Hypervalent halogen chemistry

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Editors:
Prof. Tanja Gulder, Universität Leipzig and Universität des Saarlandes
Prof. Joanna Wencel-Delord, Universität Würzburg and Université de Strasbourg/Université de Haute Alsace
 
Hypervalent halogen chemistry has recently evolved from a chemical curiosity to a widespread versatile synthetic methodology that is not limited to simple oxidation reactions anymore. In this thematic issue, we will cover the novel concepts and the latest developments in hypervalent halogen chemistry, in particular those addressing new reactivities, catalytic and/or enantioselective transformations, electrochemistry, as well as photochemistry.

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SOMOphilic alkyne vs radical-polar crossover approaches: The full story of the azido-alkynylation of alkenes

  • Julien Borrel and
  • Jerome Waser

Beilstein J. Org. Chem. 2024, 20, 701–713, doi:10.3762/bjoc.20.64

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Commentary
Published 03 Apr 2024

Ortho-ester-substituted diaryliodonium salts enabled regioselective arylocyclization of naphthols toward 3,4-benzocoumarins

  • Ke Jiang,
  • Cheng Pan,
  • Limin Wang,
  • Hao-Yang Wang and
  • Jianwei Han

Beilstein J. Org. Chem. 2024, 20, 841–851, doi:10.3762/bjoc.20.76

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Letter
Published 18 Apr 2024

Oxidative hydrolysis of aliphatic bromoalkenes: scope study and reactivity insights

  • Amol P. Jadhav and
  • Claude Y. Legault

Beilstein J. Org. Chem. 2024, 20, 1286–1291, doi:10.3762/bjoc.20.111

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Letter
Published 03 Jun 2024

Hypervalent iodine-catalyzed amide and alkene coupling enabled by lithium salt activation

  • Akanksha Chhikara,
  • Fan Wu,
  • Navdeep Kaur,
  • Prabagar Baskaran,
  • Alex M. Nguyen,
  • Zhichang Yin,
  • Anthony H. Pham and
  • Wei Li

Beilstein J. Org. Chem. 2024, 20, 1405–1411, doi:10.3762/bjoc.20.122

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Letter
Published 24 Jun 2024

A comparison of structure, bonding and non-covalent interactions of aryl halide and diarylhalonium halogen-bond donors

  • Nicole Javaly,
  • Theresa M. McCormick and
  • David R. Stuart

Beilstein J. Org. Chem. 2024, 20, 1428–1435, doi:10.3762/bjoc.20.125

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Full Research Paper
Published 27 Jun 2024

Synthesis of 4-functionalized pyrazoles via oxidative thio- or selenocyanation mediated by PhICl2 and NH4SCN/KSeCN

  • Jialiang Wu,
  • Haofeng Shi,
  • Xuemin Li,
  • Jiaxin He,
  • Chen Zhang,
  • Fengxia Sun and
  • Yunfei Du

Beilstein J. Org. Chem. 2024, 20, 1453–1461, doi:10.3762/bjoc.20.128

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Published 28 Jun 2024
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