Hypervalent halogen chemistry
Editors:
Prof. Tanja Gulder, Universität Leipzig and Universität des Saarlandes
Prof. Joanna Wencel-Delord, Universität Würzburg and Université de Strasbourg/Université de Haute Alsace
Prof. Tanja Gulder, Universität Leipzig and Universität des Saarlandes
Prof. Joanna Wencel-Delord, Universität Würzburg and Université de Strasbourg/Université de Haute Alsace
Hypervalent halogen chemistry has recently evolved from a chemical curiosity to a widespread versatile synthetic methodology that is not limited to simple oxidation reactions anymore. In this thematic issue, we will cover the novel concepts and the latest developments in hypervalent halogen chemistry, in particular those addressing new reactivities, catalytic and/or enantioselective transformations, electrochemistry, as well as photochemistry.
Still open for submission.
Still open for submission.
SOMOphilic alkyne vs radical-polar crossover approaches: The full story of the azido-alkynylation of alkenes
- Julien Borrel and
- Jerome Waser
Beilstein J. Org. Chem. 2024, 20, 701–713, doi:10.3762/bjoc.20.64
Ortho-ester-substituted diaryliodonium salts enabled regioselective arylocyclization of naphthols toward 3,4-benzocoumarins
- Ke Jiang,
- Cheng Pan,
- Limin Wang,
- Hao-Yang Wang and
- Jianwei Han
Beilstein J. Org. Chem. 2024, 20, 841–851, doi:10.3762/bjoc.20.76
Three-component N-alkenylation of azoles with alkynes and iodine(III) electrophile: synthesis of multisubstituted N-vinylazoles
- Jun Kikuchi,
- Roi Nakajima and
- Naohiko Yoshikai
Beilstein J. Org. Chem. 2024, 20, 891–897, doi:10.3762/bjoc.20.79
Auxiliary strategy for the general and practical synthesis of diaryliodonium(III) salts with diverse organocarboxylate counterions
- Naoki Miyamoto,
- Daichi Koseki,
- Kohei Sumida,
- Elghareeb E. Elboray,
- Naoko Takenaga,
- Ravi Kumar and
- Toshifumi Dohi
Beilstein J. Org. Chem. 2024, 20, 1020–1028, doi:10.3762/bjoc.20.90
Oxidative hydrolysis of aliphatic bromoalkenes: scope study and reactivity insights
- Amol P. Jadhav and
- Claude Y. Legault
Beilstein J. Org. Chem. 2024, 20, 1286–1291, doi:10.3762/bjoc.20.111
Hypervalent iodine-catalyzed amide and alkene coupling enabled by lithium salt activation
- Akanksha Chhikara,
- Fan Wu,
- Navdeep Kaur,
- Prabagar Baskaran,
- Alex M. Nguyen,
- Zhichang Yin,
- Anthony H. Pham and
- Wei Li
Beilstein J. Org. Chem. 2024, 20, 1405–1411, doi:10.3762/bjoc.20.122
A comparison of structure, bonding and non-covalent interactions of aryl halide and diarylhalonium halogen-bond donors
- Nicole Javaly,
- Theresa M. McCormick and
- David R. Stuart
Beilstein J. Org. Chem. 2024, 20, 1428–1435, doi:10.3762/bjoc.20.125
Predicting bond dissociation energies of cyclic hypervalent halogen reagents using DFT calculations and graph attention network model
- Yingbo Shao,
- Zhiyuan Ren,
- Zhihui Han,
- Li Chen,
- Yao Li and
- Xiao-Song Xue
Beilstein J. Org. Chem. 2024, 20, 1444–1452, doi:10.3762/bjoc.20.127
Synthesis of 4-functionalized pyrazoles via oxidative thio- or selenocyanation mediated by PhICl2 and NH4SCN/KSeCN
- Jialiang Wu,
- Haofeng Shi,
- Xuemin Li,
- Jiaxin He,
- Chen Zhang,
- Fengxia Sun and
- Yunfei Du
Beilstein J. Org. Chem. 2024, 20, 1453–1461, doi:10.3762/bjoc.20.128
Tetrabutylammonium iodide-catalyzed oxidative α-azidation of β-ketocarbonyl compounds using sodium azide
- Christopher Mairhofer,
- David Naderer and
- Mario Waser
Beilstein J. Org. Chem. 2024, 20, 1510–1517, doi:10.3762/bjoc.20.135
Divergent role of PIDA and PIFA in the AlX3 (X = Cl, Br) halogenation of 2-naphthol: a mechanistic study
- Kevin A. Juárez-Ornelas,
- Manuel Solís-Hernández,
- Pedro Navarro-Santos,
- J. Oscar C. Jiménez-Halla and
- César R. Solorio-Alvarado
Beilstein J. Org. Chem. 2024, 20, 1580–1589, doi:10.3762/bjoc.20.141
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