. Indeed, sacrificial electron donors and electron-deficient radical precursors can be used to form photoactive EDA complexes. Specifically, these aggregates can be employed
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Published 27 Apr 2023

Combretastatins D series and analogues: from isolation, synthetic challenges and biological activities

  • Jorge de Lima Neto and
  • Paulo Henrique Menezes

Beilstein J. Org. Chem. 2023, 19, 399–427, doi:10.3762/bjoc.19.31

Graphical Abstract
  • for synthesis. In general, the synthesis of these macrocyclic compounds can be accomplished by using two distinct disconnections (Scheme 3): one concerns the formation of the macrocycle through macrolactonization reaction from the former seco-acid formed from the Ar–O–Ar coupling from the aryl donor
  • /acceptor (route A), while the other corresponds to the intramolecular Ar–O–Ar coupling from the former ester (route B). Both synthetic routes have their advantages and disadvantages. The formation of the Ar–O–Ar bond can be accomplished using different methodologies [20] such as SNAr [21], Ullmann [22], or
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Published 29 Mar 2023

NaI/PPh3-catalyzed visible-light-mediated decarboxylative radical cascade cyclization of N-arylacrylamides for the efficient synthesis of quaternary oxindoles

  • Dan Liu,
  • Yue Zhao and
  • Frederic W. Patureau

Beilstein J. Org. Chem. 2023, 19, 57–65, doi:10.3762/bjoc.19.5

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  • ethers and N-heteroarenes by using a novel catalytic system based on sodium iodide (NaI) and triphenylphosphine (PPh3), suggested to function as an electron donoracceptor (EDA) complex [55][56][57][58][59][60]. Compared to previously reported radical reactions, this novel catalytic system has the key
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Published 16 Jan 2023

Design, synthesis, and evaluation of chiral thiophosphorus acids as organocatalysts

  • Karen R. Winters and
  • Jean-Luc Montchamp

Beilstein J. Org. Chem. 2022, 18, 1471–1478, doi:10.3762/bjoc.18.154

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  • dual donoracceptor role, such as P-stereogenic triflamide CPAs P(O)NHSO2CF3, is currently under investigation since BINOL-derived triflamides have been successful [48][49]. Another possibility would be to look at reactions in which the catalyst would not require a Brønsted basic site. Both directions
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Published 17 Oct 2022

Naphthalimide-phenothiazine dyads: effect of conformational flexibility and matching of the energy of the charge-transfer state and the localized triplet excited state on the thermally activated delayed fluorescence

  • Kaiyue Ye,
  • Liyuan Cao,
  • Davita M. E. van Raamsdonk,
  • Zhijia Wang,
  • Jianzhang Zhao,
  • Daniel Escudero and
  • Denis Jacquemin

Beilstein J. Org. Chem. 2022, 18, 1435–1453, doi:10.3762/bjoc.18.149

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  • investigate the joint influence of the conformation flexibility and the matching of the energies of the charge-transfer (CT) and the localized triplet excited (3LE) states on the thermally activated delayed fluorescence (TADF) in electron donoracceptor molecules, a series of compact electron donoracceptor
  • observed in the nanosecond transient absorption spectra with lifetimes in the 4–48 μs range. Computational investigations show that the orthogonal electron donoracceptor molecular structure is beneficial for TADF. These calculations indicate small energetic difference between the 3LE and 3CT states, which
  • -transfer (CT) and intersystem-crossing (ISC) phenomena [4][5]. Compounds showing TADF are usually presenting an orthogonal electron donoracceptor molecular structure, i.e., the π-planes of the electron donor and acceptor adopt an orthogonal geometry [6][7]. Such an architecture is beneficial to spatially
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Published 11 Oct 2022

Ionic multiresonant thermally activated delayed fluorescence emitters for light emitting electrochemical cells

  • Merve Karaman,
  • Abhishek Kumar Gupta,
  • Subeesh Madayanad Suresh,
  • Tomas Matulaitis,
  • Lorenzo Mardegan,
  • Daniel Tordera,
  • Henk J. Bolink,
  • Sen Wu,
  • Stuart Warriner,
  • Ifor D. Samuel and
  • Eli Zysman-Colman

Beilstein J. Org. Chem. 2022, 18, 1311–1321, doi:10.3762/bjoc.18.136

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  • the non-doped device, at 2.0% demonstrated 100% exciton utilization efficiency in the device and efficient energy transfer from the host to the guest cyanine emitter. Deep blue emission in LEECs is challenging. We also reported a blue-emitting LEEC employing a cationic sulfone-based donoracceptor
  • ). The presence of the DPA group in DiKTa-DPA-OBuIm transforms this compound from one that is MR-TADF to one that is better described as a donoracceptor TADF, which is reflected in the red-shifted and broadened emission [28]. Results and Discussion DiKTa-OBuIm was obtained in three steps (Scheme 1) in
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Published 22 Sep 2022

Thermally activated delayed fluorescence (TADF) emitters: sensing and boosting spin-flipping by aggregation

  • Ashish Kumar Mazumdar,
  • Gyana Prakash Nanda,
  • Nisha Yadav,
  • Upasana Deori,
  • Upasha Acharyya,
  • Bahadur Sk and
  • Pachaiyappan Rajamalli

Beilstein J. Org. Chem. 2022, 18, 1177–1187, doi:10.3762/bjoc.18.122

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  • thermally activated delayed fluorescence (TADF) characteristics are emerging due to the potential applications in optoelectronic devices, time-resolved luminescence imaging, and solid-phase sensing. Herein, we synthesized two (4-bromobenzoyl)pyridine (BPy)-based donoracceptor (D–A) compounds with varying
  • solution and in the solid state and with multicolor tunability by external stimuli are crucial for task-specific applications. Recently, donoracceptor (D–A)-based organic emitters have shown tunable optical and electrochemical properties due to alteration of the intermolecular charge-transfer (ICT
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Published 08 Sep 2022

Reductive opening of a cyclopropane ring in the Ni(II) coordination environment: a route to functionalized dehydroalanine and cysteine derivatives

  • Oleg A. Levitskiy,
  • Olga I. Aglamazova,
  • Yuri K. Grishin and
  • Tatiana V. Magdesieva

Beilstein J. Org. Chem. 2022, 18, 1166–1176, doi:10.3762/bjoc.18.121

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  • ) coordination environment in the form of a Schiff base is considered as a route to electrochemical broadening of the donoracceptor cyclopropane concept in combination with chirality induction in the targeted products. A tendency to the reductive ring-opening and the follow-up reaction paths of thus formed
  • provides targeted pharmacophoric properties of the bio-active molecule [23] but also opens a route to its further functionalization, being a building block with wide variety of reactivity. A donoracceptor cyclopropane concept suggested in the 1980s [24] became extremely popular in the recent decade [25
  • ][26]. Donoracceptor cyclopropanes constitute an easily available equivalent of all-carbon 1,3-zwitter-ions used in targeted synthesis of various alicyclic as well as carbo- or heterocyclic compounds [27][28][29][30]. The reactive synergy of the three-membered ring and the C–C bond polarization due to
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Published 08 Sep 2022

Introducing a new 7-ring fused diindenone-dithieno[3,2-b:2',3'-d]thiophene unit as a promising component for organic semiconductor materials

  • Valentin H. K. Fell,
  • Joseph Cameron,
  • Alexander L. Kanibolotsky,
  • Eman J. Hussien and
  • Peter J. Skabara

Beilstein J. Org. Chem. 2022, 18, 944–955, doi:10.3762/bjoc.18.94

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  • donoracceptor interaction [21]. With this strategy, fusing those systems should lead to greater π-delocalisation [15][22]. Moreover, the fused core system is flanked by thiophene groups with ethylhexyl groups which impart solubility [5] in common organic solvents such as tetrahydrofuran, chloroform or
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Published 01 Aug 2022

Post-synthesis from Lewis acid–base interaction: an alternative way to generate light and harvest triplet excitons

  • Hengjia Liu and
  • Guohua Xie

Beilstein J. Org. Chem. 2022, 18, 825–836, doi:10.3762/bjoc.18.83

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  • HCl, TFA, and BBr3 as dopants which were respectively added to the donoracceptor–donor (D–A–D) molecule 2,5-bis((N,N-diphenylamino)phenyl)thiazolothiazole (compound 2 in Figure 2) containing thiazolothiazole units. As shown in Figure 3b, four different colors ranged from green, yellow, red and NIR
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Published 12 Jul 2022

Heteroleptic metallosupramolecular aggregates/complexation for supramolecular catalysis

  • Prodip Howlader and
  • Michael Schmittel

Beilstein J. Org. Chem. 2022, 18, 597–630, doi:10.3762/bjoc.18.62

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  • (26) was chosen as a FRET acceptor as there is a considerable overlap in energy of the donor emission and acceptor absorption. Then, artificial LHSs were constructed with aggregates from 24b or 25b at a donor/acceptor ratio of 5:1 (Figure 6). Finally, the light harvesting materials (24b + 26) and (25b
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Published 27 May 2022

Syntheses of novel pyridine-based low-molecular-weight luminogens possessing aggregation-induced emission enhancement (AIEE) properties

  • Masayori Hagimori,
  • Tatsusada Yoshida,
  • Yasuhisa Nishimura,
  • Yukiko Ogawa and
  • Keitaro Tanaka

Beilstein J. Org. Chem. 2022, 18, 580–587, doi:10.3762/bjoc.18.60

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  • photophysically and computationally. The photophysical studies revealed that all the synthesized compounds exhibited fluorescence in organic solvents, while N-methyl-4-((pyridin-2-yl)amino)-substituted maleimide derivatives 4a–e, which are based on an acceptor–donoracceptor (A–D–A) system, exhibited aggregation
  • the electronic nature of the compounds with and without AIEE properties. Keywords: acceptor–donoracceptor; AIEE; low molecular weight; one-pot reaction; ((pyridin-2-yl)amino)maleimide; TD-DFT calculation; Introduction Fluorescent compounds have attracted considerable attention as functional
  • aminopyridines based on the acceptor–donoracceptor (A–D–A) system exhibit AIEE properties in aqueous media, which may be novel candidate molecules for AIEE. Herein, we report the synthesis, photophysical properties, and computational studies of pyrido[1,2-a]pyrrolo[3,4-d]pyrimidines and N-methyl-4-((pyridin-2
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Published 24 May 2022

Substituent effect on TADF properties of 2-modified 4,6-bis(3,6-di-tert-butyl-9-carbazolyl)-5-methylpyrimidines

  • Irina Fiodorova,
  • Tomas Serevičius,
  • Rokas Skaisgiris,
  • Saulius Juršėnas and
  • Sigitas Tumkevicius

Beilstein J. Org. Chem. 2022, 18, 497–507, doi:10.3762/bjoc.18.52

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  • ; Introduction The first reports on highly efficient thermally activated delayed fluorescence (TADF) mechanism and its successful realization in organic light emitting diodes (OLEDs) by Adachi and co-workers [1][2] have drawn the attention to the design and synthesis of various emissive donoracceptor organic
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Published 05 May 2022

Comparative study of thermally activated delayed fluorescent properties of donor–acceptor and donor–acceptor–donor architectures based on phenoxazine and dibenzo[a,j]phenazine

  • Saika Izumi,
  • Prasannamani Govindharaj,
  • Anna Drewniak,
  • Paola Zimmermann Crocomo,
  • Satoshi Minakata,
  • Leonardo Evaristo de Sousa,
  • Piotr de Silva,
  • Przemyslaw Data and
  • Youhei Takeda

Beilstein J. Org. Chem. 2022, 18, 459–468, doi:10.3762/bjoc.18.48

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  • ) compound based on a donoracceptor (D–A) architecture (D = phenoxazine; A = dibenzo[a,j]phenazine) has been developed, and its photophysical properties were characterized. The D–A compound is applicable as an emitting material for efficient organic light-emitting diodes (OLEDs), and its external quantum
  • thermally activated delayed fluorescent behavior. Keywords: charge-transfer; dibenzophenazine; donoracceptor; organic light-emitting diodes; thermally activated delayed fluorescence; Introduction Thermally activated delayed fluorescence (TADF), which was firstly reported in 1961 by Parker and Hatchard [1
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Published 25 Apr 2022
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